期刊
ANALYTICAL METHODS
卷 8, 期 29, 页码 5789-5793出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ay01121g
关键词
-
资金
- team project of State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, China [2015ZD01]
- Natural Science Foundation of China [21576105]
This work reports a simple and efficient method for the determination of the acid value in edible oils by solvent-assisted and reaction-based headspace gas chromatography (HS-GC). The neutralization reaction between the fatty acids in oils and bicarbonate in an ethanol (80%) aqueous solution was performed in a closed headspace sample vial, from which the carbon dioxide generated from the reaction was detected by HS-GC. It was found that the addition of ethanol can effectively improve the reaction of fatty acids in oils with bicarbonate, conducted at 75 degrees C for 30 min. The results showed that the relative standard deviation (RSD) of the present method in the repeatability test was less than 1.63%, and the limit of quantitation (LOQ) was about 0.039 mg KOH per g. The present method was validated by a standard reference method on a set of oil samples from the market, in which the relative differences of the AV data obtained by these two methods were within 5.52%. The present method is simple, efficient, and accurate, and it is suitable for determining the AV in oils in a wide variety of applications.
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