4.7 Article

Facile synthesis of hierarchical lychee-like Zn3V3O8@C/rGO nanospheres as high-performance anodes for lithium ion batteries

期刊

JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 533, 期 -, 页码 627-635

出版社

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2018.08.110

关键词

Zn3V3O8@C/rGO; Lychee-like architecture; Ethanol thermal reduction; Lithium-ion batteries

资金

  1. National Natural Science Foundation of China (NSFC) [51502036, U1505241, 21407025, 21307012]
  2. National Key Research and Development Program of China [2016YFB0302303]
  3. Outstanding Youth Research Training Program of University of Fujian Province
  4. Natural Science Foundation of Fujian Province [2016J05116]

向作者/读者索取更多资源

In the present work, the hierarchical Zn3V3O8@C/rGO composite with a unique lychee-like architecture was fabricated by a simple one-pot ethanol thermal reduction strategy. When used as an anode material, it exhibited outstanding electrochemical performance for lithium-ion batteries (LIBs). For instance, the Zn3V3O8@C/rGO composite delivers high reversible capacities (1012 mAh g(-1) at 0.1 A g(-1) after 200 cycles) and high rate stability (448 mAh g(-1) at 4 A g(-1) after 1000 cycles). This outstanding performance can be attributed to the synergistic effect of the diverse structural virtues, effective interface and dual-spatially hybrid carbon network. Significantly, this one-pot simple strategy can be extended to fabricating highly stable and high rate performance of vanadates or other anode materials for LIBs. (C) 2018 Elsevier Inc. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

Facile fabrication of MoS2 nanocrystals confined in waste leather derived N, P co-doped carbon fiber for long-lifespan of sodium/potassium ion batteries

Jingao Zheng, Fuyu Xiao, Hongjun Jin, Changlin Cao, Zewei Lei, Yiyi Wang, Mingdeng Wei, Qingrong Qian, Lingxing Zeng, Qinghua Chen

Summary: This study successfully develops a N/P co-doped carbon fiber composite with MoS2 nanocrystals by using waste leather as the adsorbent and bioreactor. The resulting anode material shows enhanced storage capacity and long cycle life for sodium/potassium-ion batteries. This research provides new insights into the application of waste biomass in energy storage.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2023)

Article Chemistry, Inorganic & Nuclear

Defect-rich WS2-SPAN nanofibers for sodium/potassium-ion batteries: ultralong lifespans and wide-temperature workability

Zewei Lei, Jingao Zheng, Xiaotong He, Yiyi Wang, Xuhui Yang, Fuyu Xiao, Hun Xue, Peixun Xiong, Mingdeng Wei, Qinghua Chen, Qingrong Qian, Lingxing Zeng

Summary: A composite material, WS2-SPAN, consisting of tungsten sulphide encapsulated in a sulphurized polyacrylonitrile, was prepared and exhibited impressive ultralong lifespan and stable circulation capacity over a wide temperature range. The material also showed optimized high-rate performance and ultrastable cycling properties for sodium and potassium storage. The electrochemical storage mechanism of WS2-SPAN composites was elucidated through theoretical calculations and electrochemical dynamics.

INORGANIC CHEMISTRY FRONTIERS (2023)

Article Chemistry, Physical

Multilayer structure covalent organic frameworks (COFs) linking by double functional groups for advanced K plus batteries

Zhihao Su, Jionghao Huang, Runhao Wang, Yi Zhang, Lingxing Zeng, Yufei Zhang, Haosen Fan

Summary: Multilayer structural covalent organic frameworks (COFs) connected by double functional groups have been successfully synthesized. They exhibit excellent potassium storage performance, including high reversible capacity and outstanding cycling stability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Chemistry, Physical

Progressive activation of porous vanadium nitride microspheres with intercalation-conversion reactions toward high performance over a wide temperature range for zinc-ion batteries

Ziyan Yuan, Xuhui Yang, Chuyuan Lin, Peixun Xiong, Anmin Su, Yixing Fang, Xiaochuan Chen, Haosen Fan, Fuyu Xiao, Mingdeng Wei, Qingrong Qian, Qinghua Chen, Lingxing Zeng

Summary: In this work, the morphology of vanadium nitride (VN) was modulated using different molar amounts of cetyltrimethylammonium bromide (CTAB). The optimized electrode exhibited a porous architecture and excellent electrical conductivity, alleviating volume expansion/contraction and enabling fast ion transmission during zinc-ion storage. The CTAB-modified VN cathode underwent a phase transition that provided a better framework for vanadium oxide (VOx), increasing the capacity. The cathode showed excellent electrochemical performance, high cycling stability, and wide temperature range adaptability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Chemistry, Physical

Defect engineering on VO2(B) nanoleaves/graphene oxide for the high performance of cathodes of zinc-ion batteries with a wide temperature range

Ziyan Yuan, Fuyu Xiao, Yixing Fang, Peixun Xiong, Xiaoli Sun, Xuehui Duan, Xuhui Yang, Haosen Fan, Mingdeng Wei, Qingrong Qian, Qinghua Chen, Lingxing Zeng

Summary: In this study, a vanadium dioxide/ graphene oxide (VO2(B)/GO) sample was constructed through hydrothermal route, which exhibited remarkable rate capability. The presence of oxygen vacancies in VO2(B)/GO weakened the electrostatic force, while GO prevented vanadium oxidation. The electrode showed a high reversible capacity of 423 mAh g-1 at 0.5 A g-1 and maintained long-life cycling properties at 15 A g-1. The combination of oxygen vacancies and GO contributed to excellent performance and prevented the collapse of VO2 structure during cycling. VO2(B)/GO also exhibited excellent performance in all-climate conditions (-15-60 degrees C).

JOURNAL OF POWER SOURCES (2023)

Article Chemistry, Physical

Zn3V3O8@ZnO@NC heterostructure for stable zinc ion storage from assembling nanodisks into cross-stacked architecture

Rui Sun, Xincheng Guo, Siyang Dong, Caihong Wang, Lingxing Zeng, Shengjun Lu, Yufei Zhang, Haosen Fan

Summary: In this study, a heterostructure of Zn3V3O8 and ZnO encapsulated in a 3D interpenetrating carbon network (Zn3V3O8@ZnO@NC) was prepared as a cathode material for aqueous zinc-ions batteries (AZIBs). The electrode material exhibited remarkable cycling stability and super-stable rate performance, thanks to the structural stability of the cross-stacked structure and the excellent electrochemical conductivity of the 3D interpenetrating carbon network. The zinc ion storage mechanism of Zn3V3O8@ZnO@NC was revealed through ex-situ XRD and XPS characterizations.

JOURNAL OF POWER SOURCES (2023)

Article Chemistry, Multidisciplinary

Self-Powered Disinfection Using Triboelectric, Conductive Wires of Metal-Organic Frameworks

Zheng-Yang Huo, Yuxin Yang, Jang-Mook Jeong, Xiaoxiong Wang, He Zhang, Mingdeng Wei, Keren Dai, Peixun Xiong, Sang-Woo Kim

Summary: A self-powered water disinfection system, driven by triboelectric nano generators, is presented for efficient water disinfection in rural and disaster-stricken areas lacking power supplies. The system utilizes a flow-driven TENG to generate electricity and a metal-organic framework nanowire array for H2O2 generation and electroporation. The prototype achieves complete disinfection over a wide range of flows with low water flow thresholds, offering promising potential for pathogen control.

NANO LETTERS (2023)

Article Materials Science, Multidisciplinary

Sn-doped induced stable 1T-WSe2 nanosheets entrenched on N-doped carbon with extraordinary half/full sodium/potassium storage performance

Yan-Ru Liu, Ze-Wei Lei, Ren-Ping Liu, Xin-Ye Li, Pei-Xun Xiong, Yong-Jin Luo, Qing-Hua Chen, Ming-Deng Wei, Ling-Xing Zeng, Qing-Rong Qian

Summary: In this study, stable Sn-doped metal phase tungsten selenide (1T-WSe2-Sn) was fabricated using a simple calcination technique. N-doping and Sn-doping were introduced to promote electron/ion transport and improve structural stability. The optimized 1T-WSe2-Sn electrode exhibited remarkable cycling lifespan and rate capability when applied in sodium ion batteries (SIBs) as an anode, as well as in potassium ion batteries (PIBs).

RARE METALS (2023)

Article Chemistry, Physical

Charge-Transfer Complex-Based Artificial Layers for Stable and Efficient Zn Metal Anodes

Peixun Xiong, Chuyuan Lin, Ying Wei, Jung-Hui Kim, Gun Jang, Keren Dai, Lingxing Zeng, Shuping Huang, Seok Joon Kwon, Sang-Young Lee, Ho Seok Park

Summary: In this study, a charge-transfer complex electrolyte additive, 7,7,8,8-tetracyanoquinodimethane (TCNQ), with high affinity for zinc was used to form a dense and robust interfacial complex layer on the zinc anode, suppressing the activity of H(2)O. The complex layer enabled the formation of a Zn-Zn-(TCNQ)(2) Ohmic contact interface, facilitating rapid ion/electron transport, improving electric field distribution, and preventing direct contact between active H2O and the zinc anode, resulting in a dendrite-free zinc anode and efficient zinc plating/stripping kinetics. As a result, the Zn||Zn symmetrical cell exhibited high plating/stripping reversibility for over 1000 hours at 20 mA cm(-2) and 5 mA h cm(-2), and a high depth of discharge of 43%. Furthermore, the Zn||MnO2 full cell demonstrated a high capacity of 143.3 mA h g(-1) at 2000 mA g(-1) even after 4000 cycles, with a capacity retention of 94.7% after returning to 100 mA g(-1).

ACS ENERGY LETTERS (2023)

Article Chemistry, Physical

Selenide-doped bismuth sulfides (Bi2S3-xSex) and their hierarchical heterostructure with ReS2 for sodium/potassium-ion batteries

Jinyi Lin, Shengjun Lu, Yufei Zhang, Lingxing Zeng, Yi Zhang, Haosen Fan

Summary: Selenide-doped bismuth sulfides (Bi2S3-xSex) were prepared to improve electronic conductivity and interlayer spacing. Anisotropic ReS2 nanosheet arrays were grown on the surface of Bi2S3-xSex to form a hierarchical heterostructure (Bi2S3-xSex@ReS2). This strategy greatly improved the electrochemical conductivity and relieved volume expansion during charge/discharge processes, resulting in outstanding battery performance for SIBs and PIBs.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Materials Science, Multidisciplinary

Extraordinarily stable and wide-temperature range sodium/potassium-ion batteries based on 1D SnSe2-SePAN composite nanofibers

Yiyi Wang, Fuyu Xiao, Xi Chen, Peixun Xiong, Chuyuan Lin, Hong-En Wang, Mingdeng Wei, Qingrong Qian, Qinghua Chen, Lingxing Zeng

Summary: The SnSe2-SePAN composite, fabricated through controllable electrospinning and selenylation, exhibits stable and wide-temperature range sodium/potassium storage properties. It demonstrates a high storage capacity and excellent feasibility in a wide working temperature range, delivering an ultralong cycling life even at high current densities. The study breaks new ground in improving the wide temperature workable performance of sodium/potassium storage.

INFOMAT (2023)

Review Energy & Fuels

Progress in Electrolyte Engineering of Aqueous Batteries in a Wide Temperature Range

Lingjun He, Chuyuan Lin, Peixun Xiong, Hui Lin, Wenbin Lai, Jingran Zhang, Fuyu Xiao, Liren Xiao, Qingrong Qian, Qinghua Chen, Lingxing Zeng

Summary: This review discusses recent progress in improving the performance of aqueous batteries, mainly focusing on electrolyte engineering. By reducing the solidification point and boiling point of the electrolyte and enhancing electrochemical performance, the wide temperature range performance of aqueous rechargeable batteries has been improved.

TRANSACTIONS OF TIANJIN UNIVERSITY (2023)

Article Chemistry, Inorganic & Nuclear

Rational construction of VSe2 encapsulated in selenized polyacrylonitrile toward a high-rate capacity and wide temperature tolerance for potassium-ion batteries

Lihong Xu, Jiefeng Ye, Wenti Guo, Tingjie Chen, Xiaochuan Chen, Qingrong Qian, Jianmin Zhang, Mingdeng Wei, Xiangfang Peng, Lingxing Zeng

Summary: In this study, a hybrid material called VSe2/selenized polyacrylonitrile (SePAN) was designed as an anode for potassium-ion batteries. SePAN acts as a dual functional matrix that effectively cushions volumetric variation and provides significant capacity improvement. VSe2 anchored on the SePAN substrate accelerates the reaction kinetics, resulting in excellent energy storage and cycling performance.

INORGANIC CHEMISTRY FRONTIERS (2023)

Article Chemistry, Physical

UV-robust and efficient perovskite solar cells enabled by interfacial photocatalysis suppression and defect passivation

Jingwei Zhu, Xumeng Hu, Zhuoyan Liu, Minghuang Guo, Ying Zhang, Yafeng Li, Junming Li, Mingdeng Wei

Summary: The interfacial photocatalysis of metal oxide electron transport layers (ETLs), especially TiO2, in organometal halide perovskite solar cells (PSCs) has detrimental effects on device stability. A UV absorber, 4,4'-oxybisbenzoic acid (OBBA), was used as a modification layer between TiO2 and perovskite to prevent UV photocatalytic degradation. The modified device showed a high power conversion efficiency (PCE) of up to 22.14% and excellent stability under extreme UV irradiation (365 nm, 600 mW cm(-2); 275 nm, 10 mW cm(-2)).

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Chemistry, Physical

Fine-tuning chemical passivation over photovoltaic perovskites by varying the symmetry of bidentate acceptor in D-A molecules

Minghuang Guo, Jianbin Xu, Jinting Li, Jianting Huang, Jingwei Zhu, Yafeng Li, Peng Gao, Junming Li, Mingdeng Wei

Summary: To improve the performance of perovskite solar cells (PSCs), researchers have used passivators to address the defects of perovskite. In this study, a passivator called TA-MN, which has a symmetric bidentate acceptor, was found to have a strong synergistic passivating ability due to the presence of two symmetric cyano groups (CN). This passivator achieved a higher power conversion efficiency (PCE) of 21.19% compared to the TA-CA passivator (20.54%) and the control group (19.49%). The TA-MN-based PSCs also demonstrated good stability and scalability. These findings provide useful insights for the design of passivators with symmetric bidentate acceptors.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Chemistry, Physical

Mechanistic exploration of Co doping in optimizing the electrochemical performance of 2H-MoS2/N-doped carbon anode for potassium-ion battery

Panpan Zhang, Xu Wang, Yangyang Yang, Haifeng Yang, Chunsheng Lu, Mingru Su, Yu Zhou, Aichun Dou, Xiaowei Li, Xiaochuan Hou, Yunjian Liu

Summary: In this study, the influence of transition metal doping on the electronic and mechanical properties and electrochemical performance of 2HMoS2/NC was investigated using Cobalt (Co) as an example. Co doping was found to effectively improve the electronic conductivity and active site areas of 2H-MoS2/NC at different positions, optimizing the adsorption and diffusion capability of potassium ions. Furthermore, the study revealed the optimal roles of different types of nitrogen atoms in kinetic adsorption, diffusion, and interfacial stability of potassium ions. These findings provide guidance for the experimental design of high rate 2H-MoS2/NC electrode materials and the optimal design of other functional composite materials.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Addressing the synchronized impact of a novel strontium titanium over copolymerized carbon nitride for proficient solar-driven hydrogen evolution

Zeeshan Ajmal, Mahmood Ul Haq, Shahid Zaman, M. K. Al-Muhanna, Anuj Kumar, Mohammed M. Fadhali, Siwar Ben Hadj Hassine, Muhammas Qasim, K. F. Alshammari, Ghulam Abbas Ashraf, Abdul Qadeer, Adil Murtaza, Sulaiman Al-Sulaimi, Huaqiang Zeng

Summary: This study presents a novel heterojunction structure (SrTiO3/CN-TAL10.0) for enhanced photocatalytic water splitting (PWS). The incorporation of thiophenedicarboxaldehyde (TAL) through copolymerization significantly improves the photocatalytic activity of carbon nitride (CN) while maintaining its photostability performance. The optimized composition allows efficient isolation of photoinduced charge carriers and enhanced charge transport, resulting in a remarkable increase in overall photocatalytic efficiency.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Magnetic-driven Interleukin-4 internalization promotes magnetic nanoparticle morphology and size-dependent macrophage polarization

Angela Arnosa-Prieto, Patricia Diaz-Rodriguez, Manuel A. Gonzalez-Gomez, Pelayo Garcia-Acevedo, Lisandra de Castro-Alves, Yolanda Pineiro, Jose Rivas

Summary: Macrophages can exhibit different phenotypes depending on the microenvironment and the characteristics of magnetic iron oxide nanoparticles (MNPs). This study demonstrates that the concentration and morphology of MNPs can influence the polarization of macrophages. The findings have implications for therapeutics targeting tissue regeneration and tumor progression.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Polyamide nanofiltration membranes by vacuum-assisted interfacial polymerization: Broad universality of Substrate, wide window of monomer concentration and high reproducibility of performance

Yu Fang, Cheng-Ye Zhu, Hao-Cheng Yang, Chao Zhang, Zhi-Kang Xu

Summary: This study demonstrates the advantages of vacuum-assisted interfacial polymerization (VAIP) in fabricating polyimide nanofiltration membranes. By using vacuum filtration, aqueous solutions of PIP can be evenly distributed on different microfiltration substrates, leading to the fabrication of uniform and ultra-thin polyamide layers with excellent performance. The membranes exhibit high rejection rates and water permeance, as well as satisfactory long-term stability.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Comparing polymer-surfactant complexes to polyelectrolytes

Isaac J. Gresham, Edwin C. Johnson, Hayden Robertson, Joshua D. Willott, Grant B. Webber, Erica J. Wanless, Andrew R. J. Nelson, Stuart W. Prescott

Summary: Understanding the interactions between polymers and surfactants is crucial for optimizing commercial systems. This study tested the behavior of polymer-surfactant systems, revealing that they do not behave like polyelectrolytes in the presence of salt. Additionally, the structure of polymer-surfactant complexes under confinement differs from that of polyelectrolytes.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Crosslinking alginate at water-in-water Pickering emulsions interface to control the interface structure and enhance the stress resistance of the encapsulated probiotics

Yunxiao Xie, Cui Liu, Jie Zhang, Yan Li, Bin Li, Shilin Liu

Summary: This study aimed to improve the microstructure and rheological properties of W/W Pickering emulsions by crosslinking sodium alginate at the water-water interface, thereby enhancing the activity of encapsulated probiotics in simulated gastrointestinal digestion.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Multi-layering of carbon conductivity enhancers for boosting rapid recharging performance of high mass loading lithium ion battery electrodes

Sang Ho Lee, Yige Sun, Patrick S. Grant

Summary: This research developed an effective approach to enhance the charging rates of lithium ion batteries (LIBs) by strategically incorporating carbon nanotube (CNT) conductivity boosters into Li4Ti5O12 (LTO) electrodes. Multi-layer architectures comprising CNT-rich and CNT-free LTO electrode layers were manufactured using a layer-by-layer spray coating method to promote charge transfer kinetics of high mass loading electrodes. The best performing multi-layer was paired with a spray-coated LiFePO4 (LFP) positive electrode, resulting in attractive power performance that outperformed conventional LTO || LFP combinations.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Defect engineering induces Mo-regulated Co9Se8/FeNiSe heterostructures with selenium vacancy for enhanced electrocatalytic overall water splitting in alkaline

Jingwei Liang, Shaobin Li, Fengbo Li, Li Zhang, Yufeng Jiang, Huiyuan Ma, Kun Cheng, Liang Qing

Summary: A molybdenum-regulated self-supporting electrode material with rich vacancy defects has been successfully synthesized and shows exceptional catalytic activities and stability for electrocatalytic overall water splitting. This study provides a new perspective for the design and synthesis of non-precious metal bifunctional electrocatalysts.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Surfactant-free microemulsions (SFMEs) as a template for porous polymer synthesis

Jonas Blahnik, Jennifer Schuster, Rainer Mueller, Eva Mueller, Werner Kunz

Summary: This study investigates the relationship between the morphology of PMMA monopolymers and PMMA-PHEMA copolymers with the expected nature of surfactant-free microemulsions (SFMEs) before polymerization. It is found that previously mesostructured, surfactant-free mixtures can produce porous polymers of different morphologies, while unstructured, oil-rich regions lead to solid, transparent polymers without nanostructured morphologies. Additionally, a surfactant-based reference system shows similar phase behavior and polymer morphologies as the comparable surfactant-free system, indicating the importance of the hydrotropic behavior of HEMA in this system.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Morphology regulation of isomeric covalent organic frameworks for high selective light scattering detection of lead

Zheng-Fen Pu, Wen-Zhi She, Rong Sheng Li, Qiu-Lin Wen, Bi-Chao Wu, Chun-Hua Li, Jian Ling, Qiue Cao

Summary: This study synthesized two framework-isomeric covalent organic frameworks (COFs) and discovered that the light scattering signal of COFs can be used for the analytical detection of lead ions. By controlling synthesis conditions and introducing regulators, the morphology of COFs could be controlled and framework-isomeric COFs could be precisely synthesized.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Preparation and dynamic color-changing study of fluorescent polymer nanoparticles for individualized and customized anti-counterfeiting application

Yuchen Weng, Ying Hong, Jingyu Deng, Sicheng Cao, Li-Juan Fan

Summary: This paper reports the preparation of dynamic color-changing fluorescent polymer nanoparticles (PNPs) by constructing a fluorescence resonance energy transfer (FRET) pair. The PNPs show excellent anti-counterfeiting effects and reproducibility. The study demonstrates a promising encryption strategy that can achieve multiple outputs with simple operation.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Employing polyaniline/viologen complementarity to enhance coloration and charge dissipation in multicolor electrochromic display with wide modulation range

Guodong Liu, Zijian Wang, Jianing Wang, Hanbin Liu, Zhijian Li

Summary: This study investigates the combination of multicolor switchable polyaniline (PANI) electrode and 1-methyl-4,4'-bipyridyl iodide (MBI), which demonstrates superior optical properties in visible and near-infrared light modulation, as well as excellent electrochemical performances. This combination can be used to develop novel electrochromic devices for applications in smart packaging, smart labels, and flexible smart windows.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Facile constructing Ti3C2Tx/TiO2@C heterostructures for excellent microwave absorption properties

Huying Yan, Yang Guo, Xingzhi Bai, Jiawei Qi, Haipeng Lu

Summary: By modifying Ti3C2Tx through heterogeneous interface engineering, optimized impedance matching is achieved, leading to enhanced electromagnetic wave absorption performance.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Reversible crowdedness of pH-responsive and host-guest active polymersomes: Mimicking μm-sized cell structures

Kehu Zhang, Yang Zhou, Silvia Moreno, Simona Schwarz, Susanne Boye, Brigitte Voit, Dietmar Appelhans

Summary: This article presents an advanced crosslinking strategy to fabricate clustered polymersomes using host-guest interactions. By controlling the input of crosslinker and environmental conditions, reversible aggregation and disassembly of these polymersomes can be achieved. The size and structure of these clustered polymersomes can be regulated and visualized through a fluorescent enzymatic cascade reaction.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)

Article Chemistry, Physical

Potassium regulating electronic state of zirconia supported palladium catalyst and hydrogen spillover for improved acetylene hydrogenation

Junjie Xu, Weixiong Huang, Ruiling Li, Li Li, Jinjin Ma, Jiaou Qi, Haiyan Ma, Min Ruan, Lilin Lu

Summary: In this study, a potassium doped palladium catalyst was developed for acetylene hydrogenation, showing excellent catalytic performance and durability. The doping of potassium effectively weakened the adsorption of ethylene, improved ethylene selectivity, and lowered the barriers of hydrogen activation and transfer reactions.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2024)