Article
Chemistry, Physical
Jiafeng Shi, Zhongshuai Xie, Xiaolong Tang, Yaojin Wang, Guoliang Yuan, Jun-Ming Liu
Summary: The coupling of piezoelectric and plasmonic effects has been proven to enhance the photocatalytic performances. In this study, a new piezoelectric composite composed of Na0.5Bi0.5TiO3 nanoplates coated with Ag particles was prepared, showing excellent piezo-photocatalytic performances. The plasmonic effect of Ag nanoparticles widened the catalysts' spectral absorption range, and the electric field from the deformation of Na0.5Bi0.5TiO3 piezoelectric nanoplates greatly enhanced the separation and migration efficiencies of photo-generated charge carriers in Ag@ Na0.5Bi0.5TiO3 composites. With simultaneous full-spectrum lights and ultrasonic excitation, the piezo-photocatalytic activity of Ag@ Na0.5Bi0.5TiO3 achieved a significant degradation rate of 98.8% RhB in just 30 minutes.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Li Zhang, Weiwei Lu, Peng Xu, Hao Wang, Xuefeng Wei, Kaisheng Yao, Shuge Peng
Summary: A novel photo-activation method using Ag@Pd nanocubes for the degradation of persistent organic pollutants was proposed, with SO4- radicals identified as the main species responsible for the degradation. The plasmon-mediated nature of the Ag@Pd catalysts was confirmed, with the Pd shell identified as the preferential site for producing radical species. The proposed method shows promising potential for wastewater treatment based on the detected intermediates.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Multidisciplinary
Chadrasekhar Loka, Kee-Sun Lee
Summary: Ag-Ag2O-ZnO nanocomposite with localized surface plasmon resonance (LSPR) and p-n heterojunction structure was synthesized by hydrothermal process, which effectively improved the photocatalytic efficiency and suppressed the recombination of photogenerated electron-hole pairs. The nanocomposite exhibited excellent photocatalytic activity and achieved high degradation efficiency for different dyes under visible-light irradiation.
Article
Materials Science, Multidisciplinary
Yefei Guo, Xiaonan Fu, Ying Xie, Lin Zhu, Ruijie Liu, Lixin Liu
Summary: Ag/ZnO photocatalysts with different silver content were fabricated using a hydrothermal method. These photocatalysts exhibited excellent photocatalytic activity, enhanced visible light absorption, and good recycling stability.
Article
Chemistry, Analytical
Chuhong Zhu, Qiangsheng Zhao, Xiujuan Wang, Zhongbo Li, Xiaoye Hu
Summary: In this study, a functional SERS system was developed for sensitive detection of target analytes using concentration of analyte molecules on or nearby plasmonic nanostructures. The composite film of Ag-nanocubes/graphene-oxide/Au-nanoparticles on a hydrophobic surface effectively accumulated analyte molecules for enhanced SERS activity. The system showed promising applications in food safety inspection and environmental pollutant monitoring.
MICROCHEMICAL JOURNAL
(2021)
Article
Optics
Fengrui Li, Baojie Shan, Xiaofei Zhao, Chang Ji, Zhen Li, Jing Yu, Shicai Xu, Yang Jiao, Chao Zhang, Baoyuan Man
Summary: This study proposes a new composite nanofiber membrane, PVDF@Ag-ZnO/Au, that utilizes the coordination of piezoelectric and plasmonic effects to regulate the separation and migration of photo-generated carriers. The membrane shows enhanced photocatalytic degradation of organic dyes and has excellent flexibility and recyclability.
Article
Engineering, Environmental
Wenqiang Liu, Meng Zhou, Heqing Fu
Summary: A ternary Ag@ZnO@Ti3C2 MXene heterojunction (AZM) is synthesized to enhance photocatalytic activity by compensating for MXene's narrow bandgap with ZnO and Ag nanoparticles. The optimized AZM heterojunction photocatalyst shows high degradation efficiency for organic dyes under visible light irradiation.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Engineering, Environmental
Yin Zhang, Guomin Zhao, Zupeng Chen, Hailan Lian, Lu Gan, Mingzhu Pan
Summary: This study presents a strategy for constructing hierarchically structured photocatalysts for efficient degradation of VOCs. By assembling nanobiochar, ZnO, and silver nanoparticles, VOCs can be quickly captured and dynamically diffused, and the charge transfer bridge built by the silver nanoparticles enables spatial separation of charge carriers and visible-light response. The photocatalyst exhibits high efficiency, universality, and stability.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
N. Elavarasan, S. Vignesh, M. Srinivasan, G. Palanisamy, K. Bhuvaneswari, G. Venkatesh, T. Pazhanivel, P. Ramasamy
Summary: The highly efficient novel gC(3)N(4):MoS2:ZnO-Ag hybrid nanocomposite was successfully synthesized using a simple hydrothermal technique. Characterization using various tools showed its excellent photocatalytic upgrading activity and stability, attributed to increased visible-light absorption ability, lower bandgap values, and efficient charge separation and migration properties.
COLLOID AND INTERFACE SCIENCE COMMUNICATIONS
(2021)
Article
Engineering, Environmental
Shasha Li, Ce Shi, Hao Ai, Kaifeng Du
Summary: In this study, hyperporous cellulose microspheres (BCMs) with micron-sized macropores were fabricated using a one-step pre-crosslinking strategy. The BCMs showed decreased mass transfer resistance and increased accessible active sites, enabling rapid adsorption kinetics and high adsorption capacity. Functionalized BCMs (IL-BCMs) with anion exchange capacity demonstrated rapid adsorption kinetics, high adsorption capacity, reusability, and selectivity towards the target protein.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Electrochemistry
Zhaoyang Sun, Yanling Zhai, Guoliang Mei, Weiwei Guo, Zijian Fang, Lei Jiao, Zhijun Zhu, Xiaoquan Lu, Jianguo Tang
Summary: In situ reduction of AgI to Ag nanoparticles supported on C-doped boron nitride (AgI/BN-C) was developed for CO2 electroreduction to CO. The enhanced performance, with a faradaic efficiency of 99.5% and a high current density of 56.3 mA cm-2, can be mainly attributed to the controllable construction of Ag0-Ag+ sites.
ELECTROCHIMICA ACTA
(2023)
Article
Nanoscience & Nanotechnology
Anh-Tuan Vu, Van Hung Mac, Thanh Hung Nguyen, Thu Huong Nguyen
Summary: Carnation-like ZnO nanoparticles were successfully synthesized by precipitation method and used for dye degradation. Ag-ZnO composites with uniform distribution of Ag nanoparticles on ZnO petals were also obtained, which exhibited improved catalytic ability. The impact of Ag content on the structure and performance of the composites was investigated, and the 5Ag-ZnO sample showed the highest surface area, pore volume, and the lowest energy band gap (Eg).
Article
Polymer Science
Anna Sowinska, Magdalena Maciejewska, Laina Guo, Etienne Delebecq
Summary: Task-specific ionic liquids (TSILs) are designed for specific applications to improve the efficiency of vulcanization of rubber compounds while maintaining safe processing, characterized by satisfactory functional properties in EPDM vulcanizates.
Article
Chemistry, Multidisciplinary
Khalida Mubeen, Afshan Irshad, Akif Safeen, Uzma Aziz, Kashif Safeen, Tayyaba Ghani, Kamran Khan, Zulfqar Ali, Ihsan Ul Haq, Attaullah Shah
Summary: Heterogeneous photocatalysis is a promising method for removing organic, inorganic, and microbiological contaminants from wastewater to prevent damage to ecosystems. This study focuses on tuning the band structure of ZnO/CuO nanocomposites to enhance their photocatalytic activity. Experimental results show that increasing the CuO content in the nanocomposites leads to a decrease in optical bandgap. The wt. 10% CuO/ZnO nanocomposite exhibits superior photocatalytic activity compared to pure ZnO nanoparticles, with a 66.6% increase in degradation rate for methylene blue under visible irradiation.
JOURNAL OF SAUDI CHEMICAL SOCIETY
(2023)
Article
Nanoscience & Nanotechnology
Zhoutao Sun, Xiaohui Fang, Chen Kang, Yu Han, Lei Zha, Xinping Zhang
Summary: This paper presents a SERS probe platform based on suspended-core photonic crystal fibers, which offers direct, ultrasensitive, and reusable analyte detection. The probe is decorated with Ag/ZnO nanocomposites on the inner surface, allowing for enhanced light-analyte interaction and improved SERS detection sensitivity. The probe exhibits a detection limit of 10-13 M for crystal violet solution and an enhancement factor of 1011. It also demonstrates good photocatalytic performance, capable of degrading molecules under ultraviolet-light illumination within 20 min. This ultrasensitive and reusable SERS probe shows great potential for rapid and in situ liquid detection.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Xiaoyan Pei, Zhiyong Li, Huiyong Wang, Qiuju Zhou, Zuodong Liu, Jianji Wang
Summary: Surfactant-free microemulsions (SFMEs) based on ionic liquids (ILs) have shown great potential in various applications. In this study, a new kind of CO2-responsive SFME composed of quaternary ammonium IL, dimethyl sulfoxide, and ethyl acetate was developed. The microemulsion can be reversibly switched between emulsification and complete phase separation upon CO2 and N-2 bubbling. Mechanism studies confirmed that the reversible switching is due to the generation and restoration of more hydrophilic carbamate salts from the reaction of CO2 with IL anions. The CO2-switchable SFMEs were used as a microreactor for room temperature synthesis of Zn-based metal-organic frameworks, achieving successful reaction and microemulsion recycling.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Chemistry, Physical
Jing Zhao, Hucheng Zhang, Haiyan Wang, Jianji Wang
Summary: This study explores the relationship between Lewis acid and base strengths on Pd-CoOx interfaces and catalytic activity, showing that the introduction of Pd can enhance catalytic performance. The findings offer insights for rational design and synthesis of heterogeneous catalysts including CO2 hydrogenation.
MOLECULAR CATALYSIS
(2022)
Review
Chemistry, Multidisciplinary
Li Sun, Kelei Zhuo, Yujuan Chen, Quanzhou Du, Suojiang Zhang, Jianji Wang
Summary: This review introduces the use of ionic liquid (IL) electrolytes combined with redox active species to enhance the energy density of supercapacitors (SCs). The introduction of redox active species contributes to pseudocapacitance and various IL-REs and their energy storage mechanisms are discussed. Future research needs to address current challenges in order to advance this promising field.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Engineering, Environmental
Haiyan Wang, Lijing Wang, Hucheng Zhang, Hao Jiang, Chunzhong Li, Jianji Wang
Summary: Sb-NC/PoMXene is synthesized by cross-linking Sb-NC and PoMXene through Ti-O-Sb bond, and it exhibits excellent properties including electronic conductivity, sulfur loading, polysulfide capture, and catalytic centers. These nanostructured hybrids provide fast ion transport and robust architecture, resulting in high capacity and long cyclability in lithium-sulfur batteries.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Songlin Wang, Nan Jiang, Yanyan Liu, Yan Hao, Qiying Zhang, Hongying Niu, Jianji Wang
Summary: In this study, Pb-Mg nanosheet catalysts with high activity, excellent stability, and recyclability were developed for solvent-free synthesis of MPC. The catalyst exhibited high DPC conversion and MPC selectivity, and could be easily separated and reused using simple centrifugation.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Chemistry, Physical
Hua Li, Xiaodong Hu, Chunfeng Wang, Yujuan Chen, Kelei Zhuo, Jianji Wang
Summary: In this study, an IL-rGA material was prepared using hydrothermal reduction and modification tactics with the assistance of an ionic liquid. The IL-rGA material, with its porous texture and modified surface, enables rapid infiltration and sufficient adsorption of electrolyte ions, resulting in a significant improvement in specific capacitance. By using this material and a specific IL electrolyte, high energy density and power density supercapacitors can be achieved, meeting the requirements of a wider range of electrical facilities.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Peng Wang, Runyao Zhao, Fengtao Zhang, Jianji Wang, Buxing Han, Zhimin Liu
Summary: This study demonstrates the rational design and controllable fabrication of a metal oxide hybrid catalyst for electrochemical water splitting, showing excellent performance in hydrogen evolution reaction. The catalyst exhibited promising application potentials with its unique biphasic microstructures.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Physical
Xiaohui Li, Yingying Guo, Huiyong Wang, Zhiyong Li, Jianji Wang
Summary: The regulation of anionic structures on the formation of ionic liquid vesicles in aqueous solution was investigated. It was found that the synergistic effect of hydrophobic and pi-pi interaction played a vital role in the vesicle formation of a specific ionic liquid. The reversible structural transition between vesicle and micelle was also observed.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Multidisciplinary
Zhijun Guo, Guangyue Bai, Xize Zhan, Kelei Zhuo, Jianji Wang, Yujie Wang
Summary: A coassembly strategy for a supramolecular vector/drug was proposed, which uses biocompatible molecules to achieve pH-responsive and sustained release functions. The self-assembling behaviors of the components and the functions of the vector/drug were characterized. The results demonstrate that this coassembly method is a simple and effective approach.
Article
Nanoscience & Nanotechnology
Yuanchao Pei, Yaxin Zhang, Jie Ma, Maohong Fan, Suojiang Zhang, Jianji Wang
Summary: Ionic liquids have attracted significant interest in the field of science and technology, with early research focusing on their potential as green solvents. However, recent developments have shown that their designable structure and properties make them a versatile platform for advanced materials. This mini-review summarizes the applications of newly developed ionic liquids in perovskite solar cells, seawater desalination, nanoreactors, and advanced intelligent materials, and critically analyzes existing barriers and future trends. It aims to provide a useful guide for the design and understanding of advanced materials based on ionic liquids, and to inspire research and development in this field.
MATERIALS TODAY NANO
(2022)
Article
Engineering, Environmental
Yuling Zhao, Chang Xu, Qingling Qi, Jikuan Qiu, Zhiyong Li, Huiyong Wang, Jianji Wang
Summary: In this study, a series of bipyridine-based two-dimensional (2D) covalent organic frameworks (COFs) were constructed, and by tailoring the pore environment, TFBBPY-OMe-COF showed highly efficient adsorption and excellent selectivity for palladium recovery. Furthermore, it was successfully employed to capture Pd(II) in a simulated solution derived from waste printed circuit boards.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Yuanchao Pei, Wanjun Zhang, Yaxin Zhang, Jie Ma, Yang Zhao, Zhiyong Li, Jianji Wang, Ran Du
Summary: The design of thermal-responsive functional ionic liquids that can respond reversibly remains a challenge for the construction of smart systems. This study prepared a series of PEGylated ionic liquids and characterized their structures and thermal properties. The physicochemical properties, including density and viscosity, were measured and modeled. The results showed that these PEGylated ionic liquids exhibited good surface activity and low critical solution temperature phase behavior. The interaction between the ionic liquids and water molecules was analyzed to understand the mechanism of thermal-induced phase separation. This study provides valuable information for designing new thermoresponsive ionic liquids and their applications.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Yangshuo Li, Huiyong Wang, Bing Chang, Yingying Guo, Zhiyong Li, Shamraiz Hussain Talib, Zhansheng Lu, Jianji Wang
Summary: Through liquid-phase exfoliation in N-methylpyrrolidone (NMP) assisted via aliphatic amines as intercalators, bulk ZrS2 powder was successfully exfoliated into single and few-layer nanosheets. The exfoliation yield was 27.3%, with 77.1% of ZrS2 nanosheets being 2-3 layers. The ZrS2 nanosheets exhibited higher activity in electrocatalytic dinitrogen reduction compared to ZrS2 nanofibers and bulk ZrS2 powder, indicating the great potential of liquid phase exfoliation in mass production of high activity ZrS2 nanosheets.
GREEN ENERGY & ENVIRONMENT
(2023)
Article
Chemistry, Physical
Quanzhou Du, Yuhua Zhao, Yujuan Chen, Jianming Liu, Huanhuan Li, Guangyue Bai, Kelei Zhuo, Jianji Wang
Summary: Nitrogen-doped porous carbon nanosheets (NPCNs) with unique structure were studied for their potential application as anode and cathode material in potassium-ion hybrid capacitors (PIHCs). The structural changes of NPCNs during potassiation and depotassiation were analyzed using Raman spectroscopy and transmission electron microscopy. The PIHC device assembled with NPCNs exhibited a superior energy density of 128 Wh kg-1 and a capacity retention of 90.8% after 9000 cycles. This research contributes to the development of double-functional self-matching materials for high-performance hybrid energy storage devices.
GREEN ENERGY & ENVIRONMENT
(2023)
Article
Chemistry, Multidisciplinary
Yongkui Chen, Jikuan Qiu, Xia-Guang Zhang, Huiyong Wang, Wenhui Yao, Zhiyong Li, Qingchun Xia, Guangshan Zhu, Jianji Wang
Summary: Covalent organic frameworks (COFs) have attracted significant interest as proton-exchange membranes, chemical sensors, and electronic devices. The synthesis of a light/heat switchable COF-HNU9, capable of reversible photoisomerization and high proton conductivity, has been achieved through the incorporation of a donor-acceptor Stenhouse adduct (DASA) within the COF structure. The COF-HNU9 showed a substantial increase in proton conductivity under visible light irradiation at high humidity, demonstrating promising prospects for stimuli-responsive COFs.