4.7 Article

Copper ferrite-yttrium oxide (CFYO) nanocomposite as remarkable humidity sensor

期刊

INORGANIC CHEMISTRY COMMUNICATIONS
卷 99, 期 -, 页码 180-188

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2018.11.024

关键词

Composite; Ferrites; Mechano chemical mixing; Humidity sensing; Stability

资金

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2018R1A6A1A03025708]

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In the present research paper, enhancement in humidity sensing properties of copper ferrite (CF) by methano chemical mixing it with yttrium oxide (Y2O3) to form copper ferrite-yttrium oxide (CFYO) nanocomposite is discussed. The nanocomposite was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM) techniques Appearance of characteristic bands of both CF and Y2O3 with slight shifts in the FTIR spectrum of the composite indicating interaction between them and formation of the composite confirmed. Enhancement in active sites for water adsorption in the composite due to the presence of Y2O3 confirmed from both XRD and SEM studies. Increased agglomeration of nano sized particles and improved crystallinity of the composite as compared to those of CF confirmed from TEM studies and SAED patterns. The resistive type humidity sensing behaviour of CE and CFYO composite were studied and comparatively analyzed. The composite showed maximum sensing re sponse of 4895 as against 110 of CF in the range 11%-97% RH. The response and recovery times of the composite were found to be 9 s and 23 s respectively while those of CF were 60 s and 90 s respectively. The CFYO sample showed stable sensing ability with a low humidity hysteresis. The sensing mechanism is discussed on the basis of chemisorption, physisorption and capillary condensation processes.

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