期刊
ORGANIC LETTERS
卷 21, 期 1, 页码 142-146出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03599
关键词
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资金
- National Natural Sciences Foundation of China [21672144]
- Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs [17DZ2260400]
We report an efficient approach for the direct synthesis of alkenylboronates using copper catalysis. The Cu/TEMPO catalyst system (where TEMPO = (2,2,6,6-tetramethylpiperidin-1-yl)oxyl) exhibits both excellent reactivity and selectivity for the synthesis of alkenylboronates, starting from inexpensive and abundant alkenes and pinacol diboron. This approach allows for the direct functionalization of both aromatic and aliphatic terminal alkenes. Mechanistic experiments suggest that the alkenylboronates arise from oxyboration intermediates.
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