4.7 Article

Development of nanostructured nickel reinforced polyacrylamide via frontal polymerization for a reliable room temperature humidity sensor

期刊

EUROPEAN POLYMER JOURNAL
卷 112, 期 -, 页码 161-169

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2018.12.032

关键词

Metallopolymer; Polyacrylamide; Humidity sensor; Impedance; Transmission

资金

  1. UGC
  2. INSPIRE AORC fellowship, DST, India [DST/INSPIRE Fellowship/2014/IF140317]

向作者/读者索取更多资源

The present paper reports the polymer matrix of Ni(NO3)(2)(AAm)(4)center dot 2H(2)O thin film as an electrical and optoelectronic humidity sensor. For this purpose, films were prepared by spin-coating method to investigate the adsorption/desorption of humidity at room ambient. The sensing element was investigated through X-ray diffraction (XRD), Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM) and UV-Vis absorption techniques. XRD exhibited the crystalline nature of the nanomaterial thin film and evaluated average crystallite size was 30 nm. SEM showed highly porous nanostructures of different size distributed throughout the film. Energy band-gap of the film was estimated as 4.034 eV. TEM image showed the nanostructures with the average grain size of 4-21 nm and SAED confirmed the crystalline nature of the material. The film was further employed for two different modes of humidity sensing i.e., impedance-based electrical humidity measurement and transmission based opto-electronic humidity measurement which gave a maximum average sensitivity of 37.79 M Omega/%RH and 1.31 mu W/%RH respectively at room temperature.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Biochemistry & Molecular Biology

Functionalized Magnetite Nanoparticles: Characterization, Bioeffects, and Role of Reactive Oxygen Species in Unicellular and Enzymatic Systems

Arina G. Kicheeva, Ekaterina S. Sushko, Lyubov S. Bondarenko, Kamila A. Kydralieva, Denis A. Pankratov, Nataliya S. Tropskaya, Artur A. Dzeranov, Gulzhian I. Dzhardimalieva, Mauro Zarrelli, Nadezhda S. Kudryasheva

Summary: The current study investigates the role of reactive oxygen species (ROS) in the bioeffects of different types of magnetite nanoparticles (MNPs) - bare (Fe3O4), humic acids (Fe3O4-Ha), and 3-aminopropyltriethoxysilane (Fe3O4-APTES) modified MNPs. The study found that Fe3O4-HA MNPs had the lowest amount of Fe2+ ions, while Fe3O4-APTES MNPs had the highest amount of Fe2+ ions. Bioluminescent cellular and enzymatic assays were used to monitor the toxicity and antioxidant activity of the MNPs. The results showed that the modified MNPs had toxic effects at higher concentrations (>10(-2) g/L) and stimulated ROS production by bacteria in a wide concentration range (10(-15)-1 g/L).

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2023)

Article Chemistry, Analytical

Gigantic enhancement in response of heterostructured CeO2/CdS nanospheres based self-powered CO2 gas sensor: A comparative study

Ajeet Singh, Shakti Singh, B. C. Yadav

Summary: A self-powered carbon dioxide (CO2) gas sensor based on CeO2/CdS triboelectric nanogenerator (TENG) was developed, which exhibited good sensitivity and selectivity. The resistive type and self-powered CO2 gas sensing performance of CeO2, CdS, and CeO2/CdS nanomaterials were compared. CeO2/CdS heterostructure was confirmed to form a type II heterojunction through XPS analysis. The CeO2/CdS showed a regular nanosphere morphology with a size range of 30-60 nm. The resistive type CO2 gas sensor achieved a sensor response of 3.96 at 1000 ppm CO2, while the self-powered CO2 gas sensor achieved a response of 30 at the same concentration. The minimum response and recovery times for 250 ppm CO2 were found to be 1835 and 835 ms, respectively. The self-powered CeO2/CdS TENG-based CO2 sensor demonstrated high sensitivity, selectivity, and quick responsiveness.

SENSORS AND ACTUATORS B-CHEMICAL (2023)

Article Materials Science, Multidisciplinary

Novel 3D Lightweight Carbon Foam for Ultrasensitive Humidity Sensor Operated at Different Frequencies

Anushi Sharma, Priyanka Chaudhary, Arpit Verma, Ravi Kant Tripathi, Rajeev Kumar, Gaurav Gupta, D. P. Mondal, B. C. Yadav, A. K. Srivastava

Summary: Lightweight porous carbon materials have gained significant attention in gas and humidity sensing due to their excellent properties. Carbon foam with a low density of 0.28 g cm(-3) and an electrical conductivity of 32 S cm(-1) was synthesized from phenolic resin using the polyurethane foam impregnation method. The carbon foam-based humidity sensor demonstrated good sensitivity (8.260 M/%RH) at 40 Hz and fast response and recovery times (6 s and 49 s, respectively). It also displayed high repeatability (94%) and stability.

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY (2023)

Article Energy & Fuels

Combustion-Synthesized KNiPO4: A Non-toxic, Robust, Intercalating Battery-Type Pseudocapacitive Electrode for Hybrid Supercapacitors as a Large-Scale Energy Storage Solution

Mahatim Singh, Saurabh Kumar, Rakesh Mondal, Preetam Singh, Rajiv Prakash, Neeraj Sharma

Summary: A novel electrode material consisting of polyanionic-type (PO4)n- polyhedral covalently bonded with Ni-O linkage is proposed for intercalative battery-type hybrid supercapacitors. A highly porous, flake-type KNiPO4 electrode exhibits robust electrochemical performances due to its open framework structure and active participation of the Ni2+/3+ redox couple, allowing for superior pseudocapacitive intercalating charge storage in aqueous KOH electrolyte. In full cell hybrid supercapacitor mode, the KNiPO4 electrode demonstrated high energy density and power density, as well as excellent cyclic stability, making it suitable for various applications including biomedical devices and bulk, grid-level charge storage.

ENERGY & FUELS (2023)

Article Energy & Fuels

Investigation of the Synergistic Effect in Polypyrrole/Ni-Doped NASICON Composites for an Enhanced Hydrogen Evolution Reaction

Ajay Kumar, Saurabh Kumar, Subhajit Jana, Rajiv Prakash

Summary: A nanocomposite of polypyrrole and Ni-doped NASICON-structured Na3NixFe(2-x)(PO4)(SO4)2 has been synthesized using a simple chemical oxidative polymerization method, exhibiting remarkable hydrogen evolution reaction activity. The nanocomposite shows comparable catalytic performance to polymer-based catalysts and offers high current density at lower overpotential, along with exceptional environmental and catalytic stability.

ENERGY & FUELS (2023)

Article Engineering, Electrical & Electronic

Low Voltage Operable Eco-Friendly Water-Induced LiOx Dielectric Based Organic Field Effect Transistor

Prashant Kumar, Vishwambahar Nath Mishra, Rajiv Prakash

Summary: This study reports water-induced Lithium oxide (LiOx) based Organic field effect transistors with operating voltage under -2 V, which utilize the floating film transfer method and a self-assembled poly [2,5-(2-octyldodecyl)-3,6-diketopyrrolopyrrole-alt-5,5-(2,5-di(thien-2-yl)thieno [3,2-b]-thiophene)] (DPP-DTT) semiconducting layer. The devices exhibit good performance, including high saturation mobility, low threshold voltage, and low subthreshold swing. The synthesis process is low cost and eco-friendly, using deionized water as the precursor solution of lithium oxide without toxic additives. The LiOx based dielectric also shows good characteristics, such as low leakage current and high capacitance.

IEEE ELECTRON DEVICE LETTERS (2023)

Article Engineering, Electrical & Electronic

Highly Sensitive and Selective Room Temperature-Operated NO2 Sensor Based on Eco-Friendly Water Processed Low Voltage Operable OFET

Prashant Kuamr, Vishwambhar Nath Mishra, Rajiv Prakash

Summary: We have developed a highly sensitive and selective room temperature operated NO2 gas sensor based on DPP-DTT OFETs. By using water-induced AlOx as the gate dielectric and FTM with water as a liquid substrate, we achieved a response of 2217.4% for 200 ppb and 8445.5% for 1.4 ppm of NO2. The sensor also showed a response and recovery time of 34 and 168 s for 1.4 ppm NO2, with a maximum temperature during fabrication process below 260 degrees C. Selectivity study with other gases confirmed the high selectivity of the sensor for NO2.

IEEE SENSORS JOURNAL (2023)

Article Energy & Fuels

Improved Supercapacitor Performance with Enhanced Interlayer Spacing of Nanoflower MoS2 in Long Discharge Time in LED-Glowing Application

Jitesh Pani, Devkaran Maru, Priyanka Chaudhary, Jitendra Gangwar, Kanapuram Uday Kumar, Bal Chandra Yadav, Hitesh Borkar

Summary: In this study, MoS2 nanostructures with improved interlayer spacing were synthesized through different reaction times. The synthesized MoS2 structures exhibited 3D flower-like and ultrathin 2D sheet-like morphologies. The enhanced interlayer spacing in the nanostructures was confirmed through various analytical techniques. The MoS2 nanoflower demonstrated excellent physicochemical properties and showed high specific capacitance and cyclic stability.

ENERGY TECHNOLOGY (2023)

Article Nanoscience & Nanotechnology

2D/2D Nanostructured System Based on WO3/WS2 for Acetone Sensor and Breath Analyzer

Arpit Verma, Bal Chandra Yadav

Summary: The aim of this research is to evaluate the acetone-sensing performance of the heterostructured nanohybrid of WO3/WS2 using a rapid chemiresistive sensor. The results show the formation of a 2D/2D nanosheet-like system of the WO3/WS2 heterostructure, and the sensor responds to acetone concentrations of 1000 and 1 ppm with values of 132.5 and 17.0, respectively. Therefore, this sensor device has potential applications in biomedical and industrial-scale utilization. Rating: 8 out of 10.

ACS APPLIED NANO MATERIALS (2023)

Article Engineering, Electrical & Electronic

A Self-Assembled Polymer Nanocomposite-Based Low-Voltage White Light Phototransistor With UV-Cured Synthesized LaZrOx Dielectric

Ankit Verma, Dharmendra Kumar, V. N. Mishra, Rajiv Prakash

Summary: A low-cost floating film transfer method was used to fabricate a gold-doped poly(3-hexylthiophene-2,5diyl) (P3HT)-based low-voltage organic thin-film transistor (OTFT) for white light sensing. The fabrication process involved solution-processed spin casting for high-k dielectric growth and a floating film transfer method for metal nanoparticle-doped organic semiconductor growth. The resulting OTFT showed high crystallinity, self-assembly, and cost-efficiency compared to conventional film deposition techniques. The device exhibited high photosensitivity, photoresponsivity, and detectivity, as well as low response/recovery time, making it suitable for white light sensing applications.

IEEE TRANSACTIONS ON ELECTRON DEVICES (2023)

Article Engineering, Electrical & Electronic

Ultralow-Voltage Eco-Friendly Water-Induced LiOx/AlOx Bilayer Dielectric-Based OFET

Prashant Kumar, Vishwambhar Nath Mishra, Rajiv Prakash

Summary: This article presents ultralow-voltage operable organic field effect transistors (OFETs) using a bilayer dielectric made of lithium oxide (LiOx) and aluminum oxide (AlOx). The use of water instead of toxic organic solvents for processing the dielectrics is demonstrated. A donor acceptor-based p-type polymer, poly[2,5-(2-octyldodecyl)-3, 6-diketopyrrolopyrrole-alt-5,5-(2,5di(thien-2-yl)thieno [3,2-b] -thiophene)] (DPP-DTT), is employed as the organic semiconducting layer. The OFET device shows good performance with a high ON/OFF ratio and operability under -1 V.

IEEE TRANSACTIONS ON ELECTRON DEVICES (2023)

Article Energy & Fuels

Economic and environment friendly carbon decorated electrode for efficient energy storage devices

Nirbhay Singh, Shweta Tanwar, A. L. Sharma, B. C. Yadav

Summary: Supercapacitors are the most dependent storage technologies, offering faster energy supply, sustainability, and high-capacity retaining. This research focuses on the development of a sustainable activated carbon-based iron oxyhydroxide material prepared via a low-temperature hydrothermal technique. The material exhibits excellent cyclic stability, elemental composition, and electrochemical performance.

JOURNAL OF ENERGY STORAGE (2023)

Article Engineering, Electrical & Electronic

Photomultiplicative and High External Quantum Efficient Energy Conversion Device for Paper Electronics

Arpit Verma, Priyanka Chaudhary, Anshika Singh, Ravi Kant Tripathi, Bal Chandra Yadav, Pratima Chauhan

Summary: This research presents an innovative paper electronics device with Bi2S3 nanorods integrated into a polyaniline matrix, aiming to achieve high external quantum efficiency for energy conversion. The device shows a large photoresponsivity and high external quantum efficiency at low drift potential and small optical power. It also exhibits notable responsiveness under flexibility without the use of any binder.

ACS APPLIED ELECTRONIC MATERIALS (2023)

Article Chemistry, Physical

Temperature Dependence of Direct Current Conductivity in TiO2/Epoxy Polymer Dielectric Nanocomposites

E. V. Rabenok, G. F. Novikov, L. M. Bogdanova, Yu. S. Bukichev, G. I. Dzhardimalieva

Summary: A study is conducted on how TiO2 nanoparticles affect the temperature dependence of the direct current conductivity in epoxy polymers. The value of the conductivity is determined by analyzing the frequency dependence of the complex permittivity in a specific range of frequencies. The temperature dependence of the conductivity shows two distinctive regions: the Vogel-Fulcher-Tammann dependence above the glass transition temperature, and the Arrhenius dependence below it, indicating a change in conduction mechanism after the freezing of ionic mobility.

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A (2023)

Article Materials Science, Multidisciplinary

Photocurrent conversion capability of a 2D WS2-polyvinyl alcohol matrix and its DFT-based charge carrier dynamics analysis

Arpit Verma, Anshika Singh, Priyanka Chaudhary, Ravi Kant Tripathi, B. C. Yadav, Pratima Chauhan, Devesh Kumar

Summary: In this research, we investigated the photodetection mechanism of WS2 nanosheets embedded in a polyvinyl alcohol matrix. The nanosheets were synthesized and embedded in the matrix using a solution method. The SEM micrographs confirmed the successful incorporation of WS2 nanosheets in the matrix. XRD results revealed the crystal structure of the nanosheets, while a Tauc plot showed the optical band gap energy. The zeta potentials and photodetection measurements were also analyzed.

MATERIALS ADVANCES (2023)

Article Polymer Science

Addressable and stable physically unclonable functions based on cross-linked poly(2-vinylpyridine)

Mustafa Kalay, Abidin Esidir, Mahmut Ruzi, N. Burak Kiremitler, Mustafa Serdar Onses

Summary: This study proposes stable and addressable polymer PUFs, utilizing a cross-linkable polymer system, which demonstrates high stochastic characteristics and low-cost production. The performance of the polymer features is evaluated through various analyses, and direct image authentication is achieved using feature matching algorithms.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Low migration and high performance thioxanthone based photoinitiators

Jingyu Jin, Guoqiang Lu, Jun Nie, Xiaoqun Zhu

Summary: Photopolymerization technology is limited in the fields of food packaging and biomedicine due to the high migration of small molecules from photoinitiators. In this study, a polymerizable 2-vinyl thioxanthone (ETX) was synthesized to improve the migration stability of photoinitiators. Macromolecular photoinitiators (PPI1, PPI2) were also prepared to further reduce migration. The results showed that the ETX/TEOA system had higher initiation performance and PPI2 displayed favorable initiation ability. Additionally, the migration of ETX, PPI1, and PPI2 in photocured film was significantly reduced. These low-migration photoinitiators have potential applications in the fields of food packaging and biological materials.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Photoinitiators with low migration capability based on benzophenone

Weijie Li, Jun Nie, Yingying Zhao, Xiaoqun Zhu

Summary: This study focuses on the development of high-performance, low-migration photoinitiators. A polymerizable photoinitiator (VBP) was synthesized by introducing an ethylene group into benzophenone, and three different molecular weight single-component photoinitiators (PVBN1-3) were synthesized based on VBP. The results show that these new photoinitiators have stronger absorption ability compared to benzophenone and significantly reduce the migration of initiators and co-initiators, addressing the safety concerns caused by migration.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Covalent Introduction of Plasma-Treated carbon nanotubes into polyimide nanocomposites at Ultra-Low content

Seira Morimune-Moriya, Yuki Iwahashi, Mitsuru Nakamura, Daisuke Ogawa, Keiji Nakamura

Summary: This study investigates the effect of plasma treatment on carbon nanotubes (CNTs) and the structure/properties of polyimide (PI) nanocomposites with ultra-low content of CNTs. The results show that plasma treatment introduces isocyanate groups on the surface of CNTs and enhances the interfacial interaction between PI and treated CNTs. This leads to a significant improvement in the mechanical properties of the nanocomposites, with even a small addition of treated CNTs showing a substantial increase in Young's modulus, tensile strength and toughness.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Hydroxyethyl cellulose-based stretchable, antifreeze, ion-conductive hydrogel sensor

Yuanlong Li, Chaojie Chen, Guoqing Cui, Li Liu, Chao Zhou, Guangfeng Wu

Summary: In this study, a novel ion-conducting hydrogel was fabricated using a straightforward approach. The hydrogel showed excellent tensile properties and high toughness due to physical interactions and covalent binding. Additionally, the introduction of hydroxyethyl cellulose and lithium chloride improved the biocompatibility, mechanical properties, electrical conductivity, and frost resistance of the hydrogel, demonstrating its potential for cold climate applications.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

How does the precursor backbone length affect the grafting efficiency and kinetics for bottlebrush polystyrenes prepared by graft-onto Strategy?

Dengwei Yan, Jinxian Yang, Xuejun Pan, Xiaozheng Duan, Lianwei Li, Mo Zhu

Summary: The influence of backbone length on grafting efficiency during the graft-onto reaction process was investigated. It was found that the polydispersity effect of backbone length does not affect the final grafting efficiency, indicating that the local dynamics of chain segments dominate the graft-onto process.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Catalyst-free epoxy vitrimers from rosin: Highly mechanical performance, fast self-healing, and facile recycling

Zhaoyi Luo, Xianjie Pan, Fanqi Liu, Quanxi Yi, Yanning Zeng, Yunhua Chen, Chaoyang Wang

Summary: This study provides a method to prepare high-performance epoxy materials with good malleability and thermal stability. The materials have self-healing and welding capabilities, thanks to the addition of specific chemical bonds and network structures. They exhibit mechanical properties comparable to commercial epoxy resins and show great potential for sustainable industrial development.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Novel triazine-based sulfur-containing polyamides: Preparation, adsorption efficiency and mechanism for mercury ions

Chaoji Xiong, Hao Wang, Lihua Deng, Kun Liang, Chunhua Wu, Wei Wu, Qian Chen

Summary: In this study, four polyamides were synthesized and their adsorption performances for Hg2+ in aqueous systems were investigated. The polyamides exhibited high adsorption capacities and excellent reusability, with the involvement of sulfur, nitrogen, and oxygen in the chemical adsorption process of Hg2+.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Combining isosorbide and lignin-related benzoic acids for high-Tg polymethacrylates

Siim Laanesoo, Olivier Bonjour, Rauno Sedrik, Iris Tamsalu, Patric Jannasch, Lauri Vares

Summary: The insertion of rigid aliphatic or aromatic building blocks in polymer structures is an effective way to synthesize high -Tg polymer materials. In this study, a series of isosorbide-2-aryl carboxylate-5-methacrylate monomers (ArIMAs) were synthesized by functionalizing isosorbide 5-methacrylate with various aromatic lignin-inspired esters. These monomers were polymerized to obtain high molecular-weight poly(aryl carboxylate isosorbide methacrylates) (PArIMAs). The resulting polymers showed high glass transition temperatures and thermal stability, making them suitable for use as high-performance plastics and coatings.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Influence of tannic acid post-treatment on the degradation and drug release behavior of Schiff base crosslinked konjac glucomannan/chitosan hydrogel

Yuqian Wu, Weijie Xu, Jianliang Li, Zhangfeng Zhong, Liqing Huang, Shengke Li, Huaping Tan

Summary: This study investigates the improvement of degradation and drug release characteristics of dynamic Schiff base-mediated natural polysaccharide hydrogels using tannic acid (TA), leading to enhanced stability and functionality.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Antimicrobial and anti-freezing conductive hydrogels driven by quaternary ammonium chitosan salt for flexible strain sensors

Xi Zhang, Xiangli Kong, Xin Zhou, Yiyan Gao, Yibo Sun, Guanghui Gao, Wei Liu, Kai Shi

Summary: Conductive hydrogels have great development prospects in flexible strain sensors, but long-term direct contact with human skin can cause bacterial infection. A hydrogel with antibacterial, biocompatibility, and toughness was designed and manufactured using a freeze-thaw method. The hydrogel maintains tensile properties and fatigue resistance at low temperatures and is resistant to bacteria. Therefore, hydrogel sensors can be used to monitor human movements.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Polyacrylamide quaternary ammonium salts based on stable adsorption in soil and its application on the control of soil-borne fungal disease

Wei Zhang, Jiangang Yu, Mingyang Wu, Rui Li, Anqiang Zhang, Yaling Lin

Summary: In this study, polyacrylamide containing quaternary ammonium salts (PAM-X) were synthesized and found to effectively inhibit soil-borne pathogenic fungi while maintaining the balance of microbial population in soil. PAM-X also showed low toxicity to earthworms and fish, providing a new method for the prevention and control of soil-borne fungal diseases.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Hygroscopic photothermal sorbents for atmospheric water harvesting: From preparation to applications

Jiawen He, Haojie Yu, Li Wang, Jian Yang, Yanhui Zhang, Wenbing Huang, Chenguang Ouyang

Summary: This review discusses the use of polymeric hydrogels for atmospheric water harvesting (AWH), including the mechanism of water sorption, fabrication methods, and strategies for optimizing the structure of hydrogels. The extended applications of hygroscopic photothermal hydrogels, such as agricultural irrigation and dehumidification, are also explored. The challenges and prospects of using polymeric hydrogels for AWH are summarized.

EUROPEAN POLYMER JOURNAL (2024)

Article Polymer Science

Plant-Inspired conductive hydrogels with long-lasting stability and low temperature tolerance for flexible sensors and signal transmission carriers

Ying Du, Shuaishuai Lu, Yuanna Sun, Qingshan Li, Xinhai He

Summary: This study introduces a method to improve the performance of hydrogels by incorporating proline, resulting in hydrogels with excellent stretchability, high conductivity, and long-term stability. The hydrogel remains flexible and conductive even at ultra-low temperatures.

EUROPEAN POLYMER JOURNAL (2024)