期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 3, 页码 1212-1216出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b12149
关键词
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资金
- Croatian Science Foundation
- Adris foundation
Using tandem in situ monitoring and isotope-labeled solids, we reveal that mechanochemical ball-milling overcomes inherently slow solid-state diffusion through continuous comminution and growth of milled particles. This process occurs with or without a net chemical reaction and also occurs between solids and liquid additives that can be practically used for highly efficient deuterium labeling of solids. The presented findings reveal a fundamental aspect of milling reactions and also delineate a methodology that should be considered in the study of mechanochemical reaction mechanisms.
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