Article
Thermodynamics
Jing Li, Qiang Wang, Luoyang Tian, Zhansheng Li, Yanrui Li, Yanbiao Hu, Bo Wang
Summary: A series of thermodynamic parameters of N-hexylpyridinium bromide ionic liquid were investigated using inverse gas chromatography technique. The results show that the addition of N-hexylpyridinium bromide can break the azeotropy of certain binary mixtures.
FLUID PHASE EQUILIBRIA
(2022)
Article
Chemistry, Analytical
Qiuchen Huang, Zhiqiang Cai, Ruonan Chen, Wei Zhang, Donatella Nardiello, Maurizio Quinto, Xianming Liu, Shaoqiang Hu, Tao Sun
Summary: In this study, a novel compound TCP-Bim was designed, synthesized, and used as the stationary phase for capillary gas chromatography. It showed moderate polarity and high efficiency, resulting in high resolutions and excellent separation capabilities compared to other columns.
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Physical
Ayse Erdogan Cakar, Fatih Cakar, Hale Ocak, Selvi Karavelioglu, Belkiz Bilgin Eran, Ozlem Cankurtaran
Summary: This study presents the synthesis and characterization of two new calamitic liquid crystals, and investigates their liquid crystal behavior using microscopy and calorimetry techniques. The surface properties and separation power of the liquid crystals are determined using suitable solvents, and the specific adsorption enthalpy and free energy are measured. The results indicate that all the liquid crystals possess basic character.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Biochemical Research Methods
Donghyun Ryoo, Philip Eor, Jason E. Bara, Jared L. Anderson
Summary: Silver(I) ions have been utilized in the separation of olefins from paraffins by incorporating them into polymer membranes or ionic liquids (ILs). It was found that olefins were highly retained by silver(I) ions in polymeric ionic liquids (PILs) compared to ILs, and this retention increased with higher concentration of silver(I) salt in the stationary phase. The potential for comprehensive two-dimensional gas chromatography (GC x GC) using silver(I)-containing IL and PIL stationary phases to enhance separation selectivity was also demonstrated.
JOURNAL OF CHROMATOGRAPHY A
(2023)
Article
Chemistry, Physical
Yanrui Li, Qiang Wang, Xiaoping Li, Zhansheng Li, Jing Li, Yanbiao Hu, Bo Wang
Summary: The interaction between N-octyl pyridinium hexafluorophosphate ionic liquid and solvents was evaluated using inverse gas chromatography, and the isothermal vapor-liquid equilibrium data was derived based on the experimental results, which is of great significance for modeling.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Biochemical Research Methods
J. F. Ayala-Cabrera, C. Lipok, J. Li, E. Moyano, O. J. Schmitz, F. J. Santos
Summary: The study evaluated the performance of comprehensive two-dimensional gas chromatography coupled to mass spectrometry (GCxGC-MS) for the separation of polychlorinated naphthalenes (PCNs), achieving efficient separation and surpassing traditional gas chromatography methods.
JOURNAL OF CHROMATOGRAPHY A
(2021)
Article
Chemistry, Physical
A. Hafizi, M. Rajabzadeh, M. H. Mokari, R. Khalifeh
Summary: The study successfully synthesized an innovative tricationic ionic liquid and found its potential application in carbon dioxide absorption. The research results show that the absorption performance of this ionic liquid at different pressures is affected by absorption temperature and ionic liquid concentration.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Hassiba Benguergoura, Amina Allel, Waseem Sharaf Saeed, Taieb Aouak
Summary: Capillary column inverse gas chromatography (CCIGC) was used to study the thermodynamic properties of SBR and various molecules, showing both agreement and discrepancies with literature values. Significant differences were also observed in literature values obtained by different authors, likely due to experimental errors. Activity coefficients of solvents at infinite dilution were calculated and compared using different models.
ARABIAN JOURNAL OF CHEMISTRY
(2021)
Review
Chemistry, Inorganic & Nuclear
Anna A. Kotova, Didier Thiebaut, Jerome Vial, Antoine Tissot, Christian Serre
Summary: Analytical chemistry is crucial for separating complex mixtures, and Metal-organic frameworks (MOFs) are promising porous hybrid solids with unique physico-chemical properties, which can be applied in chromatography and solid-phase extraction to address challenges in these fields.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Biochemical Research Methods
Azam Gholizadeh, Mustahsin Chowdhury, Masoud Agah
Summary: This study investigates the impact of stationary phase coating on the separation efficiency of gas chromatography microcolumns, finding that higher temperature treatment can improve efficiency but may reduce peak symmetry, with the thermally treated stationary phase at 240 degrees Celsius demonstrating significantly higher efficiency and resolution.
JOURNAL OF CHROMATOGRAPHY A
(2021)
Article
Engineering, Chemical
C. Peppersack, F. Flach, P. Prziwara, C. Damm, S. Breitung-Faes, W. Peukert, A. Kwade
Summary: The choice of stabilizers for preventing particle agglomeration during nanomilling is a complex process. This study shows how the selection of polymeric stabilizers can be narrowed down based on Hansen solubility parameters, and the importance of solubility parameter difference in achieving colloidal stability.
ADVANCED POWDER TECHNOLOGY
(2023)
Article
Biochemical Research Methods
Philip Eor, Nicholas Tryon-Tasson, Jared L. Anderson
Summary: The selectivity of olefin/paraffin offered by IL stationary phases can be improved by adding silver(I) ion, but silver(I) ion is prone to reduction, leading to a loss of chromatographic selectivity. This study investigates the effects of temperature, hydrogen content, and exposure time on the olefin selectivity of silver(I) ion/IL stationary phases.
JOURNAL OF CHROMATOGRAPHY A
(2023)
Article
Chemistry, Physical
Bakusele Kabane, Vasanthakumar Arumugam, Gan G. Redhi
Summary: A novel ionic liquid was investigated for its potential use in industrial separation processes. Experimental and computational methods were employed to analyze the molecular interactions between the ionic liquid and various solutes, and to calculate the separation parameters and excess thermodynamic properties. The results showed that the ionic liquid is suitable for the separation of close boiling point mixtures in industrial settings, and may be applicable for the separation of azeotropic mixtures.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Analytical
Xuemei Dai, Jingqiu Zhou, Honglin Yang, Meijun Wan, Yunchao Zheng, Jing Ou, Yaxin Yang, Meifang Liao, Lujun Wang
Summary: Two stationary phases, Sil-styrene and Sil-PAS, were synthesized using click chemistry. The prepared columns showed better separation effects compared with traditional commercial columns in reversed-phase and hydrophilic interaction separation modes. The amino groups on the benzene ring were found to affect the hydrophilic and hydrophobic interactions with analytes, and the Sil-styrene column showed great potential for the separation of PAHs in actual samples.
MICROCHEMICAL JOURNAL
(2022)
Article
Biochemistry & Molecular Biology
Aline Zambom, Sergio M. Vilas-Boas, Liliana P. Silva, Monia A. R. Martins, Olga Ferreira, Simao P. Pinho
Summary: The potential of methylimidazolium-based ionic liquids (ILs) as solvents for terpene fractionation and fuel processing was studied. The results showed that ILs with long alkyl chains as cations can enhance the capacity, while the selectivity depends on the solute polarity.
Article
Engineering, Chemical
Mojtaba Mirzaei, Babak Mokhtarani, Alireza Badiei, Ali Sharifi
CHEMICAL ENGINEERING & TECHNOLOGY
(2018)
Article
Chemistry, Multidisciplinary
Ali Sharifi, Maryam Moazami, M. Saeed Abaee, Mojtaba Mirzaei
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
(2020)
Article
Engineering, Chemical
Erfaneh Faghihi, Babak Mokhtarani, Hamid Reza Mortaheb, Kourosh Tabar Heydar, Mojtaba Mirzaei, Ali Sharifi
CHEMICAL ENGINEERING & TECHNOLOGY
(2020)
Article
Engineering, Electrical & Electronic
Reza Peymanfar, Elnaz Selseleh-Zakerin, Ali Ahmadi, Ali Sharifi, Mohammad M. Mojtahedi
Summary: This research focused on the synthesis of La0.8Sr0.2FeO3/cauliflower-like polyaniline (PANi) nanocomposite using dodecylbenzenesulfonic acid as a doping agent. The structure was characterized using various analytical techniques, showing that pure materials were successfully synthesized. The interactions between nanoparticles and aniline monomers led to the unique morphology of the nanocomposite, while the addition of PANi enhanced the softness and isotropic magnetic property, making it suitable for microwave absorption. Results showed that the nanocomposite exhibited desirable microwave absorption properties with improved bandwidth.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Engineering, Environmental
Reza Peymanfar, Ali Ahmadi, Elnaz Selseleh-Zakerin, Arezoo Ghaffari, Mohammad M. Mojtahedi, Ali Sharifi
Summary: In this study, a novel wrinkled Ni nanosheet/graphene carbon microsphere (CMS) nanocomposite was fabricated and its microwave absorbing characteristics were investigated with different absorbing mediums. The results showed that the nanocomposite exhibited excellent performance in microwave absorption and shielding, indicating the significant influence of the absorbing medium on microwave characteristics.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Milad Damanafshan, Babak Mokhtarani, Mojtaba Mirzaei, Ali Sharifi
Summary: The solubility of CO2 was measured in hybrid solvents composed of aqueous MDEA blended with IL at different temperatures and pressures. Increasing the IL concentration in the absorbent solutions led to a gradual enhancement of the dissolved CO2 gas. The experimental data showed that the hybrid solvents based on MDEA and IL exhibited better CO2 loading capacity compared to pure ILs and alkanolamine solvents. Additionally, a semi empirical model was used to correlate the solubility data, showing good agreement with an absolute average deviation below 1%.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Radman Hosseinzadeh Semnani, Mahsa Baghban Salehi, Babak Mokhtarani, Ali Sharifi, Mojtaba Mirzaei, Vahid Taghikhani
Summary: This study investigates the performance of novel ionic liquids in a lab-scale Enhanced Oil Recovery (EOR) setup compatible with Iranian oil reservoir conditions. The results demonstrate the resistance of these ionic liquids to harsh reservoir conditions and their potential to improve oil field production efficiency.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Applied
Mojtaba Mirzaei, Sara Hekmat Shoar, Ali Sharifi, M. Saeed Abaee
Summary: The sorption performances of CO2 and N-2 were studied in neat and mesoporous silica supported ionic liquids. The immobilization of ionic liquids onto silica was achieved via wet impregnation-vaporization method. The highest sorption capacities were observed in [C(6)mim][NO3] and (MCM-41)-[C(10)mim][NO3](20). The impregnated solid supported ionic liquids showed a decrease in mesoporosity but an increase in CO2/N-2 selectivity compared to blank solid supports.
JOURNAL OF POROUS MATERIALS
(2023)
Article
Chemistry, Physical
Mojtaba Mirzaei, Ali Sharifi, M. Saeed Abaee
Summary: The solubility of CO2 and CH4 in the ionic liquid 1-benzyl-3-methylimidazolium nitrate ([Bzmim][NO3]) was measured at temperatures ranging from 298.15 to 343.15 K and pressures up to 4.52 MPa for CO2 and 4.22 MPa for CH4. The results showed that CO2 had a significantly higher solubility than CH4 under the experimental conditions. The solubility of CO2 decreased with increasing temperature, while the solubility of CH4 slightly increased.
JOURNAL OF SUPERCRITICAL FLUIDS
(2023)
Article
Materials Science, Multidisciplinary
Morteza Mostashregh, Maryam Khavarpour, Seyed Mohammad Vahdat, Ali Sharifi, Mohammad Ansari, Saghi Sepehri
Summary: This study synthesized a series of novel compounds with biological activities and lower side effects, including 1,4-Benzothiazinone as a new anti-algae product and antibacterial agent to reduce the destructive effects of algae on industrial equipment. Benzothiazinone derivatives were rapidly and environmentally friendly synthesized using the reaction of 2-aminothiophenols and 2-bromoalkanoates, ball milling technique, and solvent-free conditions. The produced compounds showed significant growth inhibition on Spirulina platnesis and excellent activity against Gram-positive bacteria compared to traditional antibiotic (amikacin). In vitro and in silico experiments confirmed the findings.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Organic
Ali Sharifi, Maryam Moazami, Mohammad Saeed Abaee, Mojtaba Mirzaei
Summary: A convenient method for the synthesis of target molecules under mild conditions has been developed using an oxidative dehydrogenative coupling reaction. The ionic liquid used in the reaction can be recycled without losing its efficiency.
HETEROCYCLIC COMMUNICATIONS
(2022)
Article
Chemistry, Organic
Ali Sharifi, Maryam Moazami, Zahra Babaalian, M. Saeed Abaee, Mojtaba Mirzaei
Article
Chemistry, Organic
Ali Sharifi, Zahra Babaalian, M. Saeed Abaee, Maryam Moazami, Mojtaba Mirzaei
Summary: A novel C(sp(3))-C(sp(2)) cross-dehydrogenative-coupling method was developed in this work for reacting benzoxazin-2-one derivatives with various indoles, resulting in rapid coupling and good yields of desired compounds. The use of ball milling and Fe(II) catalysis allowed for the smooth coupling of derivatives of both starting materials under relatively mild conditions.
HETEROCYCLIC COMMUNICATIONS
(2021)
Article
Chemistry, Analytical
Maryam Kargar, Hossein Reza Darabi, Ali Sharifi, Abdoljalit Mostashari
Article
Chemistry, Multidisciplinary
Nazafarin Assadollahnejad, Maryam Kargar, Hossein Reza Darabi, Negar Abouali, Shadi Jamshidi, Ali Sharifi, Kioumars Aghapoor, Hani Sayahi
NEW JOURNAL OF CHEMISTRY
(2019)