期刊
SCIENTIFIC REPORTS
卷 8, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/s41598-018-34905-7
关键词
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资金
- Basic Science Research Program through the National Research Foundation of Korea, under the Ministry of Education [NRF-2017R1D1A1B03028368]
- Institute for Information & communication Technology Promotion (IITP) - Korea government (MSIP) [R75201600050001002]
- National Research Foundation by Ministry of Science and ICT of Korea [2017K1A4A3013662]
The present study investigates the fabrication of hierarchical 3D nanostructures with multi-component metal oxides in the presence of highly-porous graphene and characterized for its applications in high-performance supercapacitors. A hierarchical flowers like 3D nanostructure of Co3O4 @MnO2 on nitrogen-doped graphene oxide (NGO) hybrid composite was synthesized by thermal reduction process at 650 degrees C in the presence of ammonia and urea. The synthesized Co3O4 @MnO2/NGO hybrid composites were studied via Raman, XRD, X-ray XPS, FE-SEM, FE-SEM with EDX, FE-TEM and BET analyses. The electrochemical analysis of Co3O4 @MnO2/NGO hybrid composite electrode was investigated using cyclic voltammetry, chronopotentiometry and electrochemical impedance measurements. The hybrid composite electrode showed significant specific capacitance results of up to 347 F/g at 0.5 A/g and a corresponding energy density of 34.83Wh kg(-1) with better rate performance and excellent long-term cycling stability were achieved for 10,000 cycles. The obtained electrochemical results paved a way to utilize Co3O4 @MnO2/NGO composite electrode as a promising electrode material in high performance supercapacitors.
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