期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 32, 页码 9277-9281出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201602201
关键词
allotropy; graphene; materials science; strained molecules; structure elucidation
资金
- Deutsche Forschungsgemeinschaft [FOR 1282, SPP 1807]
- SLAC National Accelerator Laboratory by the Department of Energy, Office of Basic Energy Sciences, Division of Materials Science and Engineering [DE-AC02-76SF00515]
The fusion of the sp(3)-hybridized parent diamondoid adamantane with the sp(2)-hybridized pyrene results in a hybrid structure with a very large dipole moment which arises from bending the pyrene moiety. Presented herein is the synthesis, study of the electronic and optical properties, as well as the dynamic behavior of this new hydrocarbon.
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