Tandem Allylboration-Prins Reaction for the Rapid Construction of Substituted Tetrahydropyrans: Application to the Total Synthesis of (−)-Clavosolide A

Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A and Late-Stage Modification

(2015) Alexander M. Haydl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Short Convergent Synthesis of the Mycolactone Core Through Lithiation-Borylation Homologations

(2015) Christopher A. Brown et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total synthesis of clavosolide A via tandem allylic oxidation/oxa-conjugate addition reaction

(2015) Joseph B. Baker et al.   TETRAHEDRON LETTERS

Lithiation–Borylation Methodology and Its Application in Synthesis

(2014) Daniele Leonori et al.   ACCOUNTS OF CHEMICAL RESEARCH

Short Stereoselective Synthesis of thePhytophthoraUniversal Mating Hormone α1 Using Lithiation/Borylation Reactions

(2014) Alexander P. Pulis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent Total Synthesis of Δ9-Tetrahydrocannabinols

(2014) Michael A. Schafroth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific conversion of alcohols into pinacol boronic esters using lithiation–borylation methodology with pinacolborane

(2014) Stefan Roesner et al.   CHEMICAL COMMUNICATIONS

Competitive Silyl-Prins Cyclization versus Tandem Sakurai-Prins Cyclization: An Interesting Substitution Effect

(2014) Alberto Diez-Varga et al.   CHEMISTRY-A EUROPEAN JOURNAL

Strategies for the construction of tetrahydropyran rings in the synthesis of natural products

(2014) Nadiah Mad Nasir et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Stereoselective Total Synthesis of (+)-Giganin and Its C10 Epimer by Using Late-Stage Lithiation-Borylation Methodology

(2013) Catherine J. Fletcher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Investigation of Functionalized α-Chloroalkyllithiums for a Stereospecific Reagent-Controlled Homologation Approach to the Analgesic Alkaloid (−)-Epibatidine

(2013) Christopher R. Emerson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Prins-Type Cyclization Reactions in Natural Product Synthesis

(2013) Xun Han et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Enantioenriched Tertiary Boronic Esters by the Lithiation/Borylation of Secondary Alkyl Benzoates

(2013) Alexander P. Pulis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereo- and Enantioselective Allylboration of Aldehydes using α-Substituted Allyl/Crotyl Pinacol Boronic Esters via in Situ Generated Borinic Esters

(2013) Jack L.-Y. Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multicomponent Prins Cyclization from Allylsilyl Alcohols Leading to Dioxaspirodecanes

(2013) Asunción Barbero et al.   ORGANIC LETTERS

Focused Update on the Prins Reaction and the Prins Cyclization

(2012) Isidro M. Pastor et al.   CURRENT ORGANIC CHEMISTRY

Enantioselective Homocrotylboration of Aliphatic Aldehydes

(2012) Hongkun Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclopropane Compatibility with Oxidative Carbocation Formation: Total Synthesis of Clavosolide A

(2012) GuangRong Peh et al.   ORGANIC LETTERS

One-pot synthesis of 2,3,4,5,6-pentasubstituted tetrahydropyrans using lithiation–borylation, allylation and Prins cyclisation reactions

(2012) Adeem Mahmood et al.   TETRAHEDRON LETTERS

Use of alkyl 2,4,6-triisopropylbenzoates in the asymmetric homologation of challenging boronic esters

(2011) Robin Larouche-Gauthier et al.   CHEMICAL COMMUNICATIONS

Prins-Type Macrocyclizations as an Efficient Ring-Closing Strategy in Natural Product Synthesis

(2010) Erika A. Crane et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Total Synthesis of (-)-Clavosolide A and B

(2010) Jung-Beom Son et al.   BULLETIN OF THE KOREAN CHEMICAL SOCIETY

Application of the Lithiation−Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry

(2010) Martin Althaus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of (-)-Pironetin by an Iterative Prins Cyclisation and Reductive Cleavage Strategy

(2010) J. Yadav et al.   SYNLETT

An Efficient Formal Synthesis of (−)-Clavosolide A Featuring a “Mismatched” Stereoselective Oxocarbenium Reduction

(2009) Jesse D. Carrick et al.   ORGANIC LETTERS

Synthesis of tetrahydropyrans and related heterocycles via prins cyclization; extension to aza-prins cyclization

(2009) Clarisse Olier et al.   TETRAHEDRON

Intramolecular Prins cyclisations for the stereoselective synthesis of bicyclic tetrahydropyrans

(2008) Jon D. Elsworth et al.   CHEMICAL COMMUNICATIONS

Cationic Palladium(II)-Catalyzed Stereoselective Glycosylation with Glycosyl Trichloroacetimidates

(2008) Jaemoon Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols

(2008) Jake L. Stymiest et al.   NATURE

Total synthesis of clavosolide A

(2008) Tushar Kanti Chakraborty et al.   TETRAHEDRON

Synthesis of six-membered oxygenated heterocycles through carbon–oxygen bond-forming reactions

(2008) Igor Larrosa et al.   TETRAHEDRON