期刊
ORGANIC LETTERS
卷 20, 期 23, 页码 7679-7683出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03422
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资金
- ETH Zurich
A convergent strategy for the synthesis of dideoxysalarin C (3) as a potential intermediate for the total synthesis of the marine macrolide salarin C (1) is described. The macrolactone core of 3 was assembled by Suzuki coupling between alkyl iodide 9 and vinyl iodide 8 and Shiina macrolactonization as key transformations. All macrocyclic intermediates were found to be of low stability.
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