4.7 Article

Oxygen vacancies enhance lithium storage performance in ultralong vanadium pentoxide nanobelt cathodes

期刊

JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 539, 期 -, 页码 118-125

出版社

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2018.12.046

关键词

Vanadium pentoxide; Cathode materials; Oxygen vacancy; Ultralong nanobelts; Lithium ion batteries

资金

  1. National Natural Science Foundation of China [51401114, 51601037, 51701063]
  2. Young Talents Program in University of Hebei Province [BJ2018014]

向作者/读者索取更多资源

Ultralong V2O5 nanobelts have been successfully synthesized by a facile hydrothermal oxidation route. Oxygen vacancies are generated in the V2O5 nanobelts by annealing under N-2 atmosphere at an elevated temperature. The microstructure and chemical composition of the pristine and annealed V2O5 nanobelts are studied by different methods. Compared to the pristine V(2)O(5 )nanobelts, the annealed V2O5 nanobelts sample possesses a higher reversible capacity of 177.8 mAhg(-1) after 50 cycles at a current density of 0.3 Ag-1, corresponding to similar to 0.27% capacity loss per cycle. At a higher current density of 1.2 Ag-1 , the reversible capacity of annealed V2O5 electrode can reach 128.5 mAhg(-1) , which is two times larger than that of pristine V2O5 electrode. Ultralong flexible morphology together with oxygen vacancies in the annealed V2O5 electrode is considered to be responsible for the enhanced lithium storage properties. (C) 2018 Elsevier Inc. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Physical

Lower-voltage plateau Zn-substituted Co3O4 submicron spheres anode for Li-ion half and full batteries

Lizhi Qian, Tingli Yu, Zhiqiang Wei, Bingdong Chang, Guoyong Huang, Zhiyuan Wang, Yanguo Liu, Hongyu Sun, Lu Bai, Wei Huang

Summary: The study focuses on the utilization of Zn-substituted Co3O4 submicron spheres as anodes for LIBs, demonstrating their capability to reduce voltage plateau and improve capacity and rate performance in high-performance energy storage devices.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Nanoscience & Nanotechnology

Plasma-Assisted Microcontact Printing

Bingdong Chang, Ding Zhao, Hongyu Sun

Summary: Plasma-assisted microcontact printing (PA-mu CP) is a novel lithography method that utilizes plasma-deposited fluorocarbon as ink material to transfer patterns from a stamp to substrates via thermal evaporation. The geometry of the patterns can be modified by adjusting stamp designs and contact time, and the transferred fluorocarbon patterns can be used as etch masks for creating microstructures in substrate materials.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Engineering, Electrical & Electronic

Thermal reflow of plasma-polymerized fluorocarbon for nanochannels and particle encapsulation

Bingdong Chang

Summary: Thermal reflow is an important property for thermoplastic polymers, which can be used to achieve surface smoothening and fabricate optical devices. This study explores the thermal reflow behavior of plasma-polymerized fluorocarbon (PPFC) on different substrates, with a focus on the formation of micro-and nanochannels on trench structures. The encapsulation of silicon nanorods by reflowed PPFC demonstrates the potential of PPFC in micro-and nanofluidics and drug delivery. Additionally, due to its chemical stability and biocompatibility, PPFC can be expected to be used in various biological devices.

MICROELECTRONIC ENGINEERING (2022)

Article Nanoscience & Nanotechnology

Mesoporous NiCo2S4 nanoflakes as an efficient and durable electrocatalyst for non-enzymatic detection of cholesterol

Syeda Sughra Rabbani, Amjad Nisar, Amina Zafar, Yanguo Liu, Hongyu Sun, Shafqat Karim, Shafqat Hussain, Atta Ullah Shah, Syed Zahid Hussain, Nasir Mehboob, Yanlong Yu, Mashkoor Ahmad

Summary: Highly reliable and stable mesoporous NiCo2S4 nanoflakes were prepared for efficient detection of cholesterol with outstanding electrocatalytic properties. The nanoflakes exhibited excellent sensitivity, selectivity, and thermal stability, showing potential for cost-effective electrochemical sensors in medical and industrial applications.

NANOTECHNOLOGY (2022)

Article Biotechnology & Applied Microbiology

Fluoride Exposure Suppresses Proliferation and Enhances Endoplasmic Reticulum Stress and Apoptosis Pathways in Hepatocytes by Downregulating Sirtuin-1

Yanlong Yu, Ling Li, Wenfeng Yu, Zhizhong Guan

Summary: This study aimed to explore the function and mechanism of Sirt-1 in fluorine-induced liver injury. The results revealed that fluoride exposure aggravated pathological damage and fibrosis in rat liver tissues, and downregulated Sirt-1 expression. Additionally, fluoride exposure enhanced the endoplasmic reticulum stress (ERS) and apoptotic pathways while inhibiting cell proliferation. These findings suggest that fluoride exposure induces hepatocyte ERS and apoptosis through the downregulation of Sirt-1 expression.

BIOMED RESEARCH INTERNATIONAL (2022)

Article Biochemistry & Molecular Biology

Extract of Ginkgo biloba leaves attenuates neurotoxic damages in rats and SH-SY5Y cells exposed to a high level of fluoride

Jie Xiang, Yan-Lin Ma, Jian Zou, Xiao-Xiao Zeng, Xiao Xiao, Yan-Long Yu, Yang-Ting Dong, Long-Yan Ran, Xiao-Lan Qi, Wei Hong, Yan-Hui Gao, Zhi-Zhong Guan

Summary: This study examined the potential protective effects of Ginkgo biloba extract on neurotoxic damage induced by fluoride exposure in rats and SH-SY5Y cells, as well as the underlying mechanisms. The results showed that Ginkgo biloba extract attenuated the neurotoxic effects of fluoride on rats and cells, possibly by inhibiting PARP-1 and promoting SIRT1.

JOURNAL OF TRACE ELEMENTS IN MEDICINE AND BIOLOGY (2023)

Article Chemistry, Multidisciplinary

Development of MoS2-ZnO heterostructures: an efficient bifunctional catalyst for the detection of glucose and degradation of toxic organic dyes

Farhan Ali, Amina Zafar, Amjad Nisar, Yanguo Liu, Shafqat Karim, Faisal Faiz, Zainab Zafar, Hongyu Sun, Shafqat Hussain, Yasir Faiz, Tahir Ali, Sofia Javed, Yanlong Yu, Mashkoor Ahmad

Summary: To address the health and environmental issues caused by diabetes and pollution, the development of an efficient bifunctional catalyst is urgently needed. In this study, a heterostructured MoS2-ZnO catalyst was synthesized and its electrocatalytic and photocatalytic properties were investigated. The catalyst demonstrated excellent performance in glucose detection and degradation of toxic organic dyes, showing potential for environmental remediation and health issues.

NEW JOURNAL OF CHEMISTRY (2023)

Article Materials Science, Multidisciplinary

High-performance flexible and self-powered perovskite photodetector enabled by interfacial strain engineering

Yu Deng, Wenfang Tai, Qi Zhang, Jun Tang, Jinpeng Li, Kai Wang, Haomiao Yu

Summary: By incorporating an extra hole transport layer (HTL), the strain of the perovskite film can be regulated and improved to achieve high-performance flexible and self-powered photodetectors (FSPPDs), with potential applications in wearable and portable devices.

JOURNAL OF MATERIALS CHEMISTRY C (2023)

Article Materials Science, Ceramics

A facile, time-saving fabrication method of high purity CsPbBr3 films for efficient solar cells

Guoshuai Zhang, Xiaobing Cao, Jinquan Wei, Jinpeng Li

Summary: A facile method is proposed to prepare all-brominated cesium lead bromide perovskite films, by pre-introducing an appropriate amount of cesium bromide in the first step. This method enables the formation of a single phase cesium lead bromide film with full coverage, requiring only one cesium bromide supplementation. The preparation time of cesium lead bromide films is significantly shortened, providing a practical approach for large-scale production.

CERAMICS INTERNATIONAL (2023)

Article Chemistry, Physical

Broad Two-Photon Up-Conversion Photoluminescence Realized by Locally Polarized Heterostructures in 2D Perovskite

Yongchao Xie, Jia Zhang, Haomiao Yu, Jinpeng Li, Kai Wang, Xixiang Zhu

Summary: This paper presents a new approach to achieve broad two-photon up-conversion photoluminescence in organic-inorganic hybrid perovskites by using locally polarized heterostructure two-dimensional perovskites. The study reveals that charge-transfer excitons can be used as an artificial ability for up-conversion light emission and polarization heterostructures play a crucial role in developing the broad two-photon up-conversion light emission.

JOURNAL OF PHYSICAL CHEMISTRY C (2023)

Article Chemistry, Physical

Impact of Bychkov-Rashba Spin Splitting on Dual Emissions for Lead Halide Perovskite Nanowires

Sheng Tao, Lixuan Kan, Yang Li, Xiangpeng Zhang, Yongchao Xie, Jun Tang, Xixiang Zhu, Haomiao Yu, Jinpeng Li, Kai Wang

Summary: The Bychkov-Rashba spin-orbit coupling is found to be crucial for photoinduced photoluminescence with double emissions in one-dimensional lead halide perovskite nanowires. This phenomenon, which occurs at low temperatures, is proven to be governed solely by the Rashba effect through extensive analyses. Understanding the photoluminescence characteristics of perovskite nanowires is of great significance for the development of novel nanophotonic devices.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2023)

Article Chemistry, Multidisciplinary

Interface modification by defect engineering for g-C3N4/LaPO4-x nanorods towards efficient CO2 photoreduction

Sai Yan, Lei Chen, Fangyu Peng, Yuanyuan Fan, Yanlong Yu, Yue Liu, Yaan Cao

Summary: In this study, specific surface defects were introduced at the interface of LaPO4/g-C3N4 composites to enhance their photocatalytic performance. The introduced defects created new energy levels, facilitating the efficient separation of photoinduced electrons and holes, leading to improved activity for CO2 reduction.

NEW JOURNAL OF CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

An amphiphilic polyoxometalate-CNT nanohybrid as a highly efficient enzyme-free electrocatalyst for H2O2 sensing

Eman Gul, Gul Rahman, Yuefeng Wu, Tanveer Hussain Bokhari, Ata Ur Rahman, Amina Zafar, Zohaib Rana, Attaullah Shah, Shafqat Hussain, Khan Maaz, Shafqat Karim, Saqib Javaid, Hongyu Sun, Mashkoor Ahmad, Guolei Xiang, Amjad Nisar

Summary: The rational design of hybrid nanomaterials is crucial for the efficient detection of biomolecules. In this study, polyoxometalate (POM) nanoclusters were assembled on the surface of carbon nanotubes (CNT) using non-covalent interactions, and their electrocatalytic performance for hydrogen peroxide (H2O2) detection was investigated. The POM-CNT modified gold electrode showed outstanding electrocatalytic ability and high selectivity for H2O2 detection, with enhanced sensitivity and stability compared to pristine POM building blocks.

NEW JOURNAL OF CHEMISTRY (2022)

Article Chemistry, Physical

Improved highly efficient Dion-Jacobson type perovskite light-emitting diodes by effective surface polarization architecture

Hanjun Yang, Jun Tang, Liangliang Deng, Zhe Liu, Xia Yang, Zengqi Huang, Haomiao Yu, Kai Wang, Jinpeng Li

Summary: Quasi-2D perovskites show promise for highly stable LEDs. Researchers inhibit defects in Dion-Jacobson-type perovskite LEDs through an excessive-salt-assisted process and antisolvent treatments. Building a bulk junction interface and enhancing surface polarization improve charge carrier injection and recombination in high-performance LED devices.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2022)

Article Chemistry, Physical

Mechanistic exploration of Co doping in optimizing the electrochemical performance of 2H-MoS2/N-doped carbon anode for potassium-ion battery

Panpan Zhang, Xu Wang, Yangyang Yang, Haifeng Yang, Chunsheng Lu, Mingru Su, Yu Zhou, Aichun Dou, Xiaowei Li, Xiaochuan Hou, Yunjian Liu

Summary: In this study, the influence of transition metal doping on the electronic and mechanical properties and electrochemical performance of 2HMoS2/NC was investigated using Cobalt (Co) as an example. Co doping was found to effectively improve the electronic conductivity and active site areas of 2H-MoS2/NC at different positions, optimizing the adsorption and diffusion capability of potassium ions. Furthermore, the study revealed the optimal roles of different types of nitrogen atoms in kinetic adsorption, diffusion, and interfacial stability of potassium ions. These findings provide guidance for the experimental design of high rate 2H-MoS2/NC electrode materials and the optimal design of other functional composite materials.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Addressing the synchronized impact of a novel strontium titanium over copolymerized carbon nitride for proficient solar-driven hydrogen evolution

Zeeshan Ajmal, Mahmood Ul Haq, Shahid Zaman, M. K. Al-Muhanna, Anuj Kumar, Mohammed M. Fadhali, Siwar Ben Hadj Hassine, Muhammas Qasim, K. F. Alshammari, Ghulam Abbas Ashraf, Abdul Qadeer, Adil Murtaza, Sulaiman Al-Sulaimi, Huaqiang Zeng

Summary: This study presents a novel heterojunction structure (SrTiO3/CN-TAL10.0) for enhanced photocatalytic water splitting (PWS). The incorporation of thiophenedicarboxaldehyde (TAL) through copolymerization significantly improves the photocatalytic activity of carbon nitride (CN) while maintaining its photostability performance. The optimized composition allows efficient isolation of photoinduced charge carriers and enhanced charge transport, resulting in a remarkable increase in overall photocatalytic efficiency.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Magnetic-driven Interleukin-4 internalization promotes magnetic nanoparticle morphology and size-dependent macrophage polarization

Angela Arnosa-Prieto, Patricia Diaz-Rodriguez, Manuel A. Gonzalez-Gomez, Pelayo Garcia-Acevedo, Lisandra de Castro-Alves, Yolanda Pineiro, Jose Rivas

Summary: Macrophages can exhibit different phenotypes depending on the microenvironment and the characteristics of magnetic iron oxide nanoparticles (MNPs). This study demonstrates that the concentration and morphology of MNPs can influence the polarization of macrophages. The findings have implications for therapeutics targeting tissue regeneration and tumor progression.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Polyamide nanofiltration membranes by vacuum-assisted interfacial polymerization: Broad universality of Substrate, wide window of monomer concentration and high reproducibility of performance

Yu Fang, Cheng-Ye Zhu, Hao-Cheng Yang, Chao Zhang, Zhi-Kang Xu

Summary: This study demonstrates the advantages of vacuum-assisted interfacial polymerization (VAIP) in fabricating polyimide nanofiltration membranes. By using vacuum filtration, aqueous solutions of PIP can be evenly distributed on different microfiltration substrates, leading to the fabrication of uniform and ultra-thin polyamide layers with excellent performance. The membranes exhibit high rejection rates and water permeance, as well as satisfactory long-term stability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Comparing polymer-surfactant complexes to polyelectrolytes

Isaac J. Gresham, Edwin C. Johnson, Hayden Robertson, Joshua D. Willott, Grant B. Webber, Erica J. Wanless, Andrew R. J. Nelson, Stuart W. Prescott

Summary: Understanding the interactions between polymers and surfactants is crucial for optimizing commercial systems. This study tested the behavior of polymer-surfactant systems, revealing that they do not behave like polyelectrolytes in the presence of salt. Additionally, the structure of polymer-surfactant complexes under confinement differs from that of polyelectrolytes.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Crosslinking alginate at water-in-water Pickering emulsions interface to control the interface structure and enhance the stress resistance of the encapsulated probiotics

Yunxiao Xie, Cui Liu, Jie Zhang, Yan Li, Bin Li, Shilin Liu

Summary: This study aimed to improve the microstructure and rheological properties of W/W Pickering emulsions by crosslinking sodium alginate at the water-water interface, thereby enhancing the activity of encapsulated probiotics in simulated gastrointestinal digestion.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Multi-layering of carbon conductivity enhancers for boosting rapid recharging performance of high mass loading lithium ion battery electrodes

Sang Ho Lee, Yige Sun, Patrick S. Grant

Summary: This research developed an effective approach to enhance the charging rates of lithium ion batteries (LIBs) by strategically incorporating carbon nanotube (CNT) conductivity boosters into Li4Ti5O12 (LTO) electrodes. Multi-layer architectures comprising CNT-rich and CNT-free LTO electrode layers were manufactured using a layer-by-layer spray coating method to promote charge transfer kinetics of high mass loading electrodes. The best performing multi-layer was paired with a spray-coated LiFePO4 (LFP) positive electrode, resulting in attractive power performance that outperformed conventional LTO || LFP combinations.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Defect engineering induces Mo-regulated Co9Se8/FeNiSe heterostructures with selenium vacancy for enhanced electrocatalytic overall water splitting in alkaline

Jingwei Liang, Shaobin Li, Fengbo Li, Li Zhang, Yufeng Jiang, Huiyuan Ma, Kun Cheng, Liang Qing

Summary: A molybdenum-regulated self-supporting electrode material with rich vacancy defects has been successfully synthesized and shows exceptional catalytic activities and stability for electrocatalytic overall water splitting. This study provides a new perspective for the design and synthesis of non-precious metal bifunctional electrocatalysts.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Surfactant-free microemulsions (SFMEs) as a template for porous polymer synthesis

Jonas Blahnik, Jennifer Schuster, Rainer Mueller, Eva Mueller, Werner Kunz

Summary: This study investigates the relationship between the morphology of PMMA monopolymers and PMMA-PHEMA copolymers with the expected nature of surfactant-free microemulsions (SFMEs) before polymerization. It is found that previously mesostructured, surfactant-free mixtures can produce porous polymers of different morphologies, while unstructured, oil-rich regions lead to solid, transparent polymers without nanostructured morphologies. Additionally, a surfactant-based reference system shows similar phase behavior and polymer morphologies as the comparable surfactant-free system, indicating the importance of the hydrotropic behavior of HEMA in this system.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Morphology regulation of isomeric covalent organic frameworks for high selective light scattering detection of lead

Zheng-Fen Pu, Wen-Zhi She, Rong Sheng Li, Qiu-Lin Wen, Bi-Chao Wu, Chun-Hua Li, Jian Ling, Qiue Cao

Summary: This study synthesized two framework-isomeric covalent organic frameworks (COFs) and discovered that the light scattering signal of COFs can be used for the analytical detection of lead ions. By controlling synthesis conditions and introducing regulators, the morphology of COFs could be controlled and framework-isomeric COFs could be precisely synthesized.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Preparation and dynamic color-changing study of fluorescent polymer nanoparticles for individualized and customized anti-counterfeiting application

Yuchen Weng, Ying Hong, Jingyu Deng, Sicheng Cao, Li-Juan Fan

Summary: This paper reports the preparation of dynamic color-changing fluorescent polymer nanoparticles (PNPs) by constructing a fluorescence resonance energy transfer (FRET) pair. The PNPs show excellent anti-counterfeiting effects and reproducibility. The study demonstrates a promising encryption strategy that can achieve multiple outputs with simple operation.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Employing polyaniline/viologen complementarity to enhance coloration and charge dissipation in multicolor electrochromic display with wide modulation range

Guodong Liu, Zijian Wang, Jianing Wang, Hanbin Liu, Zhijian Li

Summary: This study investigates the combination of multicolor switchable polyaniline (PANI) electrode and 1-methyl-4,4'-bipyridyl iodide (MBI), which demonstrates superior optical properties in visible and near-infrared light modulation, as well as excellent electrochemical performances. This combination can be used to develop novel electrochromic devices for applications in smart packaging, smart labels, and flexible smart windows.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Facile constructing Ti3C2Tx/TiO2@C heterostructures for excellent microwave absorption properties

Huying Yan, Yang Guo, Xingzhi Bai, Jiawei Qi, Haipeng Lu

Summary: By modifying Ti3C2Tx through heterogeneous interface engineering, optimized impedance matching is achieved, leading to enhanced electromagnetic wave absorption performance.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Reversible crowdedness of pH-responsive and host-guest active polymersomes: Mimicking μm-sized cell structures

Kehu Zhang, Yang Zhou, Silvia Moreno, Simona Schwarz, Susanne Boye, Brigitte Voit, Dietmar Appelhans

Summary: This article presents an advanced crosslinking strategy to fabricate clustered polymersomes using host-guest interactions. By controlling the input of crosslinker and environmental conditions, reversible aggregation and disassembly of these polymersomes can be achieved. The size and structure of these clustered polymersomes can be regulated and visualized through a fluorescent enzymatic cascade reaction.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Potassium regulating electronic state of zirconia supported palladium catalyst and hydrogen spillover for improved acetylene hydrogenation

Junjie Xu, Weixiong Huang, Ruiling Li, Li Li, Jinjin Ma, Jiaou Qi, Haiyan Ma, Min Ruan, Lilin Lu

Summary: In this study, a potassium doped palladium catalyst was developed for acetylene hydrogenation, showing excellent catalytic performance and durability. The doping of potassium effectively weakened the adsorption of ethylene, improved ethylene selectivity, and lowered the barriers of hydrogen activation and transfer reactions.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)