Article
Materials Science, Ceramics
Burak Cagri Ocak, Gultekin Goller
Summary: Monolithic B4C and B4C-based ceramics incorporating FeNiCoCrMo dual-phase high entropy alloys (HEAs) were produced by spark plasma sintering (SPS) in this study. The addition of HEAs enhanced the densification behavior and increased the hardness and fracture toughness values of the samples. The highest density and the best mechanical properties were achieved with 2.00 vol.% HEA addition.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2021)
Article
Materials Science, Ceramics
Bo Wang, Delong Cai, Haoyi Wang, Wenhua Zou, Zhihua Yang, Xiaoming Duan, Peigang He, Daxin Li, Wenjiu Duan, Dechang Jia, Hua-Tay Lin, Chao Zhao, Yu Zhou
Summary: Boron carbide (B4C) ceramic composites with excellent mechanical properties were fabricated using B4C, silicon carbide (SiC), titanium boride (TiB2), and magnesium aluminum silicate (MAS) as raw materials. The influences of SiC and TiB2 content on the microstructural evolution and mechanical properties of the composites were investigated. MAS in the composites effectively removes oxide layers from ceramic particles during high temperature sintering. The toughening mechanism of the composites is mainly attributed to crack deflection along the grain boundary caused by thermal expansion mismatch between B4C and TiB2.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Ceramics
Revathi Gorle, K. Vasanthakumar, Srinivasa R. Bakshi
Summary: Sintering of pure B4C requires extremely high temperatures, but in this study, sintering at low temperature was achieved using a reactive Ti-B mixture as a sintering additive. The resulting B4C composite compacts had a pore free microstructure with improved hardness.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
R. Mnatsakanyan, D. Davtyan, T. Minasyan, S. Aydinyan, I Hussainova
Summary: The research successfully developed a high density B4C-ReB2 composite material using microwave synthesis and spark plasma sintering, making it a superhard material due to its high hardness. The fractured surfaces demonstrate the complete denseness of the composite material.
Article
Materials Science, Ceramics
Zeynep Ayguzer Yasar, Richard A. Haber
Summary: Fully dense boron carbide-silicon carbide composites were successfully produced by spark plasma sintering method, wet mixing method provided better uniformity and consistency in material properties.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Shuai Wang, Mingsheng Yang, Huaiqian Li, Luyao Wang, Hong Wang, Pengfei Xing, Yanxin Zhuang
Summary: In this study, boron carbide (B4C) matrix composites were improved by designing and fabricating B4C-SiC-SiB6-CeB6 composites with novel additives, achieving enhanced comprehensive properties. The addition of CeO2 played a crucial role in the microstructure and mechanical properties of the composites.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Ceramics
Wei Chen, Hao Wenhui, Ziqiang Zhao, Nairu He, Li Xiuqing, Huaqiang Li
Summary: The mechanical properties and tribological characteristics of boron carbide ceramic were improved by adding silicon carbide as an incorporation phase. The ceramic composite with 20 wt.% SiC content exhibited higher bending strength, lower friction coefficient, and lower wear rate under seawater lubrication. The excellent tribological performance was attributed to lubricating, cooling of seawater, and tribochemical reaction.
JOURNAL OF ASIAN CERAMIC SOCIETIES
(2021)
Article
Materials Science, Ceramics
Wen Zheng, Jia-Min Wu, Shuang Chen, Kang-Bo Yu, Jie Zhang, Heng Liu, Shi-Feng Wen, Chun-Ze Yan, Yu-Sheng Shi
Summary: In this study, silica-based ceramic cores with B4C addition were prepared by selective laser sintering (SLS) and SiO2-Al2O3 sol infiltration. The effects of B4C content and mass ratio of alumina to silica in the SiO2-Al2O3 sol on the mechanical properties of the obtained silica-based ceramic cores were explored. The results showed that the room temperature and high temperature flexural strength improved with the addition of B4C and the generated mullite phase, while the linear shrinkage decreased.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Beidi Chen, Nianyao Chai, Jinyong Zhang, Lin Ren, Weimin Wang, Fan Zhang, Xuewen Wang, Zhengyi Fu
Summary: In this paper, a novel approach to create hierarchical micro-nano surface structures on B4C using femtosecond laser irradiation is proposed. The results show that the phase structure of the sample changes after irradiation, and the wetting performance of the solution on B4C is significantly improved. This work provides a new idea for enhancing the wetting of metal/ceramic systems.
APPLIED SURFACE SCIENCE
(2023)
Article
Microscopy
K. Baranidharan, S. Thirumalai Kumaran, M. Uthayakumar, P. Parameswaran, D. Arvindha Babu
Summary: The present study focuses on the microstructural evolution of 316 stainless steel with 10 wt% of B4C samples sintered at temperatures of 800, 900, and 1000 degrees C using the Spark Plasma Sintering method. The results show that the samples sintered at 900 degrees C have a higher degree of recrystallization compared to those sintered at 800 and 1000 degrees C. This can be explained by the increase in carbon content, which reduces grain boundaries and decreases the migration rate of twin boundary generation. The experimental investigation suggests that the samples sintered at 900 degrees C have a more favorable microstructure analysis.
Article
Materials Science, Multidisciplinary
Dayu Shu, Xiuqing Li, Qingxia Yang
Summary: Adding boron carbide ceramics to a copper base improves the mechanical properties and wear resistance of pure copper. The B4C content affects the hardness, density, conductivity, and wear resistance of the composites. The Cu-15 wt.% B4C composite shows the best performance among the tested materials.
Article
Materials Science, Multidisciplinary
Ghada Almisned, Kadir Gunoglu, Hatice Varol Ozkavak, Duygu Sen Baykal, H. O. Tekin, Nurdan Karpuz, Iskender Akkurt
Summary: Researchers developed a multi-layered composite material (Al/B4C) to enhance the capabilities of shielding materials and broaden their applications in space sciences and cosmic radiation. Different multi-layered Al-B4C shield samples were manufactured through powder metallurgy method, and their performance was experimentally investigated. The study showed that the geometric configuration played a crucial role in the shielding efficiency of multi-layered materials.
MATERIALS TODAY COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Alexandre Brillon, Justo Garcia, Fanny Riallant, Christian Garnier, Anne Joulain, Yongfeng Lu, Jean-Francois Silvain
Summary: Aluminum matrix composites with boron carbide reinforcements were fabricated using solid state powder metallurgy and hot-pressing process. The incorporation of B4C particles up to 12% increased the hardness and strain hardening threshold of the composite material, but decreased ductility. The thermal conductivity and coefficient of thermal expansion also decreased with an increase in B4C volume fraction.
JOURNAL OF NUCLEAR MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Mahmut Can Senel, Yusuf Kanca, Mevlut Gurbuz
Summary: The fabrication of boron carbide reinforced aluminum matrix composites with different contents of B4C was studied using powder metallurgy. The composites with 30wt% B4C exhibited the best mechanical and tribological properties, including high density, low porosity, high hardness, low weight loss, and low specific wear rate.
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Mengdong Ma, Rongxin Sun, Lei Sun, Yingju Wu, Pan Ying, Yanhui Chu, Zhisheng Zhao, Zhenhui Kang, Julong He
Summary: A core-shell structured B4C nanopowder, Si as a sintering aid additive, and high-pressure sintering technique were used to process nanocrystalline B4C-SiC ceramics with improved mechanical properties. The addition of Si reacted with carbon layer and nanoshell to form dispersed SiC nanocrystals and Si-C phase. Furthermore, deflection of nanoscale cracks and covalent bonding at grain boundaries were responsible for the superior performance in hardness and fracture toughness.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Materials Science, Ceramics
Shengnan Jiang, Shuaibo Gao, Yang Liu, Xiaohua Cui, Xing Tin, Donghui Wei, Man Kong, Pengfei Xing
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2020)
Article
Materials Science, Ceramics
Xin Li, Minjun Lei, Shuaibo Gao, Dan Nie, Kun Liu, Pengfei Xing, Shu Yan
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2020)
Article
Materials Science, Ceramics
Xin Li, Minjun Lei, Shuaibo Gao, Shu Yan, Xiaofeng Wang, Pengfei Xing
ADVANCES IN APPLIED CERAMICS
(2019)
Article
Materials Science, Ceramics
Shuai Wang, Lamei Li, Pengfei Xing, Shu Yan, Qi Wu, Shuaibo Gao, Dan Nie
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2020)
Article
Materials Science, Ceramics
Shuai Wang, Yangyang Deng, Shuaibo Gao, Mingsheng Yang, Pengfei Xing
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2020)
Article
Materials Science, Ceramics
Shuaibo Gao, Shengnan Jiang, Pengfei Xing
Summary: Fe-containing additives, especially Fe(NO3)(3), have been found to have a significant impact on recycling silicon cutting waste (SCW) to synthesize high-purity SiC. Fe(NO3)(3) can effectively reduce the activation energy for reactions and promote material transport, dissolution, and precipitation due to the formation of FeSi melt at low temperatures. Optimal processing conditions include 1-3 wt.% Fe(NO3)(3) addition and a smelting temperature of 1200-1300 degrees Celsius.
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2022)
Review
Chemistry, Multidisciplinary
Xin Qu, Beilei Zhang, Jingjing Zhao, Baolong Qiu, Xiang Chen, Fengyin Zhou, Xiangyun Li, Shuaibo Gao, Dihua Wang, Huayi Yin
Summary: Spent lithium-ion batteries (LIBs) are crucial for regenerating new LIBs, and efficient recovery methods using inorganic salts and thermal energy have emerged as a viable approach. The salt-thermal method can easily convert spent LIBs materials to Li-rich salt and lithium-deficient oxides, allowing for easy separation and reutilization. This method has various applications, including the separation of electrode materials, leaching of valuable elemental metal, and regeneration of anode and cathode materials. We have provided a review of state-of-the-art technologies and discussed the benefits and drawbacks of using different inorganic salts for recycling spent LIBs.
Article
Chemistry, Physical
Xiang Chen, Yan Zhao, Yuan Sun, Long Wang, Hongwei Xie, Jiakang Qu, Shuaibo Gao, Dihua Wang, Huayi Yin
Summary: This study presents a molten salt electrolyzer approach for the simultaneous recovery of alloy scrap and CO2, enabling the reuse of valuable materials. The oxides in the molten salt and CO2 are converted to water-soluble sulfates and carbon, respectively, achieving high recovery rates. This method improves energy efficiency and closes the metal and carbon cycles.
SUSTAINABLE ENERGY & FUELS
(2022)
Article
Chemistry, Multidisciplinary
Jingjing Zhao, Jiakang Qu, Xin Qu, Shuaibo Gao, Dihua Wang, Huayi Yin
Summary: Clean lithium-ion battery recycling is crucial for a sustainable battery market. This study presents an electrochemical approach that can separate the cathode film and dissolve metals, allowing for the recovery of reusable materials. The method is applicable to various types of batteries and offers efficient recycling.