Review
Chemistry, Physical
Mingyu Chu, Yu Liu, Xiangxi Lou, Qiao Zhang, Jinxing Chen
Summary: This article highlights the urgent need for a deep understanding of the relationship between polymer structure and recycling performance in order to combat the global environmental crisis caused by plastic pollution. It discusses the development and challenges of chemical re/upcycling of waste PET and polyolefins, as well as prospects for innovations in catalyst synthesis and reaction engineering. The article concludes with a brief perspective on the future of plastic re/upcycling.
Article
Energy & Fuels
Ruchi Lamba
Summary: This paper investigates the esterification reaction of decanoic acid with ethanol using Amberlyst 15 solid catalyst. The catalytic stability behavior is studied by comparing the structures of fresh and reused catalysts. The effect of initial activities on reaction rate is examined using the group contribution method. The results show that the reaction kinetics of this reaction follow the Eley-Rideal mechanism.
BIOMASS CONVERSION AND BIOREFINERY
(2022)
Article
Chemistry, Physical
Mostafa El-Shafie
Summary: In this study, the ammonia formation rate equations were analyzed at different pressures and flow rates. Various kinetic models were used to predict the system behavior and evaluate their fit with experimental data. The results showed that the rate equation correlates with the overall dissociation rate of adsorbed nitrogen and the equilibrium constant for ammonia formation reactions.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Review
Chemistry, Multidisciplinary
Fan Liu, Chengxiang Shi, Xiaolei Guo, Zexing He, Lun Pan, Zhen-Feng Huang, Xiangwen Zhang, Ji-Jun Zou
Summary: This review introduces the design principles of hydrogen evolution reaction (HER) electrocatalysts, including thermodynamics, kinetics, and structural descriptors. It also discusses the reasonable design, preparation, mechanistic understanding, and performance enhancement of electrocatalysts. Furthermore, it briefly discusses recent advancements in the electrocatalytic water splitting technology and proposes the challenges and perspectives in developing highly efficient hydrogen evolution electrocatalysts.
Article
Engineering, Chemical
Ziad T. Alismaeel, Thaer M. Al-Jadir, Talib M. Albayati, Ammar S. Abbas, Aidan M. Doyle
Summary: In this study, a high purity FAU-type zeolite catalyst was prepared and modified as a heterogeneous efficient catalyst for biodiesel production. The catalyst was characterized using various techniques and the reaction conditions were optimized to improve the conversion rate.
ADVANCED POWDER TECHNOLOGY
(2022)
Review
Chemistry, Applied
Zhechen Fan, Hao Wan, Hao Yu, Junjie Ge
Summary: This review summarizes the latest research progress on Fe-M-N-C based dual-atom catalysts (DACs) for enhancing oxygen reduction catalysis. By controlling the geometric and electronic structures of the catalysts, DACs can improve their intrinsic catalytic activity through synergistic and modulation effects.
CHINESE JOURNAL OF CATALYSIS
(2023)
Article
Chemistry, Physical
Taejung Lim, Jae Hyung Kim, Jinjong Kim, Du San Baek, Tae Joo Shin, Hu Young Jeong, Kug-Seung Lee, Kai S. Exner, Sang Hoon Joo
Summary: A new CER catalyst Pt-1/CNT composed of atomically dispersed Pt-N-4 sites on carbon nanotubes has been developed, showing excellent activity and selectivity compared to traditional Ru-based mixed metal oxide catalysts. The catalysts demonstrate different reaction orders in low and high overpotential regimes, with the RDS switching from the Volmer step to the Heyrovsky step. These insights provide new understanding in the field of CER catalysis.
Article
Chemistry, Physical
Monika Sharma, Goldi Sharma, Sandeep Kaushal, Rahul Badru
Summary: In this study, DHPM analogs of Vanillin were synthesized in a one-step Biginelli condensation using a Eu-Gd@BiPO4 nano-composite catalyst. The catalyst showed high efficiency and the reaction provided good yields in a short time under solventless conditions. The synthesized compounds exhibited promising antioxidant and antibacterial activities.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
L. Gao, I. Miletto, C. Ivaldi, G. Paul, L. Marchese, S. Coluccia, F. Jiang, E. Gianotti, M. Pera-Titus
Summary: A new catalyst based on crystalline silicoaluminophosphate SAPO-5 with hierarchical porosity and optimized silicon content was developed for the one-pot synthesis of tetrahydrofuran derivatives. NH3-TPD and FT-IR spectroscopy were used to assess the acidity and accessibility of the catalyst, which showed potential for efficient hydrogenation reactions.
JOURNAL OF CATALYSIS
(2021)
Article
Environmental Sciences
Xinghao Liu, Zhaoguang Yang, Wenxiu Zhu, Ying Yang, Haipu Li
Summary: This study established a heterogeneous catalytic ozonation chemical kinetic model, with good correlation between experimentally measured and model-predicted removal ratios, allowing for satisfactory prediction of pollutant degradation rates.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2022)
Article
Chemistry, Physical
Jiadong Chen, Minkai Qin, Shuangxiu Ma, Ruxue Fan, Xiaozhong Zheng, Shanjun Mao, Chunhong Chen, Yong Wang
Summary: By modifying the adsorption behavior, a Pt/PtTex heterogeneous catalysis interface was successfully constructed to increase OH* adsorption and reduce H* adsorption, resulting in exceptionally lower Tafel slopes for Pt/PtTex NRs, making them among the best HER electrocatalysts reported.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Physical
Giovanni Di Liberto, Luis A. Cipriano, Gianfranco Pacchioni
Summary: One of the objectives of electronic structure theory is to predict chemical and catalytic activities, which has become less complex with the use of single atom catalysts and graphene-based catalysts for electrocatalytic reactions. The rapid growth of theoretical studies based on density functional theory (DFT) and proposals of universal descriptors have provided guidance for the synthesis of efficient catalysts. However, there are still challenges in predicting catalyst activity, such as the accuracy of calculations, neglect of important contributions, and the physical meaning of proposed descriptors, not to mention reproducibility issues.
Article
Chemistry, Physical
Ying Qi, Tao Zhang, Ningxiang Wu, Huarui Ding, Gongxun Yu, Jiabiao Lian, Li Xu, Jingxia Qiu, Sheng Li
Summary: Cobalt sulfides embedded in N-doped carbon composite were synthesized in this study, showing enhanced rate capability and cycling stability compared to Co9S8. This work provides an effective material design strategy for enhancing the electrochemical performance of sodium-ion storage by depicting the change of Na+ diffusion under the influence of heterostructures.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Physics, Multidisciplinary
Jinyang Liu, Min Wu, Xinyi Yang, Juan Ding, Weiwei Lei, Yongming Sui
Summary: A simple aqueous synthetic method was developed to prepare bimetallic PdAu nanoflowers catalysts for methanol oxidation reaction (MOR) in alkaline environment, showing enhanced catalytic activity and durability compared to commercial Pd/C catalyst. The unique porous structure and the shift of the d-band center of Pd are believed to contribute to the superior MOR activity of the PdAu nanoflowers.
Review
Chemistry, Multidisciplinary
Tohru Setoyama
Summary: Research and development of heterogeneous catalysts and relevant process technologies at Mitsubishi Chemical and its collaborators since 1994 have focused on catalyst design reflecting reaction mechanisms and kinetics. The studies include ring-opening polymerization catalysis, aerobic oxidation catalyzed by iron oxide, olefin interconversion, efficient water splitting catalysts, reactive separation, and innovative MTO catalysts with steam durability.
RESEARCH ON CHEMICAL INTERMEDIATES
(2021)
Article
Chemistry, Physical
Shaofeng Xiong, Shundong Bao, Weian Wang, Jian Hao, Yu Mao, Pingle Liu, Yanping Huang, Zhengkang Duan, Yang Lv, Donghong Ouyang
Summary: This study designed and prepared a surface oxygen vacancy and graphene quantum dots co-modified photocatalyst, which exhibited enhanced conversion of CO2 to CO. By optimizing the catalyst structure, the separation efficiency and fluorescence lifetime of photogenerated electrons were improved.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Engineering, Chemical
Guida Li, Wenxing Yao, Yunlei Zhao, Bo Jin, Jianyong Xu, Yu Mao, Xiao Luo, Zhiwu Liang
Summary: By combining macroscopic kinetic modeling and density functional theory calculations, the reduction kinetics and carbon formation of Cu-doped Fe-based oxygen carriers were investigated. It was found that Cu doping can enhance the reduction rate and inhibit carbon formation by reducing the activation energies and increasing the formation energy of carbon-carbon chains on the material surface. Cu dopant also promotes oxygen ion migration and improves the reduction reaction rate constant.
CHEMICAL ENGINEERING SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Qiaoyu Zhang, Qiufeng Mao, Yunpeng Zhou, Liangyu Zou, Daoyun Zhu, Yangqiang Huang, Hongxia Gao, Xiao Luo, Yu Mao, Zhiwu Liang
Summary: This study investigates the application of all possible M-N-C catalysts in formic acid dehydrogenation using density functional theory and experimental analysis. The results suggest that atomically dispersed Co sites exhibit good catalytic activity for formic acid dehydrogenation, and the appropriate nitrogen content plays a critical role in catalytic activity.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Engineering, Chemical
Daoyun Zhu, Haiou Liu, Yangqiang Huang, Xiao Luo, Yu Mao, Zhiwu Liang
Summary: In this study, ceria catalysts were screened and it was found that the (110) surface and higher oxygen vacancy content have a better promoting effect on the synthesis of dimethyl carbonate (DMC), and rod-shaped CeO2 catalyst has a better catalytic effect.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Chemistry, Physical
Yuwei Liu, Hongyang Liu, Lukai Luo, Baining Lin, Yonghua Zhou, Hanqing Wang, Ping Wang, Yu Mao
Summary: Phosphorus-doped boron nitride (PBN) has been confirmed as an effective metal-free catalyst for the direct dehydrogenation (DDH) of ethylbenzene to styrene. This study utilized barbituric acid as co-reactant sources to create B defects in PBN and mesoporous PBN (m-PBN) materials, improving their catalytic activity. The m-PBN with B defects delivered a high styrene production rate of 22.54 mmol(ST) g(-1) h(-1) and stable operation for 300 hours when grown on Al2O3, demonstrating the usefulness of defect tuning strategy in constructing efficient catalysts for styrene production.
Article
Chemistry, Inorganic & Nuclear
Fengyang Yu, Xiaohua Wang, Haiyue Lu, Gen Li, Baicheng Liao, Hanqing Wang, Chunying Duan, Yu Mao, Liyong Chen
Summary: Low-cost high-efficiency H2 evolution is essential for large-scale applications. This research aims to build highly active photocatalysts for sunlight-driven H2 production through surface engineering. Single-atom Pt doped TiO2-x nanosheets (NSs) with Pt nanoparticles (NPs) at their edges are prepared by an oxygen vacancy engaged synthetic strategy. The Pt/TiO2-x-SAP exhibits ultrahigh photocatalytic performance with a quantum yield of 90.8% and a H2 generation rate of 607 mmol gcata-1 h-1.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Zedong Zhang, Shenghua Chen, Jiexin Zhu, Chenliang Ye, Yu Mao, Bingqing Wang, Gang Zhou, Liqiang Mai, Ziyun Wang, Xiangwen Liu, Dingsheng Wang
Summary: In this work, a Pd delta--Cu3N catalyst containing charge-separated Pd delta--Cu delta+ atom pair is designed to stabilize the Cu delta+ sites and promote the CO dimerization process. The achieved 14-fold increase in C2 product Faradaic efficiency demonstrates the effectiveness of this strategy for enhancing CO2 RR.
Article
Multidisciplinary Sciences
Jian Jin, Joshua Wicks, Qiuhong Min, Jun Li, Yongfeng Hu, Jingyuan Ma, Yu Wang, Zheng Jiang, Yi Xu, Ruihu Lu, Gangzheng Si, Panagiotis Papangelakis, Mohsen Shakouri, Qunfeng Xiao, Pengfei Ou, Xue Wang, Zhu Chen, Wei Zhang, Kesong Yu, Jiayang Song, Xiaohang Jiang, Peng Qiu, Yuanhao Lou, Dan Wu, Yu Mao, Adnan Ozden, Chundong Wang, Bao Yu Xia, Xiaobing Hu, Vinayak P. Dravid, Yun-Mui Yiu, Tsun-Kong Sham, Ziyun Wang, David Sinton, Liqiang Mai, Edward H. Sargent, Yuanjie Pang
Summary: The carbon dioxide and carbon monoxide electroreduction reactions are promising pathways for decarbonization of chemical manufacture. By dispersing a low concentration of copper atoms in a host metal, acetate can be selectively synthesized from carbon monoxide. Through catalyst design and reactor engineering, high selectivity and Faradaic efficiency for acetate production have been achieved.
Article
Engineering, Chemical
Yufei Huang, Ding Wei, Ziyi Li, Yu Mao, Yangqiang Huang, Bo Jin, Xiao Luo, Zhiwu Liang
Summary: A novel composite catalyst TiO2/NH2-MIL-125 was used for the photocatalytic conversion of CO2 with CH4 under visible-light irradiation, achieving rapid conversion at room temperature with excellent stability. Various characterization techniques were employed to study the structure, morphology, and photoelectric chemical properties of the photocatalyst, and the relationship between material properties and CO2 conversion catalytic performance was discussed. A possible catalytic mechanism for the photocatalytic conversion of CO2 by NH2-MIL-125@TiO2 hybrid materials was proposed.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Physical
Jianfu Chen, Menglei Jia, Yu Mao, P. Hu, Haifeng Wang
Summary: Multicomponent catalysts are increasingly important in heterogeneous catalysis, but the cooperation mechanism among them is still unclear. This study systematically investigates the diffusion of surface intermediates and the induced activity enhancement in two-component catalytic systems using theoretical deduction and microkinetic simulations. The proposed pseudo-fluctuation method establishes a general analytical framework and explains the influence and origin of intermediate diffusion. The study shows that integrating the advantages of different components can enhance the overall reaction rate, and provides a preliminary strategy for choosing coupled components in the preparation of catalysts.
Article
Engineering, Chemical
Ziyi Li, Jia Xiong, Wei Dong, Yufei Huang, Shuchang Liu, Yangqiang Huang, Yu Mao, Zhiwu Liang, Xiao Luo
Summary: This research aimed to enhance the photocarrier transfer/separation and CO2 adsorption/activation process over amine-functionalized TiO2 nanoparticles/GO (f-TGO). The optimized f-TGO demonstrated good performance in photocatalytic CO2RR under mild conditions, achieving a turnover frequency (TOF) of 40.9 and 19.9 μmol g-1h-1 for CO and CH4, respectively, outperforming most reported TiO2-based catalysts. This study proposes a viable approach to modify the electronic structure of photocatalysts and provides new insight for designing high-performance photocatalysts, focusing particularly on how interfacial carrier transfer affects photoreduction CO2.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Multidisciplinary Sciences
Jiexin Zhu, Jiantao Li, Ruihu Lu, Ruohan Yu, Shiyong Zhao, Chengbo Li, Lei Lv, Lixue Xia, Xingbao Chen, Wenwei Cai, Jiashen Meng, Wei Zhang, Xuelei Pan, Xufeng Hong, Yuhang Dai, Yu Mao, Jiong Li, Liang Zhou, Guanjie He, Quanquan Pang, Yan Zhao, Chuan Xia, Ziyun Wang, Liming Dai, Liqiang Mai
Summary: This study reports a Bi3S2 nanowire-ascorbic acid hybrid catalyst that improves formic acid selectivity, activity, and stability at high voltages. It achieved over 95% faraday efficiency and high current densities for formate formation. The excellent catalytic performance can be attributed to a unique reconstruction mechanism and the stabilizing effect of ascorbic acid. When applied in a solid-state reactor system, the catalyst enabled efficient and continuous production of pure formic acid.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Applied
Yufei Huang, Ding Wei, Ziyi Li, Yu Mao, Yangqiang Huang, Bo Jin, Xiao Luo, Zhiwu Liang
Summary: The synthesis of high value-added chemical products using CO2 and CH4 is a promising technology that can reduce greenhouse gas emissions and alleviate the energy crisis. However, the technology faces challenges such as high energy consumption and strict reaction conditions. In this work, researchers developed carbon-nitrogen based composites and applied them in the process of photocatalytic CH4 reforming, achieving significant improvements in catalytic performance.
JOURNAL OF ENERGY CHEMISTRY
(2023)
Article
Chemistry, Physical
Jia Xiong, Anjia Yang, Qiang Sun, Hongxia Gao, Haiyan Zhang, Yu Mao, Zhiwu Liang
Summary: Large amounts of CO2 emissions have led to global warming and energy crisis. The photocatalytic reduction of CO2 shows great potential in solving these issues. However, there is still a lack of in-depth investigation and analysis on the basic issues of CO2 photocatalytic reduction over pure and modified TiO2 surfaces, such as the transfer of photogenerated electrons, CO2 adsorption configuration, and CO2 activation mechanism.
MOLECULAR CATALYSIS
(2023)
Article
Chemistry, Physical
Zhang-Jun Bai, Yu Mao, Bing-Hao Wang, Lang Chen, Sheng Tian, Biao Hu, You-Ji Li, Chak-Tong Au, Shuang-Feng Yin
Summary: By constructing a 2D/2D heterostructure using g-C3N4 nanosheet and Cs3Bi2Br9, the photocatalytic activity of Cs3Bi2Br9 was enhanced due to efficient charge carrier transfer and increased generation of carbon centered radicals. The optimized 10% Cs3Bi2Br9/g-C3N4 composite exhibited the highest benzaldehyde formation rate under visible light, which was 41.8 and 2.3 times higher than that of g-C3N4 and Cs3Bi2Br9 alone, respectively. The stability of Cs3Bi2Br9 nanosheets and the selectivity for benzaldehyde were improved by reducing surface energy and tuning the reaction pathway, respectively.