期刊
ACS APPLIED MATERIALS & INTERFACES
卷 8, 期 50, 页码 34612-34619出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b08771
关键词
perovskite solar cells; electrical transport layer; fulleropyrrolidinium iodide; stability; hysteresis effect; CH3NH3PbI3
资金
- National Natural Science Foundation of China [61422404]
- Program for Innovation Research Team in University of Ministry of Education of China
- State Key Laboratory of Optoelectronic Materials and Technologies (Sun Yatsen Unversity)
Organic inorganic halide perovskite solar cells have attracted great attention in recent years. But there are still a lot of unresolved issues related to the perovskite solar cells such as the phenomenon of anomalous hysteresis characteristics and long-term stability of the devices. Here, we developed a simple three-layered efficient perovskite device by replacing the commonly employed PCBM electrical transport layer with an ultrathin fulleropyrrolidinium iodide (C-60-bis) in an inverted p-i-n architecture. The devices with an ultrathin C-60-bis electronic transport layer yield an average power conversion efficiency of 13.5% and a maximum efficiency of 15.15%. Steady-state photoluminescence (PL) and time-resolved photoluminescence (TRPL) measurements show that the high performance is attributed to the efficient blocking of holes and high extraction efficiency of electrons by C-60-bis, due to a favorable energy level alignment between the CH3NH3PbI3 and the Ag electrodes. The hysteresis effect and stability of our perovskite solar cells with C-60-bis become better under indoor under indoor humidity conditions.
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