期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 15, 页码 4790-4793出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201601280
关键词
aromatic substitution; (benzenesulfonyl)difluoromethanesulfenamide; difluoromethylthiolation; electrophilic addition; fluorine
资金
- RADIOMI project [EU FP7-PEOPLE-2012-ITN-RADIOMI]
- CNRS
- French Fluorine Network
The (benzenesulfonyl)difluoromethylsulfanyl (PhSO2CF2S) group is a valuable substituent with specific properties which can provide access to new applications of fluoroalkylthiolated compounds. Direct introduction of this moiety can be performed by in an electrophilic manner by using a new shelf-stable reagent, namely a (benzenesulfonyl)difluoromethanesulfenamide. Furthermore, mild magnesium-mediated reduction of the PhSO2CF2S group leads to a facile synthesis of difluoromethylthiolated molecules and their deuterated analogs.
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