Article
Electrochemistry
Naveen Kumar Tailor, Satyaprasad P. Senanayak, Mojtaba Abdi-Jalebi, Soumitra Satapathi
Summary: In this study, the low-frequency carrier kinetics of organometallic halide perovskite-based solar cells were investigated. It was found that the dielectric permittivity showed a strong frequency dependence with dielectric relaxation, indicating localized charge carrier relaxation and hopping processes in these high-efficiency perovskite photovoltaics.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Multidisciplinary
Jingxuan Chen, Donglin Jia, Rongshan Zhuang, Yong Hua, Xiaoliang Zhang
Summary: A highly orientated PQD solid is achieved by precursor engineering and chemical stripping treatment. The highly ordered PQDs promote charge-carrier transport and reduce nonradiative recombination by decreasing surface trap states. This study provides a feasible approach for constructing high-performance optoelectronic devices.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Physical
Xing Meng, Yifan Chen, Fan Yang, Jieqi Zhang, Guozheng Shi, Yannan Zhang, Haodong Tang, Wei Chen, Yang Liu, Lin Yuan, Shaojuan Li, Kai Wang, Qi Chen, Zeke Liu, Wanli Ma
Summary: This study explores the potential of using conjugated polymers as hole-transporting layer (HTL) in lead sulfide (PbS) quantum dot solar cells. The precise regulation of the inorganic/organic interface is crucial for achieving high-performance devices. By introducing CsPbl(3) quantum dots as an interfacial layer between the PbS quantum dot active layer and the organic polymer HTL, the interface is mediated and favorable energy level alignment is achieved, resulting in improved charge extraction and reduced interfacial charge recombination. As a result, the photovoltaic performance is efficiently improved from 10.50% to 12.32%. This study may provide new guidelines for the device structural design of quantum dot optoelectronics by integrating different solution-processed semiconductors.
Review
Chemistry, Physical
Elnaz Ghahremanirad, Osbel Almora, Sunil Suresh, Amandine A. Drew, Towhid H. Chowdhury, Alexander R. Uhl
Summary: Impedance spectroscopy (IS) is an effective characterization technique used to probe and distinguish charge dynamics occurring at different timescales in optoelectronic and electric devices. With the rapid rise of research being conducted on perovskite solar cells (PSCs), IS has significantly contributed to the understanding of their device performance and degradation mechanisms. This review explains the most common IS protocols and discusses the application of IS measurement protocols for PSCs, providing a critical perspective and outlook on the growing topic of IS on PSCs.
ADVANCED ENERGY MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Meidan Ye, Gill M. Biesold, Meng Zhang, Weiguo Wang, Tian Bai, Zhiqun Lin
Summary: Perovskite solar cells (PSCs) have emerged as a promising candidate for next-generation photovoltaic applications, but face challenges such as moisture, thermal and UV stability, photocurrent hysteresis behavior, flexibility, and large-scale productions. Quantum dot materials have attracted research interest due to their optical, electrical, and optoelectrical properties; they can play diverse roles in PSCs and enhance efficiency and stability through strong chemical interactions with perovskites. Applications of QDs in PSCs can improve energy-level alignment, moisture stability, conversion of UV-radiation to visible light, and overall performance of the solar cells.
Article
Chemistry, Physical
Hakimeh Teymourinia, Cedric Gonzales, Juan Jesus Gallardo, Masoud Salavati-Niasari, Juan Bisquert, Javier Navas, Antonio Guerrero
Summary: The study focuses on passivating the external interfaces in lead halide perovskites through a reaction between migrating iodide ions and a silver buffer layer, which completely suppresses hysteresis and leads to more stable devices. X-ray photoelectron spectroscopy measurements and impedance spectroscopy monitoring reveal that the reaction occurs in minutes in the presence of an electrical field and light.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Jiabei Yuan, Xuliang Zhang, Jianguo Sun, Robert Patterson, Huifeng Yao, Di Xue, Yao Wang, Kang Ji, Long Hu, Shujuan Huang, Dewei Chu, Tom Wu, Jianhui Hou, Jianyu Yuan
Summary: This study demonstrates superior photovoltaic performance of hybrid solar cells consisting of CsPbI3 perovskite QDs and Y6 series non-fullerene molecules, highlighting their importance in hybrid device design. The champion CsPbI3 QD/Y6-F hybrid device achieves a record-high efficiency of 15.05% for QD/organic hybrid PV devices, paving a new way for efficient optoelectronic devices with solution-processable hybrid films.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Energy & Fuels
Ting Zhu, Hongkang Gong, Qi Song, Yi Dong, Fangtian You, Dan Li, Zhiqun He, Chunjun Liang
Summary: The interfacial or bulk defects of the perovskite layer have a significant impact on the stability and photoelectric conversion efficiency of perovskite solar cells. In this study, a multifunctional amino alcohol, BHF, was used as an additive in the active layer of p-i-n organic-inorganic halide perovskite solar cells. The BHF additive passivates the perovskite material at grain boundaries, resulting in improved crystal grain alignment and reduced defect densities. The BHF-treated perovskite films exhibit suppressed nonradiative recombination, enhanced photoluminescence, longer carrier lifetimes, and reduced ionic migration, contributing to an improved power conversion efficiency and operational stability of the PSCs.
Article
Chemistry, Physical
Jian Ni, Jiayi Guan, Minghao Hu, Rufeng Wang, Zhiwei Yang, Jun Li, Shuai Zhang, Sen Li, Juan Li, Hongkun Cai, Jianjun Zhang
Summary: Inorganic CsPbBr3 perovskite solar cells have attracted attention for their low cost and resistance to environmental factors. However, the crystallization mechanism and valence band offset limitations hinder efficiency improvement. By optimizing the crystallization process and using quantum dots for modification, higher efficiencies and stability can be achieved.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Junwei Shi, Ben Cohen-Kleinstein, Xuliang Zhang, Chenyu Zhao, Yong Zhang, Xufeng Ling, Junjun Guo, Doo-Hyun Ko, Baomin Xu, Jianyu Yuan, Wanli Ma
Summary: By introducing hydroiodic acid (HI) into the synthesis procedure, high-quality all-inorganic CsPbI3 quantum dots (QDs) can be achieved, addressing the issue of efficiency and stability degradation caused by surface trap states.
NANO-MICRO LETTERS
(2023)
Article
Chemistry, Physical
Nadja Klipfel, Agustin O. Alvarez, Hiroyuki Kanda, Albertus Adrian Sutanto, Cansu Igci, Cristina Roldan-Carmona, Cristina Momblona, Francisco Fabregat-Santiago, Mohammad Khaja Nazeeruddin
Summary: In this study, we highlight the importance of C-60 and compact-TiO2 as electron transport layers in the performance of coevaporated n-i-p perovskite solar cells. We demonstrate that there is a synergistic effect between these layers in charge extraction and optimization of the C-60 layer is crucial for enhancing device performance. Moreover, we find that excessively thick C-60 layers can introduce additional charge transport resistance and hinder the fabrication of highly efficient perovskite solar cells.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
G. Nagaraj, Mustafa K. A. Mohammed, Masoud Shekargoftar, P. Sasikumar, P. Sakthivel, G. Ravi, M. Dehghanipour, Seckin Akin, Ahmed Esmail Shalan
Summary: This study introduces a method of using graphene quantum dots to modify the SnO2/ZnO layer to enhance the performance of perovskite solar cells, significantly improving opto-electronic properties and increasing power conversion efficiency. Devices with the modified electron transport layer show higher open-circuit voltage and long-term stability.
MATERIALS TODAY ENERGY
(2021)
Article
Chemistry, Multidisciplinary
Xuliang Zhang, Hehe Huang, Xufeng Ling, Jianguo Sun, Xingyu Jiang, Yao Wang, Di Xue, Lizhen Huang, Lifeng Chi, Jianyu Yuan, Wanli Ma
Summary: A perovskite quantum dot solar cell with an internal P/N homojunction demonstrated remarkable thickness tolerance and high efficiency. By introducing an organic dopant and preparing different carrier-type QD arrays, successful carrier-type transformation from n-type to p-type was achieved, leading to enhanced power conversion efficiency.
ADVANCED MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Tulus, Junke Wang, Yulia Galagan, Elizabeth Von Hauff
Summary: We used impedance analysis to quantify electrochemical losses in perovskite solar cells based on MAPbI(3) films. We focused on the characteristic signatures in the impedance spectra, particularly the negative capacitance hook observed at low frequencies. By applying a generalized equivalent circuit model, we determined that the negative capacitance is due to slow electrochemical dynamics. We also observed a non-linear response at higher applied voltages, indicating irreversible chemical changes in the absorber layer.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Nanoscience & Nanotechnology
Hebing Tang, Tingting Xu, Xiulan Qin, Kai Zou, Shaoshen Lv, Jingquan Fan, Tao Huang, Lixin Chen, Wei Huang
Summary: In this study, two types of carbon quantum dots were used to passivate the perovskite surface of solar cells, resulting in improved photovoltaic performance. The introduction of A-CQDs led to larger crystal grains, reduced defect density, and efficient carrier transfer, achieving a champion power conversion efficiency of 13.97%. A-CQDs-based C-PSCs also showed excellent stability with over 80% retention of initial efficiency after 840 hours of storage under 35% humidity.
ACS APPLIED NANO MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Ileana Recalde, Andres. F. Gualdron-Reyes, Carlos Echeverria-Arrondo, Alexis Villanueva-Antoli, Jorge Simancas, Jhonatan Rodriguez-Pereira, Marcileia Zanatta, Ivan Mora-Sero, Victor Sans
Summary: The use of non-toxic and low-cost alpha-tocopherol (vitamin E) improves the photophysical properties and stability of perovskite nanocrystals (PNCs). Alpha-tocopherol restores the luminescent features and reduces surface defects of aged CsPbI3 PNCs. It also enables the formulation of PNCs-acrylic polymer composites with improved luminescent features and long-term stability.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Vladimir S. Chirvony, Isaac Suarez, Jesus Sanchez-Diaz, Rafael S. Sanchez, Jesus Rodriguez-Romero, Ivan Mora-Sero, Juan P. Martinez-Pastor
Summary: An unusual spectrally reproducible near-IR random lasing is observed in chemically stabilized polycrystalline films of formamidinium tin triiodide perovskite. The high Q-factor and low ASE threshold of the lasing are achieved. The spectral stability is explained by the large inhomogeneous broadening of the emitting centers in Sn-based perovskites.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ross A. Kerner, Ayala V. Cohen, Zhaojian Xu, Ahmad R. Kirmani, So Yeon Park, Steven P. Harvey, John P. Murphy, Robert C. Cawthorn, Noel C. Giebink, Joseph M. Luther, Kai Zhu, Joseph J. Berry, Leeor Kronik, Barry P. Rand
Summary: Metal halide perovskites are difficult to control in terms of electronic doping, but the study of noble-metal interstitials can provide insights into their impact on perovskite-based devices. This work investigates doping of metal halide perovskites using electrochemically formed Au+ interstitial ions, and combines experimental data with computational analysis. The study finds that Au+ cations can easily form and migrate through the perovskite bulk, acting as stable n-dopants. The results provide a deeper understanding of the effects of metal electrode reactions on the performance of perovskite devices, and offer an alternative explanation for the valence switching mechanism in halide-perovskite-based devices.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Patricio Serafini, Alexis Villanueva-Antoli, Samrat Das Adhikari, Sofia Masi, Rafael S. Sanchez, Jhonatan Rodriguez-Pereira, Bapi Pradhan, Johan Hofkens, Andres F. Gualdron-Reyes, Ivan Mora-Sero
Summary: In this study, the introduction of guanidinium (GA+) during the synthesis of high-quality Cs(1-x)GA(x)PbI(3) perovskite nanocrystals (PNCs) was explored as a promising approach for the fabrication of efficient bright-red light-emitting diodes (R-LEDs). The substitution of Cs by 10 mol % GA allowed the preparation of mixed-cation PNCs with PLQY up to 100% and long-term stability for 180 days. This substitution compensated intrinsic defect sites and suppressed the non-radiative recombination pathway, leading to R-LEDs with improved performance and stability.
CHEMISTRY OF MATERIALS
(2023)
Article
Energy & Fuels
Mostafa Roudgar-Amoli, Zahra Shariatinia
Summary: Several hybrid composite photoanodes consisting of easily synthesizable and cost-effective La0.6Sr0.4CoO3 nanoparticles combined with TiO2 nanoparticles were investigated for their light-harvesting properties in dye-sensitized solar cells. By adding pure inorganic perovskite La0.6Sr0.4CoO3 and plasmonic silver nanoparticles decorated La0.6Sr0.4CoO3 into the TiO2 photoanodes, the efficiency of the DSSCs was significantly increased.
Article
Spectroscopy
Zahra Shariatinia, Amin Alizadeh, Mostafa Roudgar-Amoli, Melika Mahmoudi
Summary: To develop efficient photoelectrode nanomaterials for DSSCs, spinel ZnFe2O4 and Ag-doped ZnFe2O4 nanomaterials were incorporated into TiO2 photoanodes. The highest efficiency of 3.89% was achieved with TiO2 + 5 wt% ZnFe2O4 photoanode. The addition of Ag+ cations further improved the power conversion efficiency. The DSSC assembled using TiO2 + 5 wt% Ag0.2Zn0.90Fe2O4 photoanode achieved the highest PCE of 5.75%.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Materials Science, Multidisciplinary
Hamid Pashaei Adl, Setatira Gorji, Guillermo Munoz-Matutano, Andres F. Gualdron-Reyes, Isaac Suarez, Vladimir S. Chirvony, Ivan Mora-Sero, Juan P. Martinez-Pastor
Summary: This study focuses on the Superradiance (SR) emission observed in superlattices (SLs) formed by CsPbBr3 and CsPbBrI2 nanocrystals (NCs). Micro-Photoluminescence spectra and transients of CsPbBr3 SLs are measured to extract information about the SR states and uncoupled domains of NCs. The study finds that CsPbBr3 SLs with homogeneous SR lines have shorter lifetimes compared to thin films made with the same NCs, and the thermal decoherence of the SR exciton state is evident above a certain temperature due to coupling with phonons.
ADVANCED OPTICAL MATERIALS
(2023)
Editorial Material
Chemistry, Physical
Nicholas E. Jackson, Joseph M. Luther, Brett M. Savoie, Kaifeng Wu
JOURNAL OF CHEMICAL PHYSICS
(2023)
Article
Materials Science, Ceramics
Thais C. A. da Silva, Carolina Fernandez-Saiz, Rafael S. Sanchez, Andres F. Gualdron-Reyes, Ivan Mora-Sero, Beatriz Julian-Lopez
Summary: This work presents a fast one-step methodology to fabricate small CsPb(ClxBr1-x)(3) nanocrystals with good control of the particle size and shape by using a Soft Chemistry strategy (ligand-mediated controlled growth) and microwave heating. The protocol is designed to closely mimic the chemistry involved in the hot injection process, facilitating its adoption by the perovskite research community.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
Mostafa Roudgar-Amoli, Zahra Shariatinia
Summary: This study investigates the performance improvement of dye-sensitized solar cells (DSSCs) by developing double-layered photoanodes. The optimal combination is achieved by coating La2MnTiO6 + Cr2O3/C nanocomposites as the overlayer and TiO2 nanoparticles as the underlayer on the TiO2 photoanode. The champion cell based on TiO2/20% (70%La2MnTiO6 + 30%Cr2O3/C) photoanode shows a 2.19-fold higher power conversion efficiency compared to the traditional TiO2 monolayer based photoanode.
Article
Engineering, Environmental
Amin Alizadeh, Shakiba Asghar, Mostafa Roudgar-Amoli, Zahra Shariatinia
Summary: In order to remove Methylene Blue (MB) from water, H-MMT/MOF-5 and H-MMT/MOF-199 composites were synthesized and used for adsorption. The composites showed high efficiency in MB removal, with optimal removal rates of 97.52% and 98.73% for H-MMT/MOF-5 and H-MMT/MOF-199, respectively.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2023)
Review
Green & Sustainable Science & Technology
Amin Alizadeh, Mostafa Roudgar-Amoli, Zahra Shariatinia, Ebrahim Abedini, Shakiba Asghar, Shayesteh Imani
Summary: This review examines the application of perovskite oxides and spinels as counter electrodes (CEs) in dye-sensitized solar cells (DSSCs). Different CEs can significantly improve the conversion efficiency and stability of DSSCs. CEs made from perovskite oxides and spinels exhibit higher efficiency and stability compared to devices using platinum.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2023)
Article
Chemistry, Physical
Seul-Yi Lee, Patricio Serafini, Sofia Masi, Andres F. Gualdron-Reyes, Camilo A. Mesa, Jhonatan Rodriguez-Pereira, Sixto Gimenez, Hyo Joong Lee, Ivan Mora-Sero
Summary: In this study, a highly efficient photoanode electrode for the degradation of pollutants was prepared by directly forming nanoscale perovskite on the surface of mesoporous titanium dioxide film, and optimization was achieved by introducing a thin aluminum oxide coating layer. A photovoltaic/PEC tandem system was also developed to supply high voltage for efficient oxidation of pollutants without an external bias.
ACS ENERGY LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Mostafa Roudgar-Amoli, Amin Alizadeh, Ebrahim Abedini, Zahra Shariatinia
Summary: To achieve high-performance DSSCs, new and effective photoelectrode materials, namely CuCoO2 and ZnO, were successfully synthesized through a hydrothermal process and heat treatment of ZIF-8, respectively. The composite heterostructures of CuCoO2/ZnO demonstrated improved photovoltaic properties, making them promising photoanodes for DSSCs. The physicochemical characteristics and photovoltaic performance of the fabricated materials were thoroughly studied and discussed. CuCoO2/ZnO (0.1 : 1) showed the best performance among all cells, with a PCE of 6.27% and enhanced Voc, Jsc, FF, and IPCE.
Article
Chemistry, Physical
Zahra Shariatinia
Summary: Some ETLs containing NDIID core with different R groups were designed for PSCs. DFT calculations were performed to investigate their structural, electronic, and optical properties. The results showed that these ETLs have the potential to improve electron injection efficiency but have lower hole transfer efficiency. Among them, NDIID-SiMe3 ETL exhibited the highest electron mobility and the highest power conversion efficiency compared to other samples.
JOURNAL OF MOLECULAR STRUCTURE
(2024)