期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 18, 页码 5550-5554出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201601126
关键词
alkylation; dimerization; multicomponent reactions; nickel; regioselectivity
资金
- JSPS [25248025]
- MEXT [2204]
- Grants-in-Aid for Scientific Research [16H01150, 25248025] Funding Source: KAKEN
In the presence of a nickel catalyst, 1,3-butadiene undergoes selective dimerization and alkylarylation with alkyl fluorides and aryl Grignard reagents to give 1,6-octadienes with alkyl and aryl groups at the 3- and 8-positions, respectively, by the consecutive formation of three carbon-carbon bonds. The formation of an anionic nickel complex plays an important role in forming C-C bonds with alkyl fluorides.
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