期刊
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
卷 66, 期 4, 页码 345-354出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jccs.201800368
关键词
mechanism; oxidation; oxidative dissolution kinetics; pyrite
资金
- Hunan Provincial Natural Science Foundation of China [2016TP1007]
- National Basic Research Program of China [2014CB643401]
- National Natural Science Foundation of China [51404299]
The mineral pyrite is considered the most common form of the sulfide minerals. Its oxidation is a very important process in nature, which involves in the redox recycling of iron. However, because of the growing need for the industrial production, sulfide oxidation produces more and more acid mine (or rock) drainage. This acid drainage has become a heavy economic and environmental problem. This review describes the oxidation mechanism of pyrite in an aqueous medium, including general oxidation and microbial oxidation, where sulfate, ferrous ion, S-0, polysulfides, iron[III], and some intermediate species are formed. Also included is recent evidence on the electrochemical oxidation determined using the electrochemical method, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), and other techniques. In addition, the factors that influence the oxidation and dissolution rate, and the descriptive approaches for different species are discussed.
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