期刊
ADVANCED ENERGY MATERIALS
卷 8, 期 33, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201802180
关键词
full cells; high-capacity; Na-ion storage; Na-Mn-O; synergistic effect
类别
资金
- National Natural Science Fund for Distinguished Young Scholars [51425204]
- National Natural Science Foundation of China [51832004, 51872218, 51521001, 21805219, 51302203]
- National Key Research and Development Program of China [2016YFA0202603]
- Programme of Introducing Talents of Discipline to Universities [B17034]
- Yellow Crane Talent (Science & Technology) Program of Wuhan City
- project of innovative group for low cost and long cycle life Na-ion batteries R&D and Industrialization of Guangdong Province [2014ZT05N013]
- Fundamental Research Funds for the Central Universities [WUT: 2017IVA100, 2017IVA096, 2017III040]
Searching for new-type cathodes to enhance the capacity of Na-ion batteries is one of the hot spots in energy storage systems. Many sodium insertion transition metal oxides, i.e., Na-Mn-O compounds, are intensively studied owing to their high voltage, abundant resources, and low toxicity. However, its relatively low capacity greatly limits its application. Here, a new synergistic composite, 0.44Na(4)Mn(2)O(5)center dot 0.56Na(0.7)MnO(2), is developed by a feasible method of organic-acid-assisted drying and heat treatment. This synergistic composite cathode delivers a reversible sodium storage capacity as high as 278.0 mAh g(-1) and stable framework structure due to the synergistic effect. It is achieved by the synergistic effect of high capacity Na4Mn2O5 with multiple Na+ ions insert/extract sites and stable Na0.7MnO2 with layered structure. Even when tested at a high mass loading of 7.42 mg cm(-2), this composite cathode demonstrates stable cycling over 400 cycles for sodium storage. Moreover, when coupled with hard carbon anode, Na-ion full battery delivers excellent charge/discharge performance with capacity retention of 84.0%, showing great application potential in the large-scale energy storage field.
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