Article
Green & Sustainable Science & Technology
Cristina Oana Stan, Radu Gabriel Pirnau, Bogdan Rosca, Doina Smaranda Sirbu-Radasanu
Summary: The present study investigates the salinization trends of different soil types in the Rosior basin of NE Romania, revealing varying levels of salinity among soil types. The mineralization of soil solution and summer temperatures are identified as the main factors promoting the precipitation of thenardite.
Article
Microbiology
Maurizio Azzaro, Maria Papale, Carmen Rizzo, Emanuele Forte, Davide Lenaz, Mauro Guglielmin, Angelina Lo Giudice
Summary: The study investigated the prokaryotic community associated with mirabilite and thenardite minerals in a glacier salt-cone in Antarctica. It identified bacterial and archaeal lineages that are similar to those found in marine and other saline environments. The study also found members of the community that play a major role in the sulfur cycle.
Article
Mineralogy
Alice Tavares, M. Clara F. Magalhaes, Rosario Soares, Anibal Costa
Summary: This article examines the salt progression and decay patterns in earthen architecture. Through laboratory and in situ tests, the researchers found that the composition of the materials and environmental conditions have an impact on salt effects. The findings contribute to future recommendations for building conservation.
MINERALOGICAL MAGAZINE
(2022)
Article
Materials Science, Multidisciplinary
Mattia Bassi, Enrico Sassoni, Elisa Franzoni
Summary: Salt crystallization is a severe deterioration mechanism affecting heritage materials, but solutions to mitigate this problem are limited. A new biopolymeric treatment based on chitosan, in combination with hydroxyapatite, shows promise in preventing salt damage in porous limestones used in historic architecture. Accelerated salt crystallization tests confirm the effectiveness of the combined treatment.
FRONTIERS IN MATERIALS
(2021)
Article
Spectroscopy
Elliot J. Tay, Jonathan E. Barnsley, Daniel B. Thomas, Keith C. Gordon
Summary: Resonance Raman spectroscopy was used to identify and characterize psittacofulvins, showing different behaviors in red and yellow regions with Raman band wavenumber shifts. One yellow region exhibited similar characteristics to the red regions, suggesting the presence of psittacofulvins with greater conjugation.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Chemistry, Analytical
Yeran Bai, Zhongyue Guo, Fatima C. Pereira, Michael Wagner, Ji-Xin Cheng
Summary: A mid-infrared photothermal-fluorescence in situ hybridization (MIP-FISH) platform is developed for simultaneous identification and metabolic analysis of microbes with single-cell resolution and high throughput. By improving MIP imaging, isotopically labeled compounds incorporated into proteins of individual bacterial cells can be sensitively detected, while FISH labeling with rRNA-targeted probes enables the identification of the analyzed cells. In proof-of-concept experiments, MIP-FISH successfully discriminates and identifies labeled bacterial cells within a complex human gut microbiome sample based on the clear spectral red shift in the protein amide I region caused by incorporation of 13C atoms from 13C-labeled glucose. This study opens up new opportunities for single-cell structure-function analyses in microbiology.
ANALYTICAL CHEMISTRY
(2023)
Article
Multidisciplinary Sciences
Rozeline Wijnhorst, Menno Demmenie, Etienne Jambon-Puillet, Freek Ariese, Daniel Bonn, Noushine Shahidzadeh
Summary: Deliquescence is a first-order phase transition that occurs when salt absorbs water vapor. This process significantly affects the stability of crystalline powders, which are crucial in various fields such as pharmacology, food science, and environmental/climate studies. Through microscopy techniques and Raman spectroscopy, we found that the salt sodium sulfate decahydrate, mirabilite, behaves differently from anhydrous salts during deliquescence. Mirabilite crystals not only lose their facets but also become soft and deformable, exhibiting properties of both crystalline and liquid states. These observations highlight the role of crystalline water and its mobility within the structure in the softness observed during deliquescence. The results have implications for applications such as thermal energy storage, where relative humidity plays a crucial role.
NATURE COMMUNICATIONS
(2023)
Article
Multidisciplinary Sciences
Andreij C. Gadelha, Douglas A. A. Ohlberg, Cassiano Rabelo, Eliel G. S. Neto, Thiago L. Vasconcelos, Joao L. Campos, Jessica S. Lemos, Vinicius Ornelas, Daniel Miranda, Rafael Nadas, Fabiano C. Santana, Kenji Watanabe, Takashi Taniguchi, Benoit van Troeye, Michael Lamparski, Vincent Meunier, Viet-Hung Nguyen, Dawid Paszko, Jean-Christophe Charlier, Leonardo C. Campos, Luiz G. Cancado, Gilberto Medeiros-Ribeiro, Ado Jorio
Summary: The twisted bilayer graphene undergoes self-organized lattice reconstruction, resulting in the formation of a superlattice that modulates vibrational and electronic structures, leading to phenomena such as strong correlations and superconductivity. Although experimental techniques and theoretical models face challenges in observing and describing these effects, nano-Raman spectroscopy can localize some vibrational modes and provide insights into the effects of electron-phonon coupling on the material properties.
Article
Materials Science, Multidisciplinary
Yusi Peng, Chenglong Lin, Yanyan Li, Yong Gao, Jing Wang, Jun He, Zhengren Huang, Jianjun Liu, Xiaoying Luo, Yong Yang
Summary: A highly sensitive semiconductor-based SERS substrate has been developed in this study, which can accurately identify the infectiousness of SARS-CoV-2 virions in actual environments through molecular enrichment and chemical enhancement effects.
Article
Biochemistry & Molecular Biology
Eric Boateng Osei, Liliia Paniushkina, Konrad Wilhelm, Juergen Popp, Irina Nazarenko, Christoph Krafft
Summary: Extracellular vesicles (EVs) ranging in size from 60 to 800 nm were isolated from plasma of control and prostate cancer patients using differential centrifugation and ultrafiltration techniques. Spontaneous Raman and surface-enhanced Raman spectroscopy (SERS) were employed to identify fractions that best discriminate between control and cancer patients, with results showing that EV12 and EV120 fractions provide the most effective separation.
Article
Chemistry, Multidisciplinary
Lanping Zeng, Weiying Song, Xiangfeng Jin, Quanfeng He, Lianhuan Han, Yuan-fei Wu, Corinne Lagrost, Yann Leroux, Philippe Hapiot, Yang Cao, Jun Cheng, Dongping Zhan
Summary: Single layer graphene (SLG) has excellent electron conductivity on its basal plane, but if its band gap could be opened and regulated controllably, it would behave as a semiconductor. By using scanning electrochemical microscopy, researchers demonstrated that electrochemically induced brominating addition reaction can open and regulate the band gap of SLG. This work provides a feasible and effective way to regulate the band gap of SLG, which would open new applications for SLG in micro-nano electronics and ultra-large-scale integrated circuits.
Article
Engineering, Chemical
Zeqiu Li, Eleazer L. Vivas, Chenyang Yang, Yong Jae Suh, Kuk Cho
Summary: Developing adsorbents with fast uptake rates and high adsorption capacities for both Sr2+ and Co2+ is a major challenge for treating radioactive wastewater. Layered potassium calcium phosphate (KCaP) demonstrates excellent adsorption performance and stability in removing Sr2+ and Co2+ from wastewater.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Robin R. Jones, Cornelia Miksch, Hyunah Kwon, Coosje Pothoven, Kristina R. Rusimova, Maarten Kamp, Kedong Gong, Liwu Zhang, Tim Batten, Brian Smith, Alejandro V. Silhanek, Peer Fischer, Daniel Wolverson, Ventsislav K. Valev
Summary: Against the backdrop of current healthcare and climate emergencies, surface enhanced Raman scattering (SERS) is gaining popularity as a technique for identifying and fingerprinting molecules in various substances. Researchers have investigated plasmonic nanohelices and found that they possess excellent SERS properties. These nanohelices can be produced at a low cost, exhibit strong and uniform Raman enhancement effects, and are anticipated to have broad applications in surface enhanced Raman spectroscopies and material science.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Analytical
Xingkang Diao, Xinli Li, Shuping Hou, Haijuan Li, Guohua Qi, Yongdong Jin
Summary: Exosomes are promising noninvasive biomarkers for the early diagnosis and treatment of diseases, especially cancer. However, accurately distinguishing exosomes from clinical samples remains a challenge due to their heterogeneity. In this study, a machine learning-based label-free surface-enhanced Raman spectroscopy method was used to accurately identify exosomes in human serum samples for the diagnosis of breast cancer and cervical cancer.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Analytical
Fanglan Yao, Pengcheng Xu, Hao Jia, Xinyu Li, Haitao Yu, Xinxin Li
Summary: The MEMS TGA technology utilizes temperature programming and microcantilever to achieve ultra-sensitive mass-loss analysis and high-efficiency rapid heating, meeting the higher requirements of TGA.
ANALYTICAL CHEMISTRY
(2022)
Article
Engineering, Aerospace
M. Aznar, A. Sanz-Arranz, S. Shkolyar, E. R. Sawyers, M. Konstantinidis, G. Lopez-Reyes, M. Veneranda, E. A. Lymer, J. R. Freemantle, M. G. Daly, E. A. Cloutisi, F. Rull-Perez, J. Martinez-Frias, E. A. Lalla
Summary: Several space missions have visited and will land on Mars to search for life. The Mars 2020 Perseverance rover and the upcoming ExoMars Rosalind Franklin rover are equipped with Raman spectroscopic systems to identify rocks, minerals, and potential organic biosignatures on the Martian surface. The analysis of data from these missions faces challenges, and studying new volcanic analogues on Earth, such as the Cha similar to das Caldeiras site, can help overcome these challenges. The site exhibits similarities to volcanic places in the Canary Islands and provides pristine samples of volcanic minerals.
ADVANCES IN SPACE RESEARCH
(2023)
Article
Spectroscopy
Imanol Torre-Fdez, Cristina Garcia-Florentino, Jennifer Huidobro, Leire Coloma, Patricia Ruiz-Galende, Julene Aramendia, Kepa Castro, Gorka Arana, Juan Manuel Madariaga
Summary: The presence and geochemical composition of olivine on Mars are important for studying the planet. Raman spectrometers, used in Mars 2020 and future missions, provide new possibilities to determine the Mg/Fe ratios in olivine-bearing rocks. Olivine's presence indicates past volcanic activity on Mars, and its forsterite/fayalite ratio can reveal information about the origin and evolution of the parent magma. This study proposes a new calibration model using Raman spectroscopy, greatly improving the accuracy and uncertainty associated with the forsterite/fayalite ratios compared to previous literature.
JOURNAL OF RAMAN SPECTROSCOPY
(2023)
Article
Geochemistry & Geophysics
E. Clave, K. Benzerara, P. -Y. Meslin, O. Forni, C. Royer, L. Mandon, P. Beck, C. Quantin-Nataf, O. Beyssac, A. Cousin, B. Bousquet, R. C. Wiens, S. Maurice, E. Dehouck, S. Schroeder, O. Gasnault, N. Mangold, G. Dromart, T. Bosak, S. Bernard, A. Udry, R. B. Anderson, G. Arana, A. J. Brown, K. Castro, S. M. Clegg, E. Cloutis, A. G. Fairen, D. T. Flannery, P. J. Gasda, J. R. Johnson, J. Lasue, G. Lopez-Reyes, J. M. Madariaga, J. A. Manrique, S. Le Mouelic, J. I. Nunez, A. M. Ollila, P. Pilleri, C. Pilorget, P. Pinet, F. Poulet, M. Veneranda, Z. U. Wolf
Summary: Perseverance rover explored two geological units in Jezero Crater, revealing the presence of carbonates. These carbonates are identified using spectroscopic techniques and are rare, suggesting a limited carbonation of the rocks in Jezero crater.
JOURNAL OF GEOPHYSICAL RESEARCH-PLANETS
(2023)
Article
Archaeology
Dante Pareja, Javier Inanez, Ayed Ben Amara, Luisa Diaz, Gorka Arana, Remy Chapoulie
Summary: The Ychsma society, developed in Lima, Peru between 900 and 1532 CE, was one of the most significant civilizations in the region. Despite being conquered by the Inca Empire around 1470 CE, the local elites in the Ychsma region maintained their position and control under Inca rule. The archaeological site of Armatambo played a crucial role as an administrative center and controlled a large part of the lower Rimac valley.
JOURNAL OF ARCHAEOLOGICAL SCIENCE-REPORTS
(2023)
Article
Multidisciplinary Sciences
Armando Azua-Bustos, Alberto G. Fairen, Carlos Gonzalez-Silva, Olga Prieto-Ballesteros, Daniel Carrizo, Laura Sanchez-Garcia, Victor Parro, Miguel Angel Fernandez-Martinez, Cristina Escudero, Victoria Munoz-Iglesias, Maite Fernandez-Sampedro, Antonio Molina, Miriam Garcia Villadangos, Mercedes Moreno-Paz, Jacek Wierzchos, Carmen Ascaso, Teresa Fornaro, John Robert Brucato, Giovanni Poggiali, Jose Antonio Manrique, Marco Veneranda, Guillermo Lopez-Reyes, Aurelio Sanz-Arranz, Fernando Rull, Ann M. Ollila, Roger C. Wiens, Adriana Reyes-Newell, Samuel M. Clegg, Maeva Millan, Sarah Stewart Johnson, Ophelie McIntosh, Cyril Szopa, Caroline Freissinet, Yasuhito Sekine, Keisuke Fukushi, Koki Morida, Kosuke Inoue, Hiroshi Sakuma, Elizabeth Rampe
Summary: By studying Red Stone samples formed in the Atacama Desert, scientists have discovered a unique group of microorganisms called "dark microbiome" and identified biosignatures associated with extant and ancient microorganisms. Comparing with minerals on Mars, they found that the organics on the red planet are extremely low and may be difficult to detect with current instruments. Therefore, bringing samples back to Earth for further analysis is crucial in determining the existence of life on Mars.
NATURE COMMUNICATIONS
(2023)
Article
Geography, Physical
Jennifer Huidobro, Julene Aramendia, Gorka Arana, Elisabeth M. Hausrath, Juan Manuel Madariaga
Summary: Raman spectra of gypsum, syngenite, and gorgeyite powders were analyzed at different temperatures. The main bands of the three sulfates shifted towards higher wavenumbers with decreasing temperature, indicating stronger bonds and higher energy. However, the behavior of -OH bands varied depending on the crystal structure acquired at different temperatures. The -OH bands of gypsum became narrower and sharper with decreasing temperature, indicating a more ordered crystalline structure.
ANNALS OF GLACIOLOGY
(2023)
Article
Archaeology
P. Irizar, O. Gomez-Laserna, G. Arana, J. M. Madariaga, I. Martinez-Arkarazo
Summary: This research investigates the potential of agar hydrogels loaded with ionic liquids (ILs) as a sustainable and gentle cleaning method for built heritage conservation. The results demonstrate that ILs can effectively remove iron and copper stains while also inhibiting microbial growth. This study showcases the potential of IL-loaded agar hydrogels as an innovative approach in the field of built heritage conservation.
JOURNAL OF CULTURAL HERITAGE
(2023)
Article
Archaeology
Eugenia Tomasini, Ilaria Costantini, Valeria Careaga, Carlos Rua Landa, Kepa Castro, Juan Manuel Madariaga, Marta Maier, Gabriela Siracusano
Summary: Research on the materiality of Andean Colonial artistic heritage provides insights into the cultural and social history of the region. This study examines a hidden mural painting in a church in Bolivia using interdisciplinary and multi-analytical approaches. The identification of pigments and painting techniques revealed the use of local materials by Andean painters, as well as their adaptation of traditional European practices. This knowledge contributes to the conservation and preservation of similar artworks in the Andean region.
JOURNAL OF CULTURAL HERITAGE
(2023)
Review
Geosciences, Multidisciplinary
Mark A. Sephton, Jonathan S. W. Tan, Jonathan S. Watson, Keyron Hickman-Lewis, Juan M. Madariaga
Summary: The search for organic biomarkers on Mars is a high-priority goal for past, present, and future missions. Thermal extraction is the most popular in situ analysis technique, but it faces challenges when analyzing mineral-organic mixtures. Potential mitigations are suggested for future experiments, which can be used both on Mars and on returned samples on Earth.
JOURNAL OF THE GEOLOGICAL SOCIETY
(2023)
Article
Biochemistry & Molecular Biology
Ilaria Costantini, Julene Aramendia, Nagore Prieto-Taboada, Gorka Arana, Juan Manuel Madariaga, Juan Francisco Ruiz
Summary: In this study, micro-samples from a rock art site in Spain were analyzed to understand the conservation state of the painted panel and to confirm the efficacy of a desalination treatment. Various techniques were used for characterization, revealing the presence of dolomitic limestone, silicon aggregates, aluminosilicates, iron oxides, and sulfate compounds. The analysis also showed evidence of biological activity and the presence of calcium oxalates, which likely contribute to the preservation of the pictographs. The presence of carotenoid pigments and the intentional use of hematite for painting were also identified.
Article
Astronomy & Astrophysics
M. Veneranda, J. A. Manrique, G. Lopez-Reyes, S. Julve-Gonzalez, F. Rull, C. Alvarez Llamas, T. Delgado Perez, E. Gibbons, E. Clave, E. Cloutis, J. Huidobro, K. Castro, J. M. Madariaga, N. Randazzo, A. Brown, P. Willis, S. Maurice, R. C. Wiens
Summary: The SuperCam instrument on Mars 2020 Perseverance rover utilizes multiple spectroscopic techniques to investigate Martian geological targets and proposes the use of multivariate analysis to optimize its capability in discriminating mineral phases. Laboratory study of carbonate phases was conducted and the discrimination capability of Raman, VISIR, and LIBS data sets was evaluated. Low-level and mid-level data combination strategies were utilized to improve mineral classification accuracy.
EARTH AND SPACE SCIENCE
(2023)
Article
Construction & Building Technology
Idoia Etxebarria, Marco Veneranda, Ilaria Costantini, Nagore Prieto-Taboada, Aitor Larranaga, Cristina Marieta, Bruno De Nigris, Alberta Martellone, Valeria Amoretti, Gorka Arana, Juan Manuel Madariaga, Kepa Castro
Summary: The aim of this research is to assess the potential use of ashes and lapilli found in Pompeii as pozzolanic material for conservation mortars. XRD analyses showed that the mineral composition of these volcanic products is similar to the original pozzolanic mortars at the archaeological site. The strength of the lapilli-based mortars was higher than that of commercial pozzolan, and replacing silica sand with volcanic aggregates further improved the mechanical properties.
CASE STUDIES IN CONSTRUCTION MATERIALS
(2023)