期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 22, 页码 6462-6466出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201602087
关键词
cluster organic frameworks; copper; heterometallic structures; luminescence; polyoxometalates
资金
- 973 Program [2011CBA00502]
- NSFC [21273239, 21401195, 21571016]
- NSF for Young Scholars of Fujian Province [2015J05041]
A new approach to prepare heterometallic cluster organic frameworks has been developed. The method was employed to link Anderson-type polyoxometalate (POM) clusters and transition-metal clusters by using a designed rigid tris(alkoxo) ligand containing a pyridyl group to form a three-fold interpenetrated anionic diamondoid structure and a 2D anionic layer, respectively. This technique facilitates the integration of the unique inherent properties of Anderson-type POM clusters and cuprous iodide clusters into one cluster organic framework.
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