4.3 Article

Superelectrophilic Diels-Alder reactions and oxidations leading to heterocyclic biaryl compounds

期刊

SYNTHETIC COMMUNICATIONS
卷 49, 期 2, 页码 316-323

出版社

TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2018.1554149

关键词

Biaryl; heterocycle; superacid; oxidation

资金

  1. U.S. National Science Foundation [1300878]

向作者/读者索取更多资源

Heterocyclic imines provide biaryl products by a two-step transformation. The first transformation involves a Diels-Alder reaction with a multiply protonated imine to give a tetrahydroquinoline product, whereas the second step involves oxidation with elemental sulfur at 260 degrees C. [GRAPHICS]

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