期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 358, 期 14, 页码 2317-2323出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600045
关键词
hydrogen/deuterium exchange; iridium; N-heterocyclic carbenes (NHCs); polyethylene; supported catalysis
资金
- CNRS
- ESCPE-Lyon
- Universite Claude Bernard Lyon 1
- ANR
The multistep synthesis of a polyethylene-supported iridium( III)-(N-heterocyclic carbene) hydrogen/deuterium exchange catalyst was performed starting from an iodo-polyethylene obtained via catalyzed polyethylene chain growth (CCG) on magnesium. Unique thermomorphic polyethylene properties give the possibility to perform catalytic hydrogen/deuterium exchange reactions at 100 degrees C in the homogeneous phase with simple catalyst separation as a precipitate at room temperature. The catalytic activity of the polymer-supported catalyst was compared with that of its monomeric analogue. The catalytic studies showed that the supported catalyst exhibits similar profiles and turnover numbers as homogeneous counterparts without deactivation.
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