期刊
ORGANIC LETTERS
卷 21, 期 6, 页码 1588-1592出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00133
关键词
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资金
- PRIME from the Japan Agency for Medical Research and Development, AMED [JP18gm5910018]
- Platform Project for Supporting Drug Discovery and Life Science Research (BINDS) from the Japan Agency for Medical Research and Development, AMED [JP18am0101091]
- JSPS KAKENHI [16H01167, 18H04417, 18H02097]
- JSPS A3 Foresight Program
- Grants-in-Aid for Scientific Research [18H02097, 18H04417, 16H01167] Funding Source: KAKEN
C-Linked carbohydrate structure, in which the cleavable O-glycosidic linkage is replaced by a carbon unit, is a useful tool for functional analyses of glycoconjugates. We describe a synthetic method for alpha-CH2-linked disaccharide structures, such as Glc(1,6)-Glc, by stereoselective radical-coupling C-glycosylation between a conformationally constrained and stable C1-sp(3) hybridized xanthate donor and a carefully designed acceptor.
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