期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 1, 页码 26-38出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600741
关键词
cross-coupling; cyanamides; cyanation; thiocyanates; transition metals
资金
- National Natural Science Foundation of China [21672028, 21572025]
- Innovation & Entrepreneurship Talents Introduction Plan of Jiangsu Province
- Key University Science Research Project of Jiangsu Province [15KJA150001]
- Natural Science Foundation for Colleges and Universities of Jiangsu Province [16KJB150002]
- Jiangsu Key Laboratory of Advanced Catalytic Materials Technology [BM2012110]
- Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University
The cyano moiety is a common and important functional group that exists in a myriad of medicinal molecules and natural products. Moreover, nitriles serve as versatile precursors that can readily be converted into diverse functional groups as well as the nitrogen-containing cyclic molecules. As a result, cyanation has become a significant type of transformation in organic chemistry. However, in comparison with the well-developed C-cyanation, few works have been reported dealing with the N-, S-and O-cyanation processes. Apart from the classical von Braun reaction, chemists have developed a number of methods with various cyanating reagents to achieve such X-cyanations (X=N, S, O). In this review, recent advances (especially those after 2000) in the X-CN (X=N, S, O) bond formation are summarized with discussion and the outlooks are also listed.
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