期刊
SEPARATION SCIENCE AND TECHNOLOGY
卷 54, 期 6, 页码 888-901出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/01496395.2018.1523192
关键词
Biochar; competitive adsorption; date seed; heavy metal; modified Langmuir
In a multicomponent systems, the adsorption of Pb2+, Cu2+, and Ni2+ by date seed biochar exhibited competitive behavior. Compared to single component systems, the adsorption capacities of each ion were reduced by 48-75% in both batch and column experiments. Surface complexation with carboxyl and hydroxyl functional groups played a major role in the removal mechanism. Ion exchange mechanism accounted for 37-40% of the total adsorption compared to 57-72% in single component systems. Modified Langmuir isotherm best described the systems. Adsorption capacities and selectivity follow the order: Pb2+> Cu2+> Ni2+. Multi-stage sequences system is recommended to avoid premature exhaustion of biochar.
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