期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 358, 期 12, 页码 1916-1923出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600127
关键词
alkynes; cyclotrimerization; homogeneous catalysis; nitrogen heterocycles; ruthenium
资金
- Czech Science Foundation [P207/11/0587]
- French Embassy in Prague
Monohalo- and dihalodiynes efficiently undergo [2+2+2]cyclotrimerization with nitriles in the presence of a catalytic amount of the ruthenium complex Cp*RuCl(cod) (10mol%) to afford the corresponding halopyridines under ambient conditions in good isolated yields (up to 90%). The halopyridines are formed as two separable regioisomers. This is the first example of a direct synthesis of halopyridines from haloalkynes and nitriles.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据