期刊
HYDROMETALLURGY
卷 184, 期 -, 页码 132-139出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.hydromet.2018.11.013
关键词
Crystal nucleus; Cr-Fe coprecipitation; Maghemite fine particles; Magnetic sedimentation; Two-stage coprecipitation
资金
- Sublimation Scholar's Distinguished Professor of Central South University
- Innovation Driven Plan of Central South University [2015CX005]
- National 111 Project [B14034]
- Collaborative Innovation Center for Clean and Efficient utilization of Strategic Metal Mineral Resource
The separation of Cr(III) from the polymetallic leaching solution is a typical problem encountered during the recycling of electroplating sludge. In this paper, a novel method was proposed to recover Cr(III) and Fe(II) synchronously by forming the Cr(III)-Fe(III) coprecipitates on the surface of maghemite (gamma-Fe2O3) fine particles with Fe-2(SO4)(3) solution as the supplemental Fe source. The results showed that high Fe(III) to Cr(III) ratio in solution promoted the hydrolysis and precipitation of Cr(Ill). In addition, the maghemite particles, served as the crystal nuclei, could induce the formation of the core-shell structured Cr(III)-Fe(III) coprecipitates on its surface and accelerate the sedimentation of the coprecipitates in the magnetic field. By using a two-stage Cr(III)-Fe(III) coprecipitation process, the recoveries of Cr and Fe reached 96.17% and 99.39%, and the grades of Ni, Cu, and Zn in the coprecipitates were at 0.41%, 0.38%, and 0.22%, respectively. The obtained coprecipitates can be recycled as the feed material of chromium smelting after heat treatment. This method is simple and efficient for high-concentration Cr3+ solution treatment, which is beneficial for the sustainable development of resources and environment.
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