4.8 Article

From Fancy Blue to Red: Controlled Production of a Vibrant Color Spectrum of Fluorescent Diamond Particles

期刊

ADVANCED FUNCTIONAL MATERIALS
卷 29, 期 19, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201808362

关键词

diamond particles; nitrogen aggregation; optical centers; photoluminescence; thermal annealing

资金

  1. Milano-Bicocca University Exchange-Extra-UE Program
  2. NHLBI, Department of Health and Human Services [HHSN268201500010C]
  3. National Cancer Institute of the National Institutes of Health [R43CA232901]

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The current study reports a breakthrough method for production of multicolor diamond particulates using a rapid thermal annealing (RTA) approach with precise temperature and time control, enabling annealing of diamond particulates up to 2100 degrees C without extensive graphitization. The RTA method generates conditions which allow formation of one-, two-, and three-atom nitrogen complexes with vacancies in electron irradiated type Ib synthetic diamond, providing vibrant luminescence in the red, green, and blue spectral ranges, correspondingly. Controlled and highly reproducible formation of specific color centers previously not possible in type Ib synthetic diamond particles opens new opportunities for particulate diamond in a plethora of fluorescence imaging applications in biological and industrial fields.

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