期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 358, 期 7, 页码 1157-1163出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201501130
关键词
aldehydes; hexamethyldisilazane (HMDS); nitriles; oxidation; oxygen; 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)
资金
- National Natural Science Foundation of China [21376224, 21206147]
- Hangzhou Qianjiang Distinguished Experts Project
An efficient method to prepare nitriles from aldehydes using hexamethyldisilazane (HMDS) as the nitrogen source has been developed. The reactions were performed with 2,2,6,6-tetramethylpiperidine l-oxyl (TEMPO) as the catalyst, NaNO2 or TBN as the co-catalyst, and molecular oxygen as the terminal oxidant under mild conditions. A variety of aromatic, heteroaromatic, aliphatic and allylic aldehydes could be converted into their corresponding nitriles in good to excellent yields.
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