期刊
JOURNAL OF CATALYSIS
卷 368, 期 -, 页码 145-154出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2018.10.004
关键词
Hydration; Epoxides; Alkynes; Zeolites; Hydrophobic interaction; Aqueous media
资金
- JSPS KAKENHI from the Japan Society for the Promotion of Science (JSPS) and [17H01341, 181(14051, 18K14057]
- Japanese Ministry of Education, Culture, Sports, Science, and Technology (MEXT)
- JST-CREST [JPMJCR17J3]
- Grants-in-Aid for Scientific Research [18K14057, 17H01341] Funding Source: KAKEN
We investigated the hydration of hydrophobic epoxides and alkynes in water using 24 types of heterogeneous and homogeneous catalysts and found that Hbeta (H beta) zeolite with a relatively high Si/Al ratio (Si/Al = 75), H beta-75, is an effective catalyst. H beta-75 showed wide substrate scope, good reusability, and applicability in gram-scale synthesis for both types of reactions. The effects of hydrophobicity, acidity, and the size of zeolite pores were also comprehensively studied through the hydration of hydrophilic and hydrophobic epoxides and alkynes with different molecular sizes using two types of zeolite (H beta and HZSM5). The high yields obtained using the H beta-75 catalyst in the hydration of hydrophobic epoxides and alkynes are attributed to the hydrophobic interaction between zeolite pores with the substrates, as well as the relatively large pore size. (C) 2018 Elsevier Inc. All rights reserved.
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