期刊
CHEMCATCHEM
卷 11, 期 16, 页码 3952-3958出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201900311
关键词
core-shell; salen; porous organic polymer; CNTs; epoxide hydration
资金
- National Key R&D Program of China [2017YFB0702800]
- National Natural Science Foundation of China [21733009, 21621063]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB17020200]
Microporous polymers have been considered as promising heterogeneous catalysts for versatile chemical transformations. However, the mass diffusion barriers through the microporous network still remains a big hindrance. Herein, an efficient and versatile strategy for shortening the mass diffusion pathway through microporous polymer was reported by constructing a CNTs@POP-salen core-shell nanostructure. CNTs@POP-Co(salen) could efficiently catalyze the epoxide hydration reaction at H2O/epoxides ratio as low as 2, demonstrating the efficient cooperation of Co(salen) integrated in the polymer network. CNTs@POP-Co(salen) showed much higher activity than bulk polymer in propylene oxide (PO) hydration reaction (TOF: 3150 versus 1470 h(-1)) due to the shortened diffusion pathway, which was further confirmed by adsorption experiment using phenol as probe molecule. Our primary results demonstrated the advantages of core-shell nanostructures to improve the catalytic activity of microporous polymers by enhancing the mass diffusion during the catalytic process.
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