期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 358, 期 15, 页码 2366-2370出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600390
关键词
asymmetric catalysis; carbene insertion; 2-carboxytetrahydroquinolines; chiral spiro ligands; copper
资金
- National Natural Science Foundation of China
- National Basic Research Program of China [2012CB821600]
- 111 project of the Ministry of Education of China [B06005]
- National Program for Support of Top-notch Young Professionals
The first highly enantioselective intramolecular N-H bond insertion was realized by using copper catalysts modified with chiral spirobisoxazoline ligands, which provides a novel strategy for the synthesis of chiral 2-carboxytetrahydroquinolines. This reaction features fast reaction rate, high yield, high enantioselectivity, and mild reaction conditions.
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