Article
Nanoscience & Nanotechnology
Shu-Yi Li, Xin Yan, Jiao Lei, Wen-Juan Ji, Shu-Cong Fan, Peng Zhang, Quan-Guo Zhai
Summary: This study combines the excited-state intramolecular proton transfer (ESIPT) mechanism with pore space partition to construct a fluorescent metal-organic framework (SNNU-301) probe with excellent water stability. The probe demonstrates remarkable performance in detecting trace water in organic solvents, with wide linear ranges, low limit of detection values, and ultrafast response. This work not only provides a promising candidate for fast and sensitive detection of water in organic solvents, but also offers valuable guidance for the design of high-performance fluorescent probes.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Spectroscopy
Aastha Palta, Gulshan Kumar, Vijay Luxami
Summary: A dual hydrogen bonded Schiff base with unsymmetrical double proton transfer sites was synthesized and used as a potential sensor for Al3+ and HSO4- ions. The probe showed intramolecular charge transfer and displayed specific absorption peaks and emission bands. It could detect Al3+ and HSO4- ions in a solvent system and determine their concentrations accurately.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Chemistry, Analytical
Wenhao Pan, Chunhong Zheng, Guanming Liao, Gang Liu, Shouzhi Pu
Summary: A diarylethene derivative with weak excited state intramolecular proton transfer fluorescence properties has been synthesized, which shows high sensitivity for detecting Al3+ in aqueous solutions. The compound exhibits strong orange ESIPT emission in solutions with over 70% water content.
MICROCHEMICAL JOURNAL
(2021)
Article
Chemistry, Inorganic & Nuclear
Xin Yan, Yong-Peng Li, Jiao Lei, Ying Wang, Shu-Ni Li, Quan-Guo Zhai
Summary: The introduction of ESIPT into porous metal-organic frameworks (MOFs) for efficient fluorescence sensing of fluorions was proposed in this study. The novel SNNU-300 probe, with unique continuous ESIPT processes, showed high selectivity and sensitivity for fluoride ion detection, making it a promising fluorion sensor in practical applications.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Pengcheng Huang, Ying Liu, Avishek Karmakar, Qikun Yang, Jing Li, Fang-Ying Wu, Ke-Yu Deng
Summary: By utilizing three different metal cations and an active linker, three luminescent metal-organic frameworks with tunable luminescence properties were obtained. The luminescence behavior of these LMOFs can be further modulated for potential applications in various fields, showcasing their versatility as photoluminescent platforms.
DALTON TRANSACTIONS
(2021)
Article
Nanoscience & Nanotechnology
Zhijian Du, Feng Zhang, Huiming Lin, Wei Guo, Miaomiao Tian, Kai Yu, Dan Gao, Fengyu Qu
Summary: Stimulus-responsive proton conduction materials have attracted interest due to their potential applications in various fields. In this study, a metal-organic framework composite incorporating a proton-conducting molecule was developed, demonstrating a high proton-conducting switch ratio. The composite was further used to form hybrid membranes with improved proton conductivity and switch ratio. The development of such thermal-responsive proton-conducting materials opens up new possibilities for remote control and intelligent device applications.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Atul Shukla, Van Thi Ngoc Mai, Velayudhan V. Divya, Cherumuttathu H. Suresh, Megha Paul, Venugopal Karunakaran, Sarah Katariina Martikainen McGregor, Ilene Allison, K. N. Narayanan Unni, Ayyappanpillai Ajayaghosh, Ebinazar B. Namdas, Shih-Chun Lo
Summary: The zwitterionic ESIPT material HBT-Fl2 exhibits remarkable features such as low ASE threshold, high ASE photostability, and large Stokes shift. It achieves innovative design tactics through charge redistribution in proton transfer.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Atul Shukla, Van Thi Ngoc Mai, Velayudhan V. Divya, Cherumuttathu H. Suresh, Megha Paul, Venugopal Karunakaran, Sarah Katariina Martikainen McGregor, Ilene Allison, K. N. Narayanan Unni, Ayyappanpillai Ajayaghosh, Ebinazar B. Namdas, Shih-Chun Lo
Summary: The study reported the first efficient zwitterionic ESIPT lasing material HBT-Fl2 with low ASE threshold, high ASE photostability, and unique zwitterionic characteristics. DFT and TD-DFT studies revealed the charge redistribution in proton transfer through the fluorene conjugation in HBT-Fl2, providing a design tactic for efficient light amplification in red and longer-wavelength emission.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Applied
Xinjie Guo, Chenyang Wan, Jiajia Li, Yuzhe Xiao, Qilong Cao, Qian Zhang, Peng Zhang, Caifeng Ding
Summary: A non-emissive probe for the detection of cysteine was designed in this study, showing bright green fluorescence with a high quantum yield due to the process of ESIPT induced by intramolecular hydrogen bonding. The probe exhibited excellent selectivity and sensitivity for cysteine detection, making it a valuable tool for monitoring cysteine in biological systems.
Article
Chemistry, Multidisciplinary
Elizabeth M. Santos, Wei Sheng, Rahele Esmatpour Salmani, Setare Tahmasebi Nick, Alireza Ghanbarpour, Hadi Gholami, Chrysoula Vasileiou, James H. Geiger, Babak Borhan
Summary: Fluorescent proteins have great potential in revolutionizing biology, with engineered design strategies allowing for high quantum yield, red-shifted emission, and Large Stokes Shift. This technology shows immense potential for applications in biological research.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Analytical
Xiaowan Han, Xiangchuan Meng, Xiang Wang, Shan Leng, Qian Liu, Leilei Zhang, Pingping Li, Qingyang Zhang, Hai-Yu Hu
Summary: A new excited-state intramolecular proton transfer-delayed fluorescence (ESIPT-DF) approach was reported to construct analyte-stimulated DF probes. These new classes of ESIPT-DF luminophores, including HBT-PXZ and HBT-PTZ, exhibited significant ESIPT and DF characters. Furthermore, a caged probe HBT-PXZ-Ga was developed and applied to investigate the influence of metal ions on beta-gal activity.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Physical
Yan Yu, Xindi Huang, Hang Yin, Yu Feng, Hua Xuan, Haixiang He
Summary: The study investigated the fluorescent mechanism and excited state intramolecular proton transfer processes of HBTHg and HBH. Results showed that the intramolecular hydrogen bond is strengthened in the S1 state, facilitating the ESIPT process, and supporting that the proton transfer is a spontaneous process in the excited state.
CHEMICAL PHYSICS LETTERS
(2021)
Article
Nanoscience & Nanotechnology
Shao-Zhe Yi, Bao-Ning Li, Peng-Yan Fu, Mei Pan, Cheng-Yong Su
Summary: A new method for synthesizing pure organic photoluminescent molecules with dual excited-state intramolecular proton transfer (ESIPT) sites was developed. These molecules can emit full-color light from blue, green, and yellow to red, and even white light, depending on the solvents used. The study verified the dual-ESIPT mechanism through experiments on copper ions' selective photoluminescent response and solid-state photoluminescent changes upon the stimulus of organic vapor. Theoretical analysis further supported the experimental results and provided insights for the design and application of advanced dual-ESIPT optical materials.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Arui Huang, Jie Hu, Mengmeng Han, Kangwei Wang, Jian Long Xia, Jiajia Song, Xuelian Fu, Kai Chang, Xiaocong Deng, Siwei Liu, Qianqian Li, Zhen Li
Summary: This study demonstrated multiple photodeformable processes in anil-poly(ethylene terephthalate) systems utilizing excited-state intramolecular proton transfer and trans-cis isomerization as microscopic molecular motions under light stimulus. The doping films were able to achieve light-driven contraction and bending angle during a simple stretching process. The internal mechanism and relationship between molecular structure and photocontrolled motion were investigated through transient absorption spectra, theoretical calculations, and crystal analysis.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Physical
Min Tao, Yang Li, Quan Huang, Hongmei Zhao, Jingbo Lan, Yan Wan, Zhuoran Kuang, Andong Xia
Summary: This study demonstrates the feasibility of continuously modulating ESIPT dynamics in HPO derivatives by investigating electron population variations on proton donor and acceptor. An index Δpdif was proposed to evaluate the overall promotion effect on proton transfer, showing high reliability in interpreting the ESIPT tendency. This method has great potential in ESIPT molecular design with chemical substitution of electron-donating/withdrawing moieties.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Jia-Wen Wang, Shu-Cong Fan, Hai-Peng Li, Xianhui Bu, Ying-Ying Xue, Quan-Guo Zhai
Summary: A de-linker strategy is proposed to optimize the storage capacity and selectivity of metal-organic frameworks (MOFs) for separation applications. The synthesized ultra-microporous MOFs (SNNU-98-M) exhibit high C2H2 uptake capacity and selectivity, and can efficiently separate C2H2 from C2H2/CO2 and C2H2/C2H4 mixtures.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Jia-Min Huo, Ze-Lin Ma, Ying Wang, Yi-Jia Cao, Yu-Cheng Jiang, Shu-Ni Li, Yu Chen, Man-Cheng Hu, Quan-Guo Zhai
Summary: This work develops a targeted-anchored and subsequent spontaneous-redox strategy to synthesize Pt@LDH, which exhibits significant improvement in electrochemical water splitting performance in alkaline media. In a real device, Pt@LDH can drive an overall water-splitting at low cell voltage, outperforming most reported similar LDH-based catalysts.
Article
Engineering, Environmental
Xiao-Hui Wang, Ze-Nong Zhang, Zhe Wang, Yu Ding, Quan-Guo Zhai, Yu-Cheng Jiang, Shu-Ni Li, Yu Chen
Summary: A handy template-post phosphatization approach is used to prepare ultra-thin CoNi0.2P nanosheets attached to nickel foam, which exhibit high electroactivity for hydrogen evolution reaction and glycol oxidation reaction. This work expands the territory for energy-saving co-generation of hydrogen and value-added chemical products.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Wanrong He, Xiao-Bing Mu, Jiao Lei, Wenyu Yuan, Peng Zhang, Quan-Guo Zhai
Summary: Four novel pillared-layer-like metal-organic frameworks (MOFs) with quadrilateral channels, SNNU-283-286, were synthesized and showed remarkable adsorption capacity, selectivity, and breakthrough interval times for the separation of C2H2/CO2. This work offers new MOFs for efficient C2H2 adsorption and purification.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Multidisciplinary
Jie Meng, Jing Zhang, Shu-Cong Fan, Ying Wang, Peng Zhang, Wenyu Yuan, Quan-Guo Zhai
Summary: Metal-organic frameworks (MOFs) have potential for CO2 capture and conversion, and it is important to control their pore sizes and catalytic sites. A new strategy called cage space partition (CSP) is proposed to regulate the pore sizes of MOFs. The feasibility of CSP is demonstrated in two different MOFs, SNNU-337 and SNNU-338, which show enhanced CO2 adsorption and catalytic performance.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Inorganic & Nuclear
Shu-Yi Li, Kun Wang, Jia-Wen Wang, Shu-Cong Fan, Peng Zhang, Quan-Guo Zhai
Summary: A series of Mg-pacs-MOFs (SNNU-10-n, n = 1-6) with flexible side chains are designed for the first time, achieving systematic pore environmental modification through alkoxy group functionalization and a pore-space partition strategy. The effects of steric hindrance, electron-donating ability, and flexibility of alkoxy groups are found to have significant influence on gas adsorption capacity and selectivity. The methoxy-modified SNNU-10-1 exhibits ideal gas uptake-selectivity balance and can effectively separate gas mixtures under ambient conditions.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Cun Gao, Xiao-Bing Mu, Wen-Yu Yuan, Peng Zhang, Ying Wang, Quan-Guo Zhai
Summary: Designing efficient absorbents for multi-gas adsorption and separation is critical for gas purification in chemical engineering. In this work, two isomorphic metal-organic frameworks (MOFs) with multiple cages were synthesized and demonstrated to have high selectivity and capacity for gas adsorption. The study highlights the potential of multicage engineering for multicomponent gas separation.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Jiao Lei, Wenyu Yuan, Jianxuan Shang, Jie Xu, Peng Zhang, Ying Wang, Yong-Peng Li, Quan-Guo Zhai
Summary: This study demonstrates a mixed multinuclear cluster strategy to synthesize three new heterometallic MOFs with potential applications in methane purification and storage.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Jia-Min Huo, Ying Wang, Jiang-Nan Xue, Wen-Yu Yuan, Quan-Guo Zhai, Man-Cheng Hu, Shu-Ni Li, Yu Chen
Summary: The precise design of low-cost, efficient, and definite electrocatalysts is crucial for sustainable renewable energy. This study successfully synthesized M-FeNi layered double hydroxides with excellent urea oxidation reaction performance by tuning the lattice expansion. The introduction of high-valence metal and the hollow structure promoted the formation of active species and mass transport. This research provides a new direction for constructing nanostructures and modulating electronic structures, which has potential implications for the development of auxiliary electrocatalysts.
Article
Chemistry, Inorganic & Nuclear
Hong-Juan Lv, Shu-Cong Fan, Yu-Cheng Jiang, Shu-Ni Li, Quan-Guo Zhai
Summary: Efficient CO2 capture and conversion techniques are essential for global sustainable development. In this study, a novel bi-microporous Sc-MOF was designed and used for CO2 storage and catalytic conversion. The material showed high adsorption selectivity, large CO2 storage capacity, and high catalytic activity.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Shu-Cong Fan, Ya-Li Zhang, Jing-Jing Ni, Yong-Peng Li, Shu-Ni Li, Quan-Guo Zhai
Summary: Comprehensive understanding of substituent engineering on metal-organic frameworks can promote gas adsorption and catalytic performance. This study selected pore-space-partitioned MOFs as a platform to evaluate the effect of organic functional groups on CO2 adsorption, separation, and catalytic conversion. Experimental results showed that MOFs with electron donors outperformed those with electron acceptors, and -OH functionalized MOFs exhibited excellent performance.
INORGANIC CHEMISTRY
(2023)
Article
Engineering, Chemical
Li-Qiu Yang, Jia Yu, Peng Zhang, Ying Wang, Wen-Yu Yuan, Quan-Guo Zhai
Summary: In this study, controllable C2H2/CO2 inverse adsorption and separation were achieved through the modulation of aromaticity in pillar-layered metal-organic frameworks. The results from adsorption experiments and dynamic breakthrough experiments show that different molecular structures and temperature variations can induce inverse C2H2/CO2 separation.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Physical
Hai-Peng Li, Jia-Wen Wang, Quan-Guo Zhai
Summary: By introducing new inorganic building blocks, a series of new MOF-5-like frameworks exhibit excellent stability and adsorption performance, showing good stability in both organic solvents and aqueous solutions, as well as high C2H2 adsorption capacity and outstanding C2H2/C2H4 separation performance.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Multidisciplinary
Hai-Peng Li, Zhao-Di Dou, Yi Xiao, Guan-Jiang Fan, Dong-Chen Pan, Man-Cheng Hu, Quan-Guo Zhai
Summary: The introduction of chlorine, bromine, or iodine sites into metal-organic frameworks enhances the adsorption capacity of acetylene with lower energy consumption.
Article
Chemistry, Physical
Jia Yu, Jing Zhang, Peng Zhang, Ying Wang, Shu-Ni Li, Quan-Guo Zhai
Summary: This study demonstrates a new Zn-MOF family with special CO2-preferred CO2/C2H2 separation performance, showing high stability and the ability to produce highly pure C2H2 from the CO2/C2H2 mixture. The results have important implications for the application and development of MOF materials in purifying C2H2.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)