期刊
FUEL
卷 236, 期 -, 页码 1505-1511出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2018.09.126
关键词
Methane storage; Gas hydrates; Solidified natural gas; Energy storage; In-situ Raman spectroscopy; Hydrate stability
资金
- Energy Innovation Research Programme (EIRP) [NRF2015EWTEIRP002-002]
- National Research Foundation (NRF), Singapore
- National University of Singapore [R-261-508-001-646/733]
The widespread use of methane (CH4) as a bridging fuel to transition into a carbon-constrained world necessitates the need to develop safe, reliable and efficient technology for large-scale CH4 storage. Solidified natural gas (SNG) technology via clathrate hydrates can store large volumes of CH4 at mild storage conditions (atmospheric pressure and moderate temperatures) compared to compressed natural gas (CNG) or adsorbed natural gas (ANG). Slow hydrate growth kinetics and stability of hydrates at moderate temperatures are two challenges that need to be mitigated in order to commercialize SNG technology. In this work, we characterize the mixed (methane-tetrahydrofuran) hydrate formation by analyzing solid hydrate phase highlighting temporal changes of the cage occupancy using in-situ Raman spectroscopy complemented by measuring the CH4 uptake along with visual observations. Powder X-ray diffraction (PXRD) characterization of synthesized hydrates confirms the presence of only sII structure. We also demonstrate the stability of the sII mixed (CH4-THF) hydrates at near atmospheric pressure for a time period of two months.
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