期刊
ORGANIC LETTERS
卷 20, 期 21, 页码 6877-6881出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02893
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资金
- National Institute of General Medical Science NIGMS [F31GM116532]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [F31GM116532] Funding Source: NIH RePORTER
A cooperative Lewis acid/photocatalytic reduction of arylidene malonates yields a versatile radical anion species. This intermediate preferentially undergoes intermolecular radical-radical coupling reactions, and not the conjugate addition-dimerization reactivity typically observed in the single-electron reduction of conjugate acceptors. Reported here is the development of this open-shell species in intermolecular radical-radical cross couplings, radical dimerizations, and transfer hydrogenations. This reactivity underscores the enabling modularity of cooperative catalysis and demonstrates the utility of stabilized enoate-derived radical anions in intermolecular bond forming reactions.
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