4.8 Article

Burgeoning Prospects of Spent Lithium-Ion Batteries in Multifarious Applications

期刊

ADVANCED ENERGY MATERIALS
卷 8, 期 33, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201802303

关键词

cathode materials; energy storage; leaching resynthesis; recycling; spent LIBs; waste-to-wealth

资金

  1. Science & Engineering Research Board (SERB), a statutory body of the Department of Science & Technology, Govt. of India [SB/S2/RJN-088/2016]

向作者/读者索取更多资源

Where sustainability is concerned, recycling of reutilizable wastes will always occupy the apex of the green chemistry research. Handling electronic wastes in a green manner without affecting the ecology and human health is one of the main challenges for material chemists and gains top priority among other fields of research. At present, handling and recycling of spent lithium-ion batteries (LIBs) is a key priority. Due to these environmental concerns, massive interest has been triggered in various crystal structures of metal oxides, and different kinds of carbon materials that provide the opportunities to replace the commercial LIBs for energy storage and conversion applications in a cost-effective manner. Reports are available on the recycling of spent LIBs, but these reports mainly focus on the metal recovery process rather than finding suitable applications for the recovered material. This present work exclusively summarizes the global demand for LIB raw materials, tactics in the resynthesis process along with the wide range of growing applications of spent LIB materials. Finally, the future prospects of applications that utilize spent LIB materials are addressed.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

Choice of Binder on Conversion Type CuO Nanoparticles toward Building High Energy Li-Ion Capacitors: An Approach Beyond Intercalation

Manohar Akshay, Krishnan Subramanyan, Madhusoodhanan Lathika Divya, Yun-Sung Lee, Vanchiappan Aravindan

Summary: This work describes the assembly of a lithium-ion capacitor using recovered CuO nanoparticles and activated carbon as the electrodes. The Li-storage property of the CuO nanoparticles with different binders is investigated, and it is found that carboxymethylcellulose (CMC) exhibits better performance compared to polyvinylidene fluoride (PVDF) binder.

ADVANCED MATERIALS TECHNOLOGIES (2022)

Article Energy & Fuels

Lithium Difluoro(Oxalate)Borate-Induced Interphase for High-Voltage LiFe0.15Co0.85PO4@C Cathode by Solid-State Synthesis

Sreekumar Sreedeep, Subramanian Natarajan, Yun-Sung Lee, Vanchiappan Aravindan

Summary: The effect of lithium difluoro(oxalate)borate (LiDFOB) as an electrolyte additive on the electrochemical performance of LiFe0.15Co0.85PO4@C cathode was investigated, and it was found that the addition of LiDFOB improved the electrochemical performance of the cathode.

ENERGY TECHNOLOGY (2023)

Article Electrochemistry

Multi-layered MXene V4C3Tx as new low-voltage insertion anode for Na-ion battery applications

Krishnan Subramanyan, Sanming Chen, Na Li, Tingting Ma, Yongping Liu, Sundaram Chandrasekaran, Vanchiappan Aravindan

Summary: We report a new low-voltage insertion anode based on MXene V4C3Tx and compare its electrochemical performance with ester and ether-based electrolytes in both half-cell and full-cell configurations. The results show that the ether-based electrolyte exhibits better retention ability and rate performance. In addition, the formation of a passivation layer in the carbonate-based electrolyte leads to increased initial Coulombic inefficiency. Full-cell tests with NVPC cathode also demonstrate that the ether-based electrolyte provides enhanced capacity, capacity retention, and rate performance compared to ester-based electrolytes.

ELECTROCHIMICA ACTA (2023)

Article Green & Sustainable Science & Technology

Recycling of value-added products from spent lithium-ion batteries for oxygen reduction and methanol oxidation reactions

Keyru Serbara Bejigo, Subramanian Natarajan, Kousik Bhunia, Vijayakumar Elumalai, Sang-Jae Kim

Summary: Environmentally friendly technology for recycling spent lithium-ion battery (LIB) electrodes was developed to explore the efficiency of regenerated electrocatalysts for electrochemical oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR). The process involved lixiviation of LixCoO2 electrodes using tartaric acid and H2O2, conversion of graphite into graphene oxide (GO), and regeneration of cobalt oxide-supported reduced graphene oxide (Co3O4/rGO). The regenerated composite material exhibited good activity for ORR and MOR, indicating the potential utilization of end-of-life LIBs as high-performance electrocatalysts in energy conversion devices.

JOURNAL OF CLEANER PRODUCTION (2023)

Article Chemistry, Multidisciplinary

MnCO3 Cuboids from Spent LIBs: A New Age Displacement Anode to Build High-Performance Li-Ion Capacitors

Subramanian Natarajan, Manohar Akshay, Vanchiappan Aravindan

Summary: The design of lithium-ion capacitors (LICs) by hybridizing battery and supercapacitor electrodes has overcome the limitations of supercapacitors and batteries and achieved higher energy and power density. The development of high-performance LICs has been hindered by the slow diffusion of Li-ion in battery anodes. In this study, the regeneration of MnCO3 cuboids from spent LiMn2O4 cathodes is introduced for LICs applications, exhibiting excellent reversibility and high Coulombic efficiency. The LIC assembled with the regenerated MnCO3 anode and commercial activated carbon cathode demonstrates a maximum energy density of 169.4 Wh kg(-1) at 25 degrees C and long durability of 15,000 cycles, even at extreme temperatures.
Article Chemistry, Physical

Towards Commercialization of Graphite as an Anode for Na-ion Batteries: Evolution, Virtues, and Snags of Solvent Cointercalation

Krishnan Subramanyan, Vanchiappan Aravindan

Summary: Sodium-ion storage in graphite through solvent cointercalation mechanism shows excellent cycling stability, rate performance, and Coulombic efficiency. The graphite half cell exhibits a low working voltage and high power density, making it a versatile energy storage device. This perspective comprehensively investigates graphite-based sodium-ion full cells and discusses important factors such as electrolyte composition, cathode working voltage, irreversibility, precycling, and high current performance. The article also proposes general considerations for full-cell assembly.

ACS ENERGY LETTERS (2023)

Article Physics, Applied

Carbothermally Synthesized MoO2 as an Insertion Host for High-Performance Li-ion Capacitors

Madhusoodhanan Lathika Divya, Yun-Sung Lee, Vanchiappan Aravindan

Summary: This work explores the potential of MoO2 nanorods as an anode material for lithium-ion capacitor (LIC) assembly. The material exhibits high discharge capacity and excellent cyclic stability. Its performance as an anode in LIC assembly is analyzed, and the effects of prelithiation and operating-voltage window are studied. The study demonstrates that MoO2-based LIC systems can be a strong competitor to graphite-based LIC configurations, offering enhanced safety features.

PHYSICAL REVIEW APPLIED (2023)

Article Materials Science, Multidisciplinary

Scalable Synthesis of Bulk TiO2 Hybrids Toward Efficient Li-Storage Performance in Rocking-Chair Type Full-Cell Assembly With High Voltage LiNi0.5Mn1.5O4 Cathode

Shaji Jyothilakshmi, Krishnan Subramanyan, Yun-Sung Lee, Vanchiappan Aravindan

Summary: A simple and green synthesis method for TiO2 bronze/anatase hybrid with excellent electrochemical performance as an anode for LIBs is reported. The Li-ion insertion/extraction properties are studied in both half and full-cell configurations, showing promising results in terms of discharge capacity and capacity retention. The TiO2 hybrids exhibit a maximum energy density of 192.75 Wh kg(-1) and good cyclability at room temperature conditions.

ADVANCED MATERIALS TECHNOLOGIES (2023)

Article Materials Science, Multidisciplinary

Defect Engineered Dendritic Fibrous Nanosilica as Prospective Alloy Anode for the Fabrication of High-Energy Li-Ion Capacitors with Ultralong Durability

Manohar Akshay, Rajesh Belgamwar, Selvarasu Praneetha, Vivek Polshettiwar, Vanchiappan Aravindan

Summary: This work reports the synthesis of defect-engineered dendritic fibrous nanosilica (SiOx) and commercial activated carbon (AC) for lithium-ion capacitors (LICs). The LICs exhibit excellent electrochemical performance, with a maximum energy density of 169.7 Wh kg-1 at room temperature and ultralong durability of >48,000 cycles. The possibility of exploring LIC at different climatic conditions is also analyzed at various temperatures from -5 to 50 degrees C.

ACS MATERIALS LETTERS (2023)

Article Chemistry, Physical

Interphase stabilized electrospun SnO2 fibers as alloy anode via restricted cycling for Li-ion capacitors with high energy and wide temperature operation

Manohar Akshay, Sundaramurthy Jayaraman, Mani Ulaganathan, Yun-Sung Lee, Vanchiappan Aravindan

Summary: The second-generation supercapacitor is composed of a hybridized energy storage mechanism of Lithium-ion batteries and electrical double-layer capacitors, known as Lithium-ion capacitors (LICs). Electrospun SnO2 nanofibers are synthesized using a simple electrospinning technique and directly used as the anode material for LICs along with activated carbon (AC) as the cathode. The LIC, AC/(LixSn + Li2O), assembled after pre-lithiation of the SnO2 electrode, exhibited a maximum energy density of 185.88 Wh kg-1 and excellent cyclic durability of over 20,000 cycles. Additionally, the feasibility of using the LIC in different environmental conditions was studied by subjecting it to various temperature conditions (-10, 0, 25, & 50 degrees C).

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Chemistry, Multidisciplinary

Controlled Synthesis of SnO2 Nanostructures as Alloy Anode via Restricted Potential Toward Building High-Performance Dual-Ion Batteries with Graphite Cathode

Parvathy Jayan, Anil Anjali, Sangho Park, Yun-Sung Lee, Vanchiappan Aravindan

Summary: Dual-ion batteries, utilizing graphite as a bi-functional electrode to reversibly store cations and anions, have shown great potential as energy storage devices. This study focuses on optimizing the Li-storage performance of SnO2 nanostructures as an alternative to graphite anodes. Additionally, the electrochemical performance of a DIB using recovered graphite and SnO2 nanostructures as the cathode and anode is evaluated, demonstrating a high discharge capacity. The study also assesses the adaptability of DIBs to different temperature conditions.
Article Green & Sustainable Science & Technology

Probing Enhanced Electrochemical Performance of Poly (3,4-ethylenedioxy Thiophene) Encapsulated 5.3 V Spinel LiCoMnO4 Cathode for Li-ion Batteries

Sreekumar Sreedeep, Yun-Sung Lee, Vanchiappan Aravindan

Summary: The effect of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT) coating on the electrochemical properties of high voltage lithium cobalt manganese oxide (LCMO) cathodes is investigated. The results demonstrate that LCMO@PEDOT exhibits improved cycling performance and diffusion coefficient compared to pristine LCMO in a half-cell configuration. Furthermore, LCMO@PEDOT/LTO in a full-cell assembly displays superior electrochemical performance compared to pristine LCMO/LTO.

ADVANCED SUSTAINABLE SYSTEMS (2023)

Article Chemistry, Multidisciplinary

High-Performance Li-Ion and Na-Ion Capacitors Based on a Spinel Li4Ti5O12 Anode and Carbonaceous Cathodes

Manohar Akshay, Shaji Jyothilakshmi, Yun-Sung Lee, Vanchiappan Aravindan

Summary: This article primarily focuses on the synthetic methods and modifications of lithium titanate (LTO) in lithium-ion hybrid capacitors (LICs) to enhance their electrochemical performance. It also discusses the influence of other factors, such as the anode material and electrolyte, on LIC performance.
Article Electrochemistry

Exfoliated Graphene Oxide @ Sb2O3 Octahedrons as Alloy-Conversion Anode for High-Performance Na-Ion Batteries with P2-Type Na2/3Ni1/ 3Mn2/3O2 Cathode

Krishnan Subramanyan, Murukabhavan Ramar Palmurukan, Yun-Sung Lee, Vanchiappan Aravindan

Summary: Conversion-alloying-based anodes for sodium-ion batteries have high energy density and specific capacity, but suffer from volume expansion and poor cycling stability. This study introduces exfoliated graphene oxide (EGO) as a carbon matrix to alleviate volume expansion issues and promote fast kinetics.

ELECTROCHIMICA ACTA (2023)

暂无数据