期刊
ORGANIC LETTERS
卷 21, 期 7, 页码 2441-2444出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b00744
关键词
-
资金
- National Natural Science Foundation of China [21520102003]
- Hubei Province Natural Science Foundation of China [2017CFA010]
Considering the ubiquitous C(sp(3))-H and the important value of alkylated heteroarenes, developing a universal method for C(sp(3))-H arylation with heteroarenes is significant. Herein, we proposed a method where Selectfluor can promote the oxidative C(sp(3))-H arylation with heteroarenes without external photocatalysis under visible-light irradiation. By EPR study, the N-F activation of Selectfluor by blue LED irradiation can generate the N radical cation, which is the key step for this conversion.
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