期刊
NANO
卷 13, 期 11, 页码 -出版社
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1793292018501321
关键词
Metal-organic frameworks; acid-base bifunctional catalysts; modulated hydrothermal approach; glucose; 5-hydroxymethylfurfural
资金
- National Natural Science Foundation of China [21606100]
- Natural Science Foundation of Jiangsu Province [BK20160498]
The direct synthesis of metal-organic frameworks (MOFs) with acidic and basic active sites is challenging due to the introduction of functional groups by post-functionalization method often jeopardize the framework integrity. Herein, we report the direct synthesis of acid-base bifunctional MOFs with tuning acid-base strength. Employing modulated hydrothermal (MHT) approach, microporous MOFs named UiO-66-NH2 was prepared. Through the ring-opening reaction of 1,3-propanesultone with amino group, UiO-66-NH2-SO3H-type catalysts can be obtained. The synthesized catalysts were well characterized and their catalytic performances were evaluated in one-pot glucose to 5-HMF conversion. Results revealed the acid-base bi-functional catalyst possessed high activity and excellent stability. This work provides a general and economically viable approach for the large-scale synthesis of acid-base bi-functional MOFs for their potential use in catalysis field.
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