期刊
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS
卷 1847, 期 2, 页码 294-306出版社
ELSEVIER
DOI: 10.1016/j.bbabio.2014.11.006
关键词
Model complex; Nano-sized manganese oxides; Photosystem II; Water oxidation; Water-oxidizing complex
资金
- Institute for Advanced Studies in Basic Sciences
- National Elite Foundation
- JSPS, MEXT, Japan [24370025, 26220801, 24000018]
- Russian Science Foundation [14-14-00039]
- Grants-in-Aid for Scientific Research [24000018] Funding Source: KAKEN
Back to Nature is a promising way to solve the problems that we face today, such as air pollution and shortage of energy supply based on conventional fossil fuels. A Mn cluster inside photosystem II catalyzes light-induced water-splitting leading to the generation of protons, electrons and oxygen in photosynthetic organisms, and has been considered as a good model for the synthesis of new artificial water-oxidizing catalysts. Herein, we surveyed the structural and functional details of this cluster and its surrounding environment. Then, we review the mechanistic findings concerning the cluster and compare this biological catalyst with nano-sized Mn oxides, which are among the best artificial Mn-based water-oxidizing catalysts. (C) 2014 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据