期刊
INORGANIC CHEMISTRY
卷 57, 期 23, 页码 14617-14623出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b02280
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资金
- National Key Research and Development Program of China [2017YFA0303002]
- State Key Lab of Silicon Materials, China [SKL2017-12]
- Fundamental Research Funds for the Central Universities of China
A metastable vanadium oxytelluride V2Te2O is prepared via a topochemical deintercalation of interlayer Rb+ cations in Rb1-delta V2Te2O. The new ternary mixed-anion compound crystallizes in a body-centered tetragonal lattice with a = 3.9282(1) angstrom and c = 13.277(5) angstrom, containing V2O square nets that are sandwiched by Te-atomic sheets. The charge-neutral [V2OTe2] block layers stack along the c axis with van der Waals forces, which shows a metallic behavior with a dominant T-2 dependence for resistivity at low temperatures. The electronic specific-heat coefficient reaches 33.9 mJ K-2 mol(-1), similar to 4 times that of the electronic structure calculations, suggesting a significant electron-mass renormalization. The electron correlation effect is concurrently demonstrated by the Wilson and Kadowaki-Woods ratios. Neither charge/spin-density wave nor superconductivity was observed down to 0.03 K.
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