期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 6, 页码 3328-3339出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b03248
关键词
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Development of a palladium-catalyzed carbonylative Suzuki-Miyaura coupling reaction between 2-iodoglycal partners and diverse aryl- and alkenyl-boronic acids is presented, leading to original 2-ketoglycals. The newly formed carbonyl link could be exploited to access 2-aryl/alkenyl-methylene-alpha-glucopyranoside scaffolds via a three-step sequence including an indium-mediated Ferrier-type reaction.
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