期刊
ADVANCED FUNCTIONAL MATERIALS
卷 26, 期 17, 页码 2959-2965出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201504979
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资金
- NRF of Korea - Ministry of Science, ICT & Future Planning [NRF-2013R1A2A1A09014038]
- Energy Efficiency & Resources Core Technology Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Ministry of Trade, Industry & Energy, Republic of Korea [20152010103470]
Metal oxides have been regarded as promising next-generation anode materials for rechargeable lithium ion batteries; however, their poor stability, which is caused by large volume changes during repeated lithiation/delithiation, remains a challenge. Here, conformally encapsulated low-oxidation state oxide cubes with reduced graphene oxide (RGO) obtained via a new pressurized reduction consisting of external mechanical compression and internal thermokinetic reduction from highly porous metal oxides/RGO aerogel (RGOA) are reported. Using single crystalline (SC) cobalt oxides and iron oxide cubes as model systems, the SC-Co3O4 or Fe2O3 cube/RGOA are pressurized into compacted xerogel along with a uniform thermokinetic reduction, which result in topotactic transformation to core-shelled CoO/RGO or Fe3O4@RGO cubes. The SC-CoO and SC-Fe3O4 cubes isolated perfectly in the RGO shells have dramatically improved their cycling stabilities for lithium ion storage to hundreds of times.
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