Article
Chemistry, Physical
Jinzhi Wang, Junzhe Du, Jingwen Zhao, Yantao Wang, Yue Tang, Guanglei Cui
Summary: The study revealed a sequential conversion reaction involving H+/Zn2+ with 6e(-) transfer for tellurium-based cathodes, achieving outstanding capacity in aqueous zinc electrolytes. Two distinct redox processes of TeO2 <-> Te and Te <-> ZnTe were explicitly revealed within the electrochemical window of routine aqueous Zn electrolytes.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Review
Chemistry, Multidisciplinary
Hanisha Ponnuru, Ifra Marriam, Imesha Rambukwella, Jun-Chao Zheng, Cheng Yan
Summary: Liquid metals are being increasingly studied and applied in various fields such as energy storage, catalysis, electronics, and biomedical engineering. In rechargeable batteries, the introduction of liquid metals has shown great potential in improving performance and addressing common challenges. This review article provides an overview of recent advances in using liquid metals for rechargeable batteries, highlighting their unique properties and potential for future development.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Chemistry, Physical
Yu Jiao, Fan Wang, Yuhong Ma, Sangang Luo, Yaoyao Li, Anjun Hu, Miao He, Fei Li, Dongjiang Chen, Wei Chen, Tianyu Lei, Yin Hu
Summary: This review categorizes the basic failure mechanisms and major challenges of Li-S batteries at low temperature, and discusses strategies and advances in the design of optimized electrolyte, composite cathode and functional separator. Suggestions for future development of practical Li-S batteries at low temperature are proposed.
Editorial Material
Multidisciplinary Sciences
Jelena Popovic
Summary: Rechargeable metal batteries are highly investigated for their potential to store higher energy, but overcoming issues related to reactive interfaces and interphases is crucial for producing reliable batteries.
NATURE COMMUNICATIONS
(2021)
Review
Chemistry, Physical
Xuan Zhang, Huiyang Ma, Jiqiong Liu, Jiahang Chen, Huichao Lu, Yudai Huang, Jiulin Wang
Summary: The S@pPAN composite material, which provides a conductive pathway for sulfur active material at the molecular level, has shown promising electrochemical performances in lithium-sulfur batteries. However, the accurate structure of S@pPAN and its redox reaction mechanism during charge-discharge process have not been determined yet. This review summarizes previous research and inferences on the structure and electrochemical reaction mechanism of S@pPAN, providing a reference for future study of lithium-sulfur batteries.
Review
Chemistry, Multidisciplinary
Zhenfang Zhou, Guicun Li, Jiujun Zhang, Yufeng Zhao
Summary: Lithium sulfur batteries, with their ultrahigh theoretical gravimetric energy density and low cost and environmental friendliness, are being further developed to operate at a wide range of temperatures. Challenges in material performance, electrolytes, lithium metal anodes, and the impact of thermal changes are key areas for future research directions in enabling lithium sulfur batteries to function effectively in extreme temperature conditions.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Lenin W. Kum, Ashish Gogia, Nick Vallo, Deependra Kumar Singh, Jitendra Kumar
Summary: Lithium-ion batteries (LIBs) are widely used in modern electronics and electric vehicles due to their high energy and power densities, cycle-life, and safety. This study presents a simple method to improve the high-voltage charge capability of LIBs by applying an artificial cathode-electrolyte interface (Li+-ACEI) on the state-of-the-art cathode, LiCoO2 (LCO). The application of Li+-ACEI using a superionic ceramic Li+ ion conductor, lithium aluminum germanium phosphate (LAGP), results in reduced charge-transfer resistance, higher discharge capacity, higher Coulombic efficiency, and higher rate capability of the LCO cathodes.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Lei Yan, Wenhui Yang, Haoxiang Yu, Liyuan Zhang, Jie Shu
Summary: In this review, the recent advances in rechargeable calcium-ion batteries (CIBs) are systematically summarized and discussed, including cathode and anode materials as well as the electrolytes. The relationship between the structures of electrode materials and their reaction mechanisms is comprehensively introduced. Moreover, the design strategies of electrode materials and suitable electrolytes are also elaborated to improve the energy density and enlarge the cycle life of CIBs.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Physical
Yongseok Lee, Jungmin Kang, Jinho Ahn, Wonseok Ko, Hyunyoung Park, Seokjin Lee, Sangyeop Lee, Jung-Keun Yoo, Jongsoon Kim
Summary: In this study, the conversion properties of Cu(PO3)(2) as a cathode material for Li rechargeable batteries were enhanced through amorpholization and carbon-mixing. The amorphorized Cu(PO3)(2)/C composite exhibited higher reversible capacity and average operation voltage compared to crystalline Cu(PO3)(2)/C composites. The excellent power capability and cyclability of the amorphorized Cu(PO3)(2)/C composite were attributed to the enhanced kinetics of the conversion reaction in Cu(PO3)(2). The reversible conversion-reaction mechanism of Cu(PO3)(2) in a Li-cell system was also demonstrated through various experimental measurements.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Materials Science, Multidisciplinary
Chunmao Huang, Shenghong Liu, Yang Wang, Jingjie Feng, Yanming Zhao
Summary: NaVMoO6 with brannerite-type structure was successfully synthesized using a sol-gel method, and utilized as a cathode material for lithium ion batteries for the first time. The material showed stable reversible specific capacity, indicating its potential as a cathode material for LIBs and enriching the possibilities of molybdenum-based materials for this application.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Review
Chemistry, Multidisciplinary
Ze-Chen Lv, Peng-Fei Wang, Jian-Cang Wang, Shu-Hui Tian, Ting-Feng Yi
Summary: Lithium-sulfur (Li-S) battery, which combines abundant sulfur with lithium metal to release energy, is considered a potential substitute for current lithium-ion batteries. However, the shuttle effect of lithium polysulfides, large volume change, poor conductivity of sulfur and its solid-state products, and self-discharge phenomenon limit its practical application. This review systematically introduces the development of Li-S batteries, summarizes the latest work on anode, cathode, separator and electrolyte, and proposes some promising views on future research directions of this battery system.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2023)
Review
Polymer Science
Siyuan Ren, Pengfei Sang, Wei Guo, Yongzhu Fu
Summary: Organosulfur copolymers have the potential as cathode materials in rechargeable batteries due to their unique molecular structure and reduced formation of lithium polysulfides. Compared to linear polysulfides, organosulfur copolymers can significantly reduce the shuttle effect of polysulfides during cycling.
Article
Chemistry, Multidisciplinary
Buddha Deka Boruah, Bo Wen, Michael De Volder
Summary: A novel photorechargeable lithium-ion battery has been proposed, which can be charged using light. This battery utilizes photocathodes made from vanadium pentoxide nanofibers mixed with P3HT and rGO additives, leading to significant improvements in capacity and conversion efficiency.
Review
Chemistry, Physical
Sang A. Han, Hamzeh Qutaish, Jong-Won Lee, Min-Sik Park, Jung Ho Kim
Summary: Lithium-ion batteries play a crucial role in portable electronic devices, and innovative solutions are needed to address technical issues and enhance safety. Metal-organic frameworks (MOFs) have shown promise in meeting the requirements of advanced energy storage technologies, particularly in different types of lithium batteries.
Article
Chemistry, Physical
Pallavi Thakur, Khorsed Alam, Prasenjit Sen, Tharangattu N. Narayanan
Summary: By incorporating -OH functionalities into the cathode through polysaccharide addition, the discharge capacity and cyclability of Li-O2 batteries are enhanced. This rational design route provides high capacities for the emergent Li-O2 batteries.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Chemistry, Physical
Mathew J. Boyer, Linas Vilciauskas, Gyeong S. Hwang
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2016)
Article
Biotechnology & Applied Microbiology
Mathew J. Boyer, Gyeong S. Hwang
CURRENT OPINION IN CHEMICAL ENGINEERING
(2016)
Article
Electrochemistry
Mathew J. Boyer, Gyeong S. Hwang
ELECTROCHIMICA ACTA
(2018)
Article
Chemistry, Multidisciplinary
Xingwen Yu, Mathew J. Boyer, Gyeong S. Hwang, Arumugam Manthiram
Article
Chemistry, Analytical
Yang-kyu Park, Mathew Boyer, Gyeong S. Hwang, Jae-won Lee
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2019)
Article
Electrochemistry
Hyunseo Kang, Mathew Boyer, Gyeong S. Hwang, Jae-won Lee
ELECTROCHIMICA ACTA
(2019)
Article
Chemistry, Physical
Mathew J. Boyer, Gyeong S. Hwang
JOURNAL OF PHYSICAL CHEMISTRY C
(2019)
Article
Chemistry, Physical
Mathew J. Boyer, Gyeong S. Hwang
JOURNAL OF PHYSICAL CHEMISTRY C
(2020)
Article
Chemistry, Physical
Mathew J. Boyer, Gyeong S. Hwang
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2019)
Article
Chemistry, Physical
Xingwen Yu, Sinan Feng, Mathew J. Boyer, Myungsuk Lee, Robert C. Ferrier, Nathaniel A. Lynd, Gyeong S. Hwang, Guibin Wang, Steve Swinnea, Arumugam Manthiram
MATERIALS TODAY ENERGY
(2018)