期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 44, 页码 13872-13876出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201608192
关键词
alkynes; cooperative effects; copper; palladium; trimerization
资金
- Singapore National Research Foundation [R-143-000-477-281]
- Ministry of Education of Singapore [R-143-000-613-112]
- National University of Singapore [R-143-000-605-112]
Presented herein is a mild, operationally simple, mix-and-go procedure for the synthesis of acyclic trisubstituted Z-enediynes, from readily available terminal alkynes, in good yields. This method stems from a serendipitous discovery, and makes use of cooperative palladium/copper bimetallic catalysis and air as an oxidant to effect an intriguing alkyne trimerization to yield the valuable Z-enediyne moiety.
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