期刊
ADSORPTION SCIENCE & TECHNOLOGY
卷 34, 期 2-3, 页码 176-192出版社
SAGE PUBLICATIONS INC
DOI: 10.1177/0263617415623426
关键词
Polysquaraine; porous particle; pyrrolyl squaraine
资金
- Faculty of Health and Life Sciences, Coventry University
- West Midlands Manufacturing Advisory Service (TOR) [09/188]
- BlueSkyNano program
- Advantage West Midlands Science City Hydrogen Energy Project [BG/IN7008]
The article reports an experimental study of the metal uptake properties of poly(1-methylpyrrol-2-ylsquaraine) particles, in the context of 51 elemental metal complexes. Vagaries of the experimental results meant that the final analysis took place for 43 of these metals. After an initial descriptive analysis, an Analysis of Variance model was fitted. This revealed that several factors, some intrinsic to the metals themselves, others relating to the experimental conditions, have an important influence on the adsorption characteristics of the poly(1-methylpyrrol-2-ylsquaraine) particles. Of these, the most important is the ratio of the number of moles of the metal to the number of moles of the adsorbent particles. X-ray mapping of the poly(1-methylpyrrol-2-ylsquaraine) particles treated with contrast agent revealed that, although adsorption was all throughout the particles, the majority of the agent was adsorbed within 10-15% (diameter distance) of the surface of the particles.
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