Article
Engineering, Environmental
Zhen Chen, Haibo Yin, Chizhong Wang, Rong Wang, Yue Peng, Changfu You, Junhua Li
Summary: The competitive adsorption and photocatalytic reaction on TiO2@SiO2 were investigated, showing that SO2 negatively impacts NO conversion efficiency and adsorption capacity. Surface hydroxyls on anatase (101) are favorable for NO/SO2 adsorption, while lone pair electrons of N or S atoms form covalent bonds with surface-O.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2021)
Article
Engineering, Environmental
Zhuoyao Fang, Siyuan Pan, Xiaolin Zhang, Lu Lv, Bingcai Pan
Summary: Efficient removal of As(III) from groundwater was achieved by preparing a novel nanocomposite Zr-Mn@N201, which enabled simultaneous oxidation and sequestration of As(III). The results showed that Zr-Mn@N201 exhibited stable performance in adsorption-regeneration cycles and significantly increased the treatment capacity compared to the single nano-HZO column in fixed-bed assays.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Environmental Sciences
Ying Yuan, Siyuan Lei, Xinyu Jin, Chunyu Wang, Ziyi Zhai, Chaoyue Zhao, Changsong Zhou
Summary: A series of adsorption/oxidation bifunctional material with different Fe(II) loading amounts was prepared and characterized using various techniques. The optimal reaction conditions for benzene adsorption efficiency were determined and the adsorption results were analyzed using different kinetic models. The catalytic oxidation efficiency of the bifunctional resin materials in a heterogeneous Fenton system was significantly improved and had excellent stability. This study provides a novel process for the adsorption and oxidative degradation of VOCs.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Chemistry, Physical
Vladimir Paunovic, Vitaly Sushkevich, Przemyslaw Rzepka, Luca Artiglia, Roland Hauert, Sung Sik Lee, Jeroen A. van Bokhoven
Summary: This study investigates the potential of regenerating catalysts by reacting coke deposits with hydrogen. The reactivation efficiency is enhanced under high pressure, and hydrogen treatment can remove coke and restore catalyst activity in various Si/Al ratios.
JOURNAL OF CATALYSIS
(2022)
Article
Engineering, Environmental
Xiaobo Wang, Wenjun Zhu, Nan Wang, Xiaohua Zuo
Summary: By controlling the synthetic conditions and introducing oxygen and nitrogen functional groups on the surface of the activated carbon, N-OAC showed enhanced adsorption and activation ability towards persulfate while improving its adsorption capacity and catalytic degradation efficiency towards bisphenol A.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Fan Lin, Mengze Xu, Karthikeyan K. Ramasamy, Zhenglong Li, Jordan Lee Klinger, Joshua A. Schaidle, Huamin Wang
Summary: The article discusses the challenges faced by biomass conversion technologies, specifically in terms of catalyst deactivation and mitigation. It highlights the unique properties of biomass-derived feedstocks that cause catalyst deactivation and provides information on potential mitigation approaches to guide the design of robust catalysts and processes for biomass conversion.
Article
Chemistry, Physical
Xiucheng Sun, Yuehan Wang, Geqian Fang, Jian Zhang, Chaojie Wang, Yang Chen, Yiming Gu, Lin Li, Ying Li, Jian Lin
Summary: This study developed a Pt catalyst supported by a metal-organic framework (CAU-1) material, achieving complete elimination of HCHO through a one-step storage-oxidation process at room temperature, with high adsorption capacity and catalytic efficiency.
APPLIED SURFACE SCIENCE
(2022)
Article
Metallurgy & Metallurgical Engineering
Oksana Dudarko, Natalia Kobylinska, Vadim Kessler, Gulaim Seisenbaeva
Summary: Rare earth elements (REEs) such as Nd3+ and Dy3+ were recovered from simulated and real leaching solution of the NdFeB magnet via solid phase extraction. Various experimental factors were investigated and a method based on silica functionalization was developed for the selective separation and recovery of REEs.
Article
Engineering, Environmental
Qianxin Zhang, Menghan Zhang, Tong Li, Roujia Du, Gang Yu, Shubo Deng
Summary: In this study, FeOCl confined into activated carbon (FeOCl/AC) was used for catalytic oxidation of contaminants on spent activated carbon. The results showed that FeOCl/AC had high regeneration efficiency and remained stable even after multiple cycles of adsorption and regeneration.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Chemistry, Physical
Xinyi Zhang, Chunling Bo, Shuang Cao, Zhijie Cheng, Zhaozhong Xiao, Xiaolong Liu, Ting Tan, Lingyu Piao
Summary: This study investigates the deactivation mechanism of Pt/b-TiO2 NFs photocatalyst used in photocatalytic pure water splitting for hydrogen production, and proposes simple and effective methods to improve stability. The accumulation of H-2 and the adsorption of the product H2O2 are found to decrease the stability of the photocatalyst. Timely transfer of large amounts of H-2 and mechanical disturbance can significantly improve the stability of the catalyst.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Nanoscience & Nanotechnology
Jun Wang, Bin Li, Yang Li, Xiaobin Fan, Fengbao Zhang, Guoliang Zhang, Yuanzhi Zhu, Wenchao Peng
Summary: In this study, gamma-Al2O3-supported CuO materials were synthesized using a novel method and showed excellent catalytic activities for bisphenol A degradation. The catalyst can be easily regenerated through aerobic calcination and has great potential applications in wastewater treatment.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Engineering, Environmental
G. Guicheney, S. Dorge, H. Nouali, B. Lebeau, M. Soulard, J. Patarin, M. Moliere, M. Vierling, A. C. Houdon, L. Vidal, J. F. Brilhac
Summary: The effect of water vapor on the DeSOx performance of regenerable CuO/SBA-15 adsorbent was investigated. Water vapor at 400 degrees C decreased the SO2 adsorption capacity, while at 450 degrees C it increased the adsorption capacity. Lower CuO loading reduced the deactivation of the adsorbent under wet conditions. The deactivation induced by water vapor was shown to be reversible or partially reversible.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Yuhao Wang, Genyuan Wang, Lars I. van der Wal, Kang Cheng, Qinghong Zhang, Krijn P. de Jong, Ye Wang
Summary: The catalytic performance of composite catalysts is influenced by the interaction between components and the migration of metals. Different metals exhibit different migration behavior towards zeolite, affecting the selectivity of hydrocarbon products.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Engineering, Chemical
I Sanchis, E. Diaz, A. H. Pizarro, J. J. Rodriguez, A. F. Mohedano
Summary: Nitrate pollution of water bodies is a serious global environmental problem, and there is a lack of cost-effective solutions for its removal. Catalytic reduction is an emerging technology that can transform nitrate into harmless nitrogen gas, but it faces challenges in stability and catalyst regeneration.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Chemical
Nga Tran, Yoshimitsu Uemura, Thanh Trinh, Anita Ramli
Summary: In this study, the activity and stability of different metal catalysts in vapor-phase HDO process were investigated, revealing that bimetallic Pd-Co and Pd-Fe catalysts showed higher HDO yield and stability compared to monometallic catalysts, with Pd-Fe catalyst demonstrating higher stability and regeneration ability.