4.7 Article

LSCF-GDC composite particles for solid oxide fuel cells cathodes prepared by facile mechanical method

期刊

ADVANCED POWDER TECHNOLOGY
卷 27, 期 2, 页码 646-651

出版社

ELSEVIER
DOI: 10.1016/j.apt.2016.02.022

关键词

Mechanical synthesis; LSCF-GDC; Composite cathode; SOFC

资金

  1. JSPS KAKENHI Grant [24360315]

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La0.6Sr0.4Co0.2Fe0.8O3 (LSCF)-Ce0.9Gd0.1O1.95 (GDC) composite is one of the most promising cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFC). However, currently most commonly used synthesis techniques for preparation of LSCF-GDC composite powders are very complicated and energy-consuming. In this study, a facile mechanical method to synthesize La0.6Sr0.4Co0.2Fe0.8O3 (LSCF)-Ce0.9Gd0.1O1.95 (GDC) composite powder was proposed. Such composite powder was formed by mechanical treatment of La2O3, Sr(OH)(2), Co3O4, Fe2O3, and GDC powders using a high-speed attrition-type mill. The results revealed that the LSCF-GDC composite powder was successfully synthesized through a short-duration (20 min) mechanical treatment, and the synthesized powder formed composite particles consisting of nano-sized particles. Furthermore, the resultant cathode after sintering at 900 degrees C exhibited very low polarization resistances of 0.08, 0.17, 0.38, and 0.69 Omega cm(2) at temperatures of 800, 750, 700, and 650 degrees C, respectively. (C) 2016 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.

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